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Varanasi, Prasad

Publications and source records attributed to Varanasi, Prasad.

16 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Improvement of the Database on the 1.13-microns Band of Water Vapor

Corrections have recently been reported (Giver et al.) on the short-wave (visible and near-infrared) line intensities of water vapor that were catalogued in the spectroscopic database known as HITRAN. These updates have been posted on www.hitran.com, and are being used to reanalyze the polar stratospheric absorption in the 0.94 microns band as observed in POAM. We are currently investigating additional improvement in the 1.13 microns band using data obtained by us with an absorption path length of 1.107 km and 4 torr of water vapor and the ab initio line list of Partridge and Schwenke (needs ref). We are proposing the following four types of improvement of the HITRAN database in this region: 1) HITRAN has nearly 200 lines in this region without proper assignments of rotational quantum levels. Nearly all of them can now be assigned. 2) We have measured positions of the observable H2O-17 and H2O-18 lines. These lines in HITRAN currently have approximate positions based upon rather aged computations. 3) Some additional lines are observed and assigned which should be included in the database. 4) Corrections are necessary for the lower state energies E" for the HITRAN lines of the 121-010 "hot" band.

Giver, Lawrence P.↗
NASA NTRS2000

Consensus Assignments for Water Vapor Lines Not Assigned on the HITRAN Database: 13,200 to 16,500/cm

There are nearly 800 water Vapor-lines in the 13,200-16,500/cm region that do not have rovibrational assignments in the HITRAN database. The positions and intensities in the database were determined by Mandin et al., but assignments could not be determined at that time. Polyansky, et al. have now assigned over 600 of the unassigned lines in the 11,200-16,500/cm region. Schwenke has also given rovibrational assignments to many of these unassigned lines throughout the visible and near-infrared. Both articles changed the assignments of some HITRAN lines. Carleer et al. extend assignments to some weaker lines measured by them on new spectra with excellent signal/noise. However, some lines measured by Mandin et al. were omitted by Carleer, et al. because of blends due to lower spectral resolution. The rovibrational assignments of Polyansky et al. completely agree with those in Schwenke's article for only about 200 lines. However, Schwenke's ab initio line list is available on his internet site (http://ccf.arc.nasa.gov/-dschwenke). A detailed comparison of the Polyansky et al.line list, the Carleer et al.line list, and Schwenke's ab initio line list shows a larger number of agreements. In many cases the disagreement is only about the vibrational and/or rotational upper level, while there is agreement on the lower state assignment and energy level, "E", which is of primary importance for atmospheric applications. We will present a line list of "consensus" assignments in the 13,200-16,500/cm region for consideration of inclusion on the HITRAN and GEISA databases. This will substantially reduce the number of unassigned lines on the databases in this spectral region.

Giver, Lawerence P.↗
NASA NTRS1994

Measurement of the absorption cross-sections of CFC-11 at conditions representing various model atmospheres

Absorption cross-sections, K(sub V)(/(cm)(atm)), have been measured in the 9.2 and 11.8 micrometer bands of CFC-11 (CCl3F) using a high-resolution Fourier transform spectrometer. Temperature and total (N2-broadening) pressure have been varied to obtain results at conditions representative of the atmosphere. The measured absolute intensities (in units of 10(exp -17) cm/molecule of the 9.2 and 11.8 micrometer bands are 2.591 +/- 0.013 and 6.974 +/- 0.038, respectively.

Li, Zhenhua↗
NASA NTRS1993

Line widths of (N-14)H3 and (N-15)H3 applicable to planetary atmospheric observations

The collision-broadened half-widths of sP(1,0), sP(3,2), sP(4,1), sP(4,2), and sP(4,3) in the v2 sup s-fundamental bands of (N-14)H3 and (N-15)H3 have been measured at 198, 245, and 295 K employing the Doppler-limited spectral resolution of a tunable diode laser spectrometer. The temperature dependence of the collision-broadened half-widths of these lines broadened by H2 and N2 has been determined. In addition, we have also measured the air-broadened line widths of all of these lines at 295 K and the half-width of the sP(3,2) line of (N-15)H3 broadened by (N-14)H3 at 198, 245, and 295 K.

Varanasi, Prasad↗
NASA NTRS1993

Infrared spectroscopic measurements relevant to atmospheric remote sensing

SF6 is a synthetic chemical which is used in many industrial applications and as a meteorological tracer. This paper describes determinations of spectral absorption coefficients k-nu of SF6 measured in the central Q-branches of the nu(3)-fundamental at 947/cm at various temperature-pressure combinations representing tangent heights in solar-occultation experiments or layers in the atmosphere. Spectral data were also obtained for C2H4 and NH3 fundamental bands. Measurements were made with the Doppler-limited spectral resolution of a tunable diode laser spectrometer with a cryogenically cooled absorption cell, described by Varanasi and Chudamani (1992).

Varanasi, Prasad↗
NASA NTRS1992

Absorption coefficients of CFC-11 and CFC-12 needed for atmospheric remote sensing and global warming studies

Spectral absorption coefficients k(v) in the atmospheric window are reported for CFC-11 and CFC-12. Data obtained with a grating spectrometer are compared with NCAR cross sections and measurements of k(v) made with a tunable diode laser spectrometer at various temperature-pressure combinations representing tangent heights or layers in the atmosphere are presented. The results are suitable for atmospheric remote sensing and global warming studies.

Varanasi, Prasad↗
NASA NTRS1992

Absorption spectra of HCFC-22 around 829/cm at atmospheric conditions

Spectral absorption coefficients of HCFC-22 have been measured around 829/cm in the laboratory at various temperature-pressure combinations chosen to represent tangent heights (as in solar-occultation experiments) or layers in the atmosphere. The data measured employing the Doppler-limited spectra resolution (about 10 exp -4/cm) of a tunable diode laser spectrometer are free of instrumental distortion and are more practical in this case than the spectral line parameters adapted in conventional line-by-line procedures for analyzing atmospheric spectra. The present data obtained with N2 as the broadening gas are shown to be directly applicable to the real atmosphere.

Varanasi, Prasad↗
NASA NTRS1992

Intensity and linewidth measurements in the 13.7-micron fundamental bands of (C-12)2H2 and (C-12)(C-13)H2 at planetary atmospheric temperatures

The absolute intensities and collision-broadened half-widths of several lines in the P-,Q-, and R-branches of the nu5-fundamental band of (C-12)2H2 have been measured at various temperatures between 147 and 295 K employing the Doppler-limited spectral resolution (about 10 exp -4/cm) of a tunable diode laser spectrometer. The absolute intensities of R(5), R(7), R(9), and R(20) in the same fundamental belonging to (C-12)(C-13)H2 have also been measured at 294 K. The temperature dependence of the collision-broadened half-width has been determined for some of the lines broadened by planetary atmospheric gases, namely, He, Ar, H2, and N2. Four self-broadened linewidths of (C-12)2H2, as well as three H2-broadened linewidths and a self-broadened half-width of (C-12)(C-13)H2, have also been retrieved from the measurements.

Varanasi, Prasad↗
NASA NTRS1990

Infrared line parameters at low temperatures relevant to planetary atmospheres

Employing the techniques that were described in several publications for measuring infrared lineshifts, linewidths and line intensities with a tunable diode laser, these parameters were measures for lines in the important infrared bands of several molecules of interest to the planetary astronomer at low temperatures that are relevant to planetary atmospheres using He, Ne, Ar, H2, N2, O2, and air as the perturbers. In addition to obtaining the many original data on the temperature dependence of the intensities and linewidths, it was also the first measurement of the same for the collision-induced lineshift of an infrared line and it showed that it was markedly different from that of the corresponding collision-broadened linewidth.

Varanasi, Prasad↗
NASA NTRS1989

Intensity measurements in the 720.8/cm Q branch of (C-12)(O-16)2

Measurements of the 15-micron bands of CO2 are presented, focusing on measurements to determine the validity of the intensity measurements in the 720.8/cm band used as a spectroscopic parameter in temperature sounding experiments. The absolute intensities of the lines between 718.9449/cm and 719.8319/cm in the Q branch of (C-12)(O-16)2 at 295 K are measured using the Doppler-limited spectral resolution (about 0.0001/cm) of a tunable diode laser. The differences between the results and previously reported data are discussed.

Varanasi, Prasad↗
NASA NTRS1989

Intensity and line width measurements in the nu(u) fundamental band of (C-13)H4

Intensities and collision-broadened line widths have been measured in the nu(u) fundamental band of (C-13)H4 at 295 K, employing the Doppler-limited spectral resolution of a tunable diode laser spectrometer and a (C-13)-enriched sample of CH4, H2, He, Ar, N2, O2, and air were chosen as the broadening gases in order to provide the data needed in atamospheric and planetary atamospheric applications.

Varanasi, Prasad↗
NASA NTRS1989

Linewidth measurements in the thermal infrared bands of (C-12)H3D at planetary atmospheric temperatures

Collision-broadened halfwidths of three lines in the nu3 fundamental band and of four lines in the nu6 fundamental band of (C-12)H3D have been measured at temperatures between 123 and 295 K using the Doppler-limited spectral resolution of a tunable diode laser spectrometer. Temperature dependence of the linewidths has been determined in self-broadening and in broadening by H2, He and N2.

Varanasi, Prasad↗
NASA NTRS1988

Infrared line widths at planetary atmospheric temperatures

Recent theoretical models and measurements of the variation of collision-broadened line width with temperature in the infrared are discussed for temperatures relevant to planetary atmospheres. The present review is restricted to lines broadened by H2, N2, O2, CO2, and He, the lines formed in the atmospheres of Jupiter, Saturn, Uranus, and Neptune. The design for a low-temperature absorption cell consisting of a nickel-coated copper tube is described. The lack of an adequate theoretical model for variation of the collision-broadened line width with temperature in terms of the molecular constants of the colliding partners is pointed out.

Varanasi, Prasad↗