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Vasilkov, A.

Publications and source records attributed to Vasilkov, A..

Global Free-tropospheric NO2 Abundances Derived Using a Cloud Slicing Technique from AURA OMI

We derive free-tropospheric NO2 volume mixing ratios (VMRs) by applying a cloud-slicing technique to data from the Ozone Monitoring Instrument (OMI) on the Aura satellite. In the cloud-slicing approach, the slope of the above-cloud NO2 column versus the cloud scene pressure is proportional to the NO2 VMR. In this work, we use a sample of nearby OMI pixel data from a single orbit for the linear fit. The OMI data include cloud scene pressures from the rotational-Raman algorithm and above-cloud NO2 vertical column density (VCD) (defined as the NO2 column from the cloud scene pressure to the top of the atmosphere) from a differential optical absorption spectroscopy (DOAS) algorithm. We compare OMI-derived NO2 VMRs with in situ aircraft profiles measured during the NASA Intercontinental Chemical Transport Experiment Phase B (INTEX-B) campaign in 2006. The agreement is generally within the estimated uncertainties when appropriate data screening is applied. We then derive a global seasonal climatology of free-tropospheric NO2 VMR in cloudy conditions. Enhanced NO2 in the free troposphere commonly appears near polluted urban locations where NO2 produced in the boundary layer may be transported vertically out of the boundary layer and then horizontally away from the source. Signatures of lightning NO2 are also shown throughout low and middle latitude regions in summer months. A profile analysis of our cloud-slicing data indicates signatures of lightning-generated NO2 in the upper troposphere. Comparison of the climatology with simulations from the global modeling initiative (GMI) for cloudy conditions (cloud optical depth less than10) shows similarities in the spatial patterns of continental pollution outflow. However, there are also some differences in the seasonal variation of free-tropospheric NO2 VMRs near highly populated regions and in areas affected by lightning-generated NOx.

NO2↗

Fast Simulators for Satellite Cloud Optical Centroid Pressure Retrievals, 1. Evaluation of OMI Cloud Retrievals

The cloud Optical Centroid Pressure (OCP), also known as the effective cloud pressure, is a satellite-derived parameter that is commonly used in trace-gas retrievals to account for the effects of clouds on near-infrared through ultraviolet radiance measurements. Fast simulators are desirable to further expand the use of cloud OCP retrievals into the operational and climate communities for applications such as data assimilation and evaluation of cloud vertical structure in general circulation models. In this paper, we develop and validate fast simulators that provide estimates of the cloud OCP given a vertical profile of optical extinction. We use a pressure-weighting scheme where the weights depend upon optical parameters of clouds and/or aerosol. A cloud weighting function is easily extracted using this formulation. We then use fast simulators to compare two different satellite cloud OCP retrievals from the Ozone Monitoring Instrument (OMI) with estimates based on collocated cloud extinction profiles from a combination of CloudS at radar and MODIS visible radiance data. These comparisons are made over a wide range of conditions to provide a comprehensive validation of the OMI cloud OCP retrievals. We find generally good agreement between OMI cloud OCPs and those predicted by CloudSat. However, the OMI cloud OCPs from the two independent algorithms agree better with each other than either does with the estimates from CloudSat/MODIS. Differences between OMI cloud OCPs and those based on CloudSat/MODIS may result from undetected snow/ice at the surface, cloud 3-D effects, low altitude clouds missed by CloudSat, and the fact that CloudSat only observes a relatively small fraction of an OMI field-of-view.

Joiner, J.↗

Top-of-the-Atmosphere Shortwave Flux Estimation from UV Observations: An Empirical Approach

Measurements of top of the atmosphere (TOA) radiation are essential to the understanding of Earth's climate. Clouds, aerosols, and ozone (0,) are among the most important agents impacting the Earth's short-wave (SW) radiation budget. There are several sensors in orbit that provide independent information related to the Earth's SW radiation budget. Having coincident information from these sensors is important for understanding their potential contributions. The A-train constellation of satellites provides a unique opportunity to analyze near-simultaneous data from several of these sensors. They include the Ozone Monitoring Instrument (OMI), on the NASA Aura satellite, that makes TOA hyper-spectral measurements from ultraviolet (UV) to visible wavelengths, and Clouds and the Earth's Radiant Energy System (CERES) instrument, on the NASA Aqua satellite, that makes broadband measurements in both the long- and short-wave. OMI measurements have been successfully utilized to derive the information on trace gases (e.g., 0 1, NO" and SO,), clouds, and absorbing aerosols. TOA SW fluxes are estimated using a combination of data from CERES and the Aqua MODerate-resolution Imaging Spectroradiometer (MODIS). In this paper, OMI retrievals of cloud/aerosol parameters and 0 1 have been collocated with CERES TOA SW flux retrievals. We use this collocated data to develop a neural network that estimates TOA shortwave flux globally over ocean using data from OMI and meteorological analyses. This input data include the effective cloud fraction, cloud optical centroid pressure (OCP), total-column 0" and sun-satellite viewing geometry from OMI as well as wind speed and water vapor from the Goddard Earth Observing System 5 Modern Era Retrospective-analysis for Research and Applications (GEOS-5 MERRA) along with a climatology of chlorophyll content. We train the neural network using a subset of CERES retrievals of TOA SW flux as the target output (truth) and withhold a different subset of the CERES data to be used for validation.

Gupta, P.↗

Observations over Hurricanes from the Ozone Monitoring Instrument

There is an apparent inconsistency between the total column ozone derived from the total ozone mapping spectrometer (TOMS) and aircraft observations within the eye region of tropical cyclones. The higher spectral resolution, coverage, and sampling of the ozone monitoring instrument (OMI) on NASA s Aura satellite as compared with TOMS allows for improved ozone retrievals by including estimates of cloud pressure derived simultaneously using the effects of rotational Raman scattering. The retrieved cloud pressures from OM1 are more appropriate than the climatological cloud-top pressures based on infrared measurements used in the TOMS and initial OM1 algorithms. We find that total ozone within the eye of hurricane Katrina is significantly overestimated when we use climatological cloud pressures. Using OMI-retrieved cloud pressures, total ozone in the eye is similar to that in the surrounding area. The corrected total ozone is in better agreement with aircraft measurements that imply relatively small or negligible amounts of stratospheric intrusion into the eye region of tropical cyclones.

Joiner, J.↗

Improving Total Column Ozone Retrievals by Using Cloud Pressures Derived from Raman Scattering in the UV

The higher spectral resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals, including estimates of tropospheric ozone. By default, the TOMS-like OMI total column ozone algorithm uses climatological cloud-top pressures based on infrared (IR) measurements to estimate the column ozone below the clouds. Alternatively, cloud pressure can be retrieved using atmospheric rotational Raman scattering with OMI. The retrieved cloud pressures should be more consistent with assumptions made in the total ozone algorithm. Here, we use data from the global ozone monitoring experiment (GOME) to estimate total ozone using both the IR-climatological and retrieved cloud pressures. The exceed approximately 15 DU. Use of the UV cloud pressure retrievals leads to a smoother distribution of ozone along a satellite track by reducing small spatial irregularities presumably caused by errors in the climatological cloud pressures.

Vasilkov, A.↗

Accuracy Assessments and Validation of an Expanded UV Irradiance Database from Satellite Total Ozone Mapping Spectrometer (TOMS)

The TOMS UV irradiance database (1978 to 2000) has been expanded to include 5 new products (noon irradiance at 305, 310, 324, and 380 nm, and noon erythemal-weighted irradiance), in addition to the existing erythemal daily exposure, which permit direct Comparisons with ground-based measurements from UV spectrometers. Sensitivity studies are conducted to estimate uncertainties of the new TOMS UV irradiance data due to algorithm apriori assumptions. Comparisons with Brewer spectrometers as well as filter radiometers are used to review of the sources of known errors. Inability to distinguish between snow and cloud cover using only TOMS data results in large errors in estimating surface UV using snow climatology. A correction is suggested for the case when the regional snow albedo is known from an independent source. The summer-time positive bias between TOMS UV estimations and Brewer measurements can be seen at all wavelengths. This suggests the difference is not related to ozone absorption effects. We emphasize that uncertainty of boundary layer UV aerosol absorption properties remains a major source of error in modeling UV irradiance in clear sky conditions. Neglecting aerosol absorption by the present TOMS algorithm results in a positive summertime bias in clear-sky UV estimations over many locations. Due to high aerosol variability the bias is strongly site dependent. Data from UV-shadow-band radiometer and well-calibrated CIMEL sun-sky radiometer are used to quantify the bias at NASA/GSFC site in Greenbelt, MD. Recommendations are given to enable potential users to better account for local conditions by combining standard TOMS UV data with ancillary ground measurements.

Krotkov, N. A.↗