Diffusion in the system K2O-SrO-SiO2. IV - Mobility model, electrostatic effects, and multicomponent diffusion.
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Engineering topics
Publications and source records attributed to Varshneya, A. K..
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Electron microprobe examination revealed that glassy lunar fragments had inclusions as well as boundaries between mineral glasses of different compositions. Glassy lunar spherules showed detectable heterogeneity less marked than that of the fragments. The room-temperature refractive indices and densities of the spherules are changed by heat-treating them at 500 to 700 C. The large increases (as much as 2% in density and 0.7% in index of refraction) are difficult to explain on the basis of classical glass-transition phenomena alone unless extremely rapid cooling rates are assumed. Further, the spherules darkened significantly when they were heated in air or a medium vacuum above 625 C.
The self-diffusion coefficients were measured by introducing a slab of glass previously irradiated in a reactor between two slabs of unirradiated glass. By heating the specimens, etching them sequentially and determining the radioactivity, self-diffusion coefficients for K and Sr were measured. It is pointed out that the results obtained in the investigations appear to support the proposal that the network of the base glass predominantly controls the activation energy for the diffusion of ions.
Multicomponent diffusion theory in glasses and application to tektites
Fe diffusion coefficients measured at various temperatures above 1150 C to calculate homogenization times of Thailand tektite source
Electron microscopic examination of Thailand tektite
Effective binary diffusion coefficients for multicomponent diffusion determined for potassium oxide and SrO in system potassium oxide-SrO- silicon dioxide