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Engineering topics

Victor, G. A.

Publications and source records attributed to Victor, G. A..

Electron energy deposition in carbon monoxide gas

A comprehensive set of electron impact cross sections for carbon monoxide molecules is presented on the basis of the most recent experimental measurements and theoretical calculations. The processes by which energetic electrons lose energy in CO gas are analyzed with these input cross sections. The efficiencies are computed of vibrational and electronic excitation, dissociation, ionization, and heating for CO gas with fractional ionization ranging from 0% to 10%. The calculated mean energy per ion pair for neutral CO gas is 32.3 eV, which is in excellent agreement with the experimental value of 32.2 eV. It increases to 35.6 eV at a fractional ionization of 1%, typical of supernovae ejecta.

Liu, Weihong↗

Electron energy deposition in N2 gas

The processes by which energetic electrons lose energy in a weakly ionized gas of molecular nitrogen are analyzed and calculations are carried out taking into account the discrete nature of the excitation processes. The excitation, ionization, dissociation and heating efficiencies are computed for energies up to 200 eV absorbed in a gas with fractional ionizations varying from 10(-6) to 10(-2). Individual vibrational excitations up to the seventh vibrational level are presented.

Fox, J. L.↗

The 2145 A dayglow and the high altitude nitric oxide density

It is argued that dissociative photoionization of N2 by solar ultraviolet radiation at wavelengths shorter than 329 A is a large source of atmospheric N(+)(5S 0 2) ions which radiate at 2143.6 A and 2139.7 A. Calculations of the daytime production of N(+)(5S 0 2) ions are carried out. The band pass of the instrument used to measure the intensity of the NO gamma band at 2150 A contains the N(+) emission wavelengths and we suggest that the NO densities at high altitudes may be affected.

Victor, G. A.↗

Double photoionization and doubly charged ions in the thermosphere

It is shown that a plausible cross section for the double photoionization of oxygen at wavelengths less than 254 A accounts for the observed concentration of O(2+) ions in the thermosphere. Due to the lack of laboratory measurements, double ionization cross sections for atomic oxygen were estimated from laboratory measurements of the ionization cross sections of other species. For altitudes between 150 and 400 km, where O(2+) is assumed to be in photochemical equilibrium, calculations reveal a significantly greater contribution to O(2+) production by double ionization of O atoms than by single ionization of O(+) ions. The concentration of O(2+) ions, assuming a double photoionization creation mechanism and a large sink by charge exchange with molecular nitrogen, is calculated to agree with that measured by AE-C down to altitudes of 250 km.

Victor, G. A.↗

Photoemission in the second positive system of molecular nitrogen in the earth's dayglow

The results are presented of analyses of 3371-A profiles measured by the visible airglow experiment reported by Hayes et al. (1973). The measured emission rate profiles are presented as functions of the O and N2 densities determined simultaneously by means of an open source mass spectrometer. The experimental methods used are discussed along with the obtained results. The experimental data are compared with theoretical predictions. It is found that the 3371-A emission depends greatly on the O/N2 concentration ratio.

Kopp, J. P.↗

Discrepancy between electron heating and cooling rates derived from Atmosphere Explorer-C measurements

The present theory of electron temperature in the daytime mid-latitude ionosphere is tested by using Atmosphere Explorer-C measurements. In the region below 300 km, where a balance is expected between electron heating by photoelectron impact and electron cooling to ions and neutrals, we find an imbalance in which the cooling rate is consistently higher than the heating rate. The shapes of the altitude profiles also differ substantially. The cooling rate has a sharp peak at about 220 km, while the heating rate exhibits a broad peak about 30 km lower. Improved agreement is achieved at higher altitudes by using an oxygen fine structure loss rate smaller by a factor of 2, based on more recent collision strength calculations. Although this improves the overall agreement of the heating and cooling rates, the shape discrepancy remains, and the new cooling rate falls consistently below the heating rate below 200 km.

Brace, L. H.↗

The O I /5577-A wavelength/ airglow - Observations and excitation mechanisms

Analysis of the O I /5577-A wavelength/ airglow observations conducted on board the Atmosphere Explorer C satellite yields the following results when combined with simultaneous measurements of ion and neutral composition. A volume emission rate profile derived after sunset requires the production of an O(1S) atom in 8% of the O2(+) recombinations. Photoelectric impact on atomic oxygen and the dissociative recombination of O2(+) are important sources of O(1S) in the dayglow; however, the airglow measurements require a large additional production of O(1S) below 200 km in addition to these. The reaction N + O2(+) yielding NO(+) + O(1S) can provide the missing O(1S) source if the rate coefficient is near 2.5 times 10 to the minus 11th cu cm per sec.

Frederick, J. E.↗

Calculations of the equilibrium photoelectron flux in the thermosphere

Theoretical calculations of the equilibrium photoelectron fluxes in the upper atmosphere are reported. The calculations employ an accurate description of the photoelectron production processes and take explicit account of the discrete nature of the electron energy losses. The neutral atmospheric and ionospheric parameters were obtained from simultaneous measurements by the various instruments of the Atmosphere Explorer-C mission and the solar EUV fluxes measured on the same satellite were used. The photoelectron fluxes are calculated using a recent compilation of photon and electron cross section data. The results are in good agreement with the measured photoelectron fluxes over several orders of magnitude, though there are detailed differences at specific energies that have yet to be resolved.

Victor, G. A.↗

The absorption of energetic electrons by molecular hydrogen gas

The processes by which energetic electrons lose energy in a weakly ionized gas of molecular hydrogen are analyzed, and calculations are carried out taking into account the discrete nature of the excitation processes. The excitation, ionization, and heating efficiencies are computed for electrons with energies up to 100 eV absorbed in a gas with fractional ionizations up to 0.01, and the mean energy per pair of neutral hydrogen atoms is calculated.

Cravens, T. E.↗

Long-range interaction between metastable helium and ground state helium.

Results of analysis for the long-range interaction between ground state helium and triplet metastable helium, which shows that the long-range coefficient is the same for both gerade and ungerade states. Those terms which lead to the second term on the right hand side of a developed equation vanish through spin selection rules.

Victor, G. A.↗

Dipole properties of molecular hydrogen.

Molecular hydrogen electron scattering, optical refractivity and molecular anisotropy used to construct model dipole spectrum consistent with oscillator strength rules

Dalgarno, A.↗