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Unruh, D. M.

Publications and source records attributed to Unruh, D. M..

At least 19 records

Pb, Sr, Nd, and Hf isotopic constraints on the origin of Hawaiian basalts and evidence for a unique mantle source

The isotopic Pb, Sr, Nd, and Hf compositions of rocks from nine Hawaiian volcanos are determined using the analytical procedures described by Tatsumoto and Unruh (1976) and Patchett and Tatsumoto (1980). The results are presented in graphs, tables, and maps and characterized in detail. The mantle plume, the oceanic lithosphere, and the depleted mantle are identified as distinct sources of the Hawaiian basalts, with different mechanisms responsible for the formation of shield-building tholeiites, late-stage alkalic rocks, and posterosional basalts. The uniqueness of the Hawaiian basalts and the possibility that the Koolau end member represents an undepleted 'primitive' mantle reservoir are considered.

Stille, P.↗

Lu-Hf and Sm-Nd evolution in lunar mare basalts

Existing cumulate remelting models for mare basalt genesis are evaluated in light of Lu-Hf, Rb-Sr, Sm-Nd data and overall REE characteristics in order to determine the simplest model that can account for these data. A data base for comparing Lu-Hf evolution in the lunar mantle as inferred from Lu-Hf analyses of oceanic basalts is presented along with a preliminary comparison of Lu-Hf and Sm-Nd evolution betwee mare basalts and terrestrial oceanic basalts. It is found that Lu/Hf characteristics of mare basalts cannot be explained in terms of modal melting of cumulate sources formed from a magma ocean with chondritic Lu/Hf. The data are consistent with a model in which the cumulate sources formed from a light REE + HF-enriched magma ocean. Nonmodal melting of ilmenite in the sources is also required. The Lu-Hf data suggest that even the high-Ti basalt sources contained no more than about 3 percent ilmenite.

Unruh, D. M.↗

The Lf-Hf evolution of KREEP

The most widely accepted theory for lunar evolution is the cumulate remelting model. According to the model, the outer several hundred kilometers of the Moon were molten early in its history at about 4.4 to 4.5 billion years ago. As this magma ocean cooled minerals began to crystallize and accumulate either at the base or the top of the magma ocean depending upon the density of the mineral. The accumulated minerals at the base were partially remelted at about 3.9 to 3.2 billion years to produce the mare basalts.

Unruh, D. M.↗

Pb, Sr, Nd and Hf isotopic evidence of multiple sources for Oahu, Hawaii basalts

Pb, Sr, Nd and Hf isotopic compositions of Oahu volcanics indicate that the three principal volcanic series on Oahu Koolau, Honolulu and Waianae - were derived from isotopically distinct sources. Honolulu and Waianae basalts plot on the Nd-Pb-Sr 'mantle plane' whereas Koolau data plot distinctly below the plane.

Stille, P.↗

Ar-40/Ar-39 and U-Th-Pb dating of separated clasts from the Abee E4 chondrite

Ar-40/Ar-39 and U-Th-Pb are investigated for three clasts from the Abee (E4) enstatite chondrite, yielding Ar-40/Ar-39 plateau ages (and/or maximum ages) of 4.5 Gy, while two of the clasts give average ages of 4.4 Gy. The 4.4-4.5 Gy range does not resolve possible age differences among the clasts. The U-Th-Pb data are consistent with the interpretation that initial clast formation occurred 4.58 Gy ago, and that the clasts have since remained closed systems which have been contaminated with terrestrial Pb. The thermal history of Abee deduced from Ar data seems consistent with that deduced from magnetic data, suggesting that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, experiencing no significant subsequent heating.

Bogard, D. D.↗

Origin and evolution of the Nakhla meteorite inferred from the Sm-Nd and U-Pb systematics and REE, Ba, Sr, Rb and K abundances

Analyses of whole rock and mineral separates from the Nakhla meteorite are carried out by means of Sm-Nd and U-Tn-Pb systematics and by determining their REE, Ba, Sr, Rb, and K concentrations. Results show that the Sm-Nd age of the meteorite is 1.26 + or - 0.7 b.y., while the high initial epsilon(Nd) value of +16 suggests that Nakhla was derived from a light REE-depleted, old planetary mantle source. A three-stage Sm-Nd evolution model is developed and used in combination with LIL element data and estimated partition coefficients in order to test partial melting and fractional crystallization models and to estimate LIL abundances in a possible Nakhla source. The calculations indicate that partial melting of the source followed by extensive fractional crystallization of the partial melt could account for the REE abundances in the Nakhla constituent minerals. It is concluded that the significantly younger age of Nakhla than the youngest lunar rock, the young differentiation age inferred from U-Th-Pb data, and the estimated LIL abundances suggest that this meteorite may have been derived from a relatively large, well-differentiated planetary body such as Mars.

Nakamura, N.↗

U-Th-Pb age of the Barwell chondrite - Anatomy of a 'discordant' meteorite

A Pb-Pb internal isochron for the Barwell L5-6 chondrite yields an age of 4.530 plus or minus 0.005 billion years, using the measured U-238/U-235 ratio of 135.24 plus or minus .17. If the terrestrial U isotope composition is used, an age of 4.559 billion years is obtained. The Pb isotopic composition is distinctly different from that of a terrestrial contaminant found in the fusion crust of the Barwell stone. When the U-Th-Pb data are plotted on the concordia diagram, the data define a line that intersects the concordia curve at approximately 4.53 and 0 billion years, and nearly all of the data plot above the concordia curve, regardless of the initial Pb correction. This discordancy and the Pb isotopic composition of the triolite are attributed to a recent reequilibration of Pb and not to terrestrial contamination.

Unruh, D. M.↗

Implications from Luna 24 sample 24170 to U-Pb evolution in the lunar mantle

The concentrations of U, Th and Pb, as well as the Pb isotopic composition, have been determined for a Luna 24 sample from the Mare Crisium area. A relatively recent disturbance to the U-Pb system during meteorite impact or burial in hot ejecta is suggested by the findings. According to three-stage U-Pb evolution model calculations, the source cumulates of the Luna 24 basalt evolved in a U-238/Pb-204 environment much lower than that of the Apollo mare basalts. A laterally heterogeneous lunar magma ocean, U-Pb fractionation during cumulate formation, and/or lack of KREEP addition to the Luna 24 basalt are also reflected in the calculations.

Unruh, D. M.↗

Origin and history of the adcumulate eucrite, Moama as inferred from REE abundances, Sm-Nd and U-Pb systematics

The abundances of Sm-Nd and U-Pb isotopes and of rare earth elements (REE) in Moama cumulate eucrite were investigated. The Sm-Nd data plotted on a Nd-143/Nd-144 vs Sm-147/Nd-144 evolution diagram define a line with a slope corresponding to an age of 4.58 plus or minus 0.05 billion years and an initial Nd-143/Nd-144 ratio of about 0.50684. Moama was found to contain the lowest overall trivalent REE abundances, the most light REE-depleted abundance pattern, and largest positive Eu anomaly of any eucrite yet studied. The REE data indicate that Moama could have been derived by about 1 to 5% fractional crystallization from a liquid with REE contents similar to Juvinas, or about 20 to 30% fractional crystallization from a Sioux County-like liquid. The data are consistent with the hypothesis that the Moama, Serra de Mage, and Moore county cumulate meteorites could have been derived from the same parent liquid. Results of the U-Th-Pb study indicate that the majority of the Pb in Moama is of terrestrial origin, and suggest that the meteorite has undergone a minor thermal event causing re-equilibration of the U-Pb system.

Hamet, J.↗

Early history of the moon: Implications of U-Th-Pb and Rb-Sr systematics

Anorthosite 60015 contains the lowest initial Sr-87/Sr-86 ratio yet reported for a lunar sample. The initial ratio is equal to that of the achondrite Angra dos Reis and slightly higher than the lowest measured Sr-87/Sr-86 ratio for an inclusion in the C3 carbonaceous chondrite Allende. The Pb-Pb ages of both Angra does Reis and Allende are 4.62 X 10 to the ninth power yr. Thus, the initial Sr/87/Sr-86 ratio found in lunar anorthosite 60015 strongly supports the hypothesis that the age of the Moon is about 4.65 b.y. The U-238/Pb-204 value estimated for the source of the excess lead in "orange soil" 74220 is approximately 35 and lower than the values estimated for the sources of KREEP (600-1000), high-K (300-600), and low-K (100-300) basalts. From these and other physical, chemical and petrographic results it was hypothesized that (1) the moon formed approximately 4.65 b.y. ago; (2) a global-scale gravitational differentiation occurred at the beginning of lunar history; and (3) the differentiation resulted in a radical chemical and mineralogical zoning in which the U-238/Pb-204 ratios increased toward the surface, with the exception of the low U-238/Pb-204 surficial anorthositic layer which "floated" at the beginning of the differentiation relative to the denser pyroxene-rich material.

Tatsumoto, M.↗

Evolution of mare basalts - The complexity of the U-Th-Pb system

An attempt has been made to gain more insight into mare-basalt evolution by performing a very detailed leaching and mineral-separation U-Th-Pb systematics study on mare basalt 15085. It is found that about 20-50% of the U, Th, and Pb reside on the grain boundaries or in the mesostasis and that the Pb-207/Pb-206 ratios of the grain boundaries and crystal interiors are distinctly different. These distinct trends appear to represent either continuous or episodic postcrystallizational disturbances to the U-Th-Pb system of this rock. Using U and Pb partition coefficients, it is concluded that existing two- and three-stage U-Pb evolution models do not accurately describe mare-basalt genesis. An alternative two-stage + KREEP mixing model is proposed as a simple approximation to U-Pb evolution in lunar rocks. Most Rb-Sr and Sm-Nd data are compatible with this model.

Unruh, D. M.↗

U-Th-Pb and Rb-Sr systematics of Apollo 17 boulder 7 from the North Massif of the Taurus-Littrow valley

Portions of highland breccia boulder 7 collected during the Apollo 17 mission were studied using U-Th-Pb and Rb-Sr systematics. A Rb-Sr internal isochron age of 3.89 plus or minus 0.08 b.y. with an initial Sr-87/Sr-86 of 0.69926 plus or minus 0.00008 was obtained for clast 1 (77135,57) (a troctolitic microbreccia). A troctolitic portion of microbreccia clast 77215,37 yielded a U-Pb internal isochron of 3.8 plus or minus 0.2 b.y. and an initial Pb-206/Pb-207 of 0.69. These internal isochron ages are interpreted as reflecting metamorphic events, probably related to impacts, which reset Rb-Sr and U-Pb mineral systems of older rocks.

Nunes, P. D.↗

Early history of the moon: Implications of U-Th-Pb and Rb-Sr systematics

Anorthosite 60015 contains the lowest initial Sr-87/Sr-86 ratio (0.69884 + or - 0.00004) yet reported for a lunar sample. The initial ratio is equal to that of the achondrite Angra dos Reis and slightly higher than the lowest measured Sr-87/Sr-86 ratio for an inclusion in the C3 carbonaceous chondrite Allende. The Pb-Pb ages of both Angra dos Reis and Allende are 4.62 x 10 to the 9th power years (4.62 billion years). Thus, the initial Sr-87/Sr-86 ratio found in lunar anorthosite 60015 strongly supports the hypothesis that the age of the moon is about 4.65 b.y. The U-238/Pb-204 value estimated for the source of the excess lead in orange soil 74220 is lower than the values estimated for the sources of KREEP (600-1000), high K (300-600) and low K (100-300) basalts.

Tatsumoto, M.↗

U-Th-Pb systematics of some Apollo 17 lunar samples and implications for a lunar basin excavation chronology

U, Th, and Pb concentrations and lead isotopic compositions of selected Apollo 17 soil and rock samples are presented. Concordia treatments of U-Pb whole samples of Apollo 17 mare basalts and highland rocks probably reflect several early thermal events about 4.5 b.y. old more consistently than do U-Pb ages of samples collected at other lunar sites. We propose that all lunar U-Th-Pb data reflect a multistate U-Pb evolution history most easily understood as being related to a complex planetesimal bombardment history of the moon which apparently dominated lunar events from about 4.5 to about 3.9 b.y. ago. Semi-distinct events at about 4.0, about 4.2, and 4.4-4.5 b.y. are evident on whole-rock frequency versus Pb-207/Pb-206 age histograms. Each of these events may reflect multiple cratering episodes. For mare basalts, complete resetting of the source rock U-Pb systems owing to Pb loss relative to U was apparently often approached after a major planetesimal impact.

Nunes, P. D.↗