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Viezee, W.

Publications and source records attributed to Viezee, W..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

In-Situ Measurements of HCN and CH3CN In the Pacific Troposphere: Sources, Sinks, and Comparisons with Satellite Observations

A new capillary gas chromatographic method using a Reduction Gas Detector was developed to measure HCN and CH3CN in the remote troposphere. This instrumental configuration was deployed for the very first time in the Trace-P field mission performed during the spring of 2001. The NASA DC-8 aircraft afforded an opportunity to measure HCN and CH3CN in polluted and pristine environments over the Pacific to a maximum altitude of 12 km. These are some of the first in situ measurements of the distribution of HCN and CH3CN over the Pacific. Large background concentrations of both nitriles were found to be present and significant variability was observed. The abundance of HCN and CH3CN was strongly impacted by outflow of pollution from Asia. In general there appeared to be a direct but nonlinear relationship between the mixing ratios of HCN and CH3CN. The vertical structure of these chemicals shows direct evidence of the presence of a significant oceanic sink. These observations will be compared with the column content HCN data from satellites and other available measurements. A large body of data have been collected and are being analyzed, both statistically and with the help of models, to better understand the sources and sinks of these nitriles. These results will be presented.

Singh, Hanwant B.↗
NASA NTRS2002

Measurements of Oxygenated Organic Chemicals In the Pacific Troposphere During TRACE-P: Higher Aldehydes (less than C(sub 1)), Their Sources, and Potential Role In Atmospheric Oxidation

Airborne measurements of a large number of oxygenated organics were carried out in the Pacific troposphere (to 12 km) in the Spring of 2001 (Feb. 24-April 10). Specifically these measurements included acetaldehyde, propanaldehyde, acetone, methylethyl ketone, methanol, ethanol, PAM and organic nitrates. Independent measurements of formaldehyde, peroxides, and tracers were also available. Highly polluted as well as pristine air masses were sampled. Oxygenated organics were abundant in the clean In troposphere and were greatly enhanced in the outflow regions from Asia. Extremely high concentrations of aldehydes could be measured in the troposphere. It is not possible to explain the large abundances of aldehydes in the background troposphere without invoking significant oceanic sources. A strong correlation between the observed mixing ratios of formaldehyde and acetaldehyde is present. We infer that higher aldehydes (such as acetaldehyde and propanaldehyde) may provide a large source of formaldehyde and sequester Cox throughout the troposphere. The atmospheric behavior of acetone, methylethyl ketone, and methanol is generally indicative of their common terrestrial sources with a Image contribution from biomass/biofuel burning. A vast body of data has been collected and it is being analyzed both statistically and with the help of models to better understand the role that oxygenated organics play in the atmosphere and to unravel their sources and sinks. These results will be presented.

Singh, Hanwant B.↗
NASA NTRS2002

In-Situ Measurements of HCN and CH3CN in the Pacific Troposphere: Sources, Sinks, and Comparisons with Spectroscopic Observations

We report the first in-situ measurements of hydrogen cyanide (HCN) and acetonitrile (CH3CN) from the Pacific troposphere (0-12 km) obtained during the NASA/Trace-P mission (Feb.-April, 2001). Mean HCN and CH3CN mixing ratios of 243 (+/-118) ppt and 149 (+/-56) ppt respectively, were measured. The in-situ observations correspond to a total HCN column of 4.4-4.9 x 10(exp 15) molec. cm(exp -2) and a CH3CN column of 2.8-3.0 x 10(exp 15) molec. cm(exp -2). This HCN column is in good agreement with available spectroscopic observations. The atmospheric concentrations of HCN and CH3CN were greatly influenced by outflow of pollution from Asia. There is a linear relationship between the mixing ratios of HCN and CH3CN, and in turn these are well correlated with tracers of biomass combustion (e.g. CH3Cl, CO). Relative enhancements with respect to known tracers of biomass combustion within selected plumes in the free troposphere, and pollution episodes in the boundary layer allow an estimation of a global biomass burning source of 0.8+/-0.4 Tg (N)/y for HCN and 0.4+/-0.1 Tg (N)/y for CH3CN. In comparison, emissions from automobiles and industry are quite small (<0.05 Tg (N)/y). The vertical structure of HCN and CH3CN indicated reduced mixing ratios in the MBL (Marine Boundary Layer). Using, a simple box model, the observed gradients across the top of the MBL are used to derive an oceanic flux of 6.7 x 10(exp -15) g (N) cm(exp -2)/s for HCN and 4.8 x 10(exp -15) g (N) cm(exp -2)/s for CH3CN. An air-sea exchange model is used to conclude that this flux can be maintained if the oceans are under-saturated in HCN and CH3CN by 23% and 17%, respectively. It is inferred that oceanic loss is a dominant sink for these nitrites, and they deposit some 1.3 Tg (N) of nitrogen annually to the oceans. Assuming reaction with OH radicals and loss to the oceans as the major removal processes, a mean atmospheric residence time of 4.7 months for HCN and 5.1 months for CH3CN is calculated. A global budget analysis shows that the sources and sinks of HCN and CH3CN are roughly in balance. There are indications that biogenic sources may also be present. Mechanisms involved in nitrate formation during combustion and removal in the oceans are poorly understood.

Singh, Hanwant B.↗
NASA NTRS2001

Global Distribution and Sources of Volatile and Nonvolatile Aerosol In the Remote Troposphere

Airborne measurements of aerosol (Condensation Nuclei, CN) and selected trace gases made in the areas of the North Atlantic Ocean during SONEX (October/November 1997), and the south tropical Pacific Ocean during PEM-Tropics A (September/October 1996) and PEM-Tropics B (March/April 1999) have been analyzed. Emphasis is on the interpretations of variations in the number densities of the fine (>17 nm) and ultrafine (>8 nm) CN in the upper troposphere (8-12 km). These data suggest that large number densities of highly volatile CN (10(exp 4)-10(exp 5)/cu cm) are present in the clean upper troposphere with highest values over the tropical1subtropical region. Through marine convection and long-distance horizontal transport, volatile CN originating from the tropical/subtropical regions can frequently impact the abundance of aerosol in the middle and upper troposphere at mid to high latitudes. Nonvolatile aerosol particles behave in a manner similar to tracers of combustion (CO) and photochemical pollution (PAN), implying a source from continental pollution of industrial or biomass burning origin. In the upper troposphere, we find that volatile and nonvolatile partials number densities are inversely correlated. An aerosol microphysical model is used to suggest that coagulation of fine volatile particles with fewer larger nonvolatile particles provides one possible mechanism for this relationship. It appears that nonvolatile particles, of principally anthropogenic origin,provide a highly efficient removal process for the fine volatile aerosol.

Singh, Hanwant B.↗
NASA NTRS1999

Biomass Burning Influences on the Composition of the Remote South Pacific Troposphere: Analysis Based on Observations from PEM Tropics-A

Airborne, in-situ measurements from PEM-Tropics-A (September/October 1996) are analyzed to show the presence of distinct pollution plumes in the middle-tropical troposphere of the remote South Pacific (10-30degS). These elevated plumes cause a relative maximum at about 5-7km attitude in the vertical distribution of primary and secondary species characteristic of fuel combustion and biomass burning (CO, C2H2, C2H6, CH3Cl, PAN, O3). Similar plumes were also observed at mid-latitudes in the middle troposphere during three flights east of New Zealand (40-45degS). In all, pollution plumes with CO larger than 100 ppb were observed 24 times on 7 separate flight days south of the equator. The observed plumes were generally embedded in very dry air. Ten-day back trajectory analysis supports the view that these originated from the biomass burning regions of South Africa (and South America) and were transported to the South Pacific along long-distance subsiding trajectories. The chemical composition of the southern Pacific troposphere analyzed from the PEM-Tropics-A data is compared with data from the tropical regions of the northern Pacific (PEM-West-A) and southern Atlantic (TRACE-A) during the same Sept/Oct time period. Sizable perturbations in the abundance of ozone and its key precursors, resulting from the transport of pollution originating from biomass burning sources, are observed in much of the Southern Hemispheric troposphere.

Singh, H. B.↗
NASA NTRS1992

Measurement of volatile organic chemicals at selected sites in California

Urban air concentrations of 24 selected volatile organic chemicals that may be potentially hazardous to human health and environment were measured during field experiments conducted at two California locations, at Houston, and at Denver. Chemicals measured included chlorofluorocarbons, halomethanes, haloethanes, halopropanes, chloroethylenes, and aromatic hydrocarbons. With emphasis on California sites, data from these studies are analyzed and interpreted with respect to variabilities in ambient air concentrations, diurnal changes, relation to prevailing meteorology, sources and trends. Except in a few instances, mean concentrations are typically between 0 and 5 ppb. Significant variabilities in atmospheric concentrations associated with intense sources and adverse meteorological conditions are shown to exist. In addition to short-term variability, there is evidence of systematic diurnal and seasonal trends. In some instances it is possible to detect declining trends resulting from the effectiveness of control strategies.

Singh, Hanwant B.↗
NASA NTRS1986

Global distribution of peroxyacetyl nitrate

Peroxyacetyl nitrate (PAN) atmospheric concentration samples were collected hourly from an ocean vessel 50 mi off the continental coast traveling from Seattle to Chile in 1984. Air concentration data for PAN and light hydrocarbons (LHC) were also taken by aircraft in the same period over Wyoming and Colorado and over the eastern Pacific. The PAN concentrations were higher and more variable in the Northern Hemisphere than in the Southern Hemisphere, increased with altitude, and were higher in the winter than in summer. The summer PAN concentrations were higher in the continental troposphere than in the marine troposphere. The results show that photochemical models of the atmosphere which do not account for the reaction between nonmethane hydrocarbons and PAN will probably overestimate the abundances of NO(x) and HNO3. The collection of further PAN concentration data is recommended as a means to characterizing the moderating role of PAN in the photochemistry of the troposphere.

Singh, H. B.↗
NASA NTRS1979

Relation between West Coastal rainfall and Nimbus 6 SCAMS liquid water data over the northeastern Pacific Ocean

A research study is described in which the application to rainfall prediction of cloud liquid water data obtained from the SCAMS experiment of Nimbus 6 is explored. The study area is the Pacific Northwest coast of the United States, where rainfall is produced by extratropical storms that approach from across the Pacific Ocean. SCAMS data related to cloud liquid water over the ocean, and coastal rainfall data, are analyzed for 20 different storm systems in the northeastern Pacific Ocean; these produced significant rainfall from Washington to central California during the period October 1975-March 1976. Results show that the distribution of storm-cloud water analyzed from the SCAMS data over the ocean foreshadows the distribution of coastal rainfall accumulated from the storm at a later time. It is concluded that passive microwave sensor measurements of cloud water over the ocean, when used in conjunction with numerical and other objective guidance, can be used to enhance the accuracy of predictions of coastal rainfall distribution. Limitations in the SCAMS measurements and in the data analysis and interpretation are noted.

Viezee, W.↗
NASA NTRS1979

Application of Nimbus-6 microwave data to problems in precipitation prediction for the Pacific west coast

The preliminary results of a research study that emphasizes the analysis and interpretation of data related to total precipitable water and nonprecipitating cloud liquid water obtained from NIMBUS-6 SCAMS are reported. Sixteen cyclonic storm situations in the northeastern Pacific Ocean that resulted in significant rainfall along the west coast of the United States during the winter season October 1975 through February 1976 are analyzed in terms of their distributions and amounts of total water vapor and liquid water, as obtained from SCAMS data. The water-substance analyses for each storm case are related to the distribution and amount of coastal precipitation observed during the subsequent time period when the storm system crosses the coastline. Concomitant precipitation predictions from the LFM are also incorporated. Techniques by which satellite microwave data over the ocean can be used to improve precipitation prediction for the Pacific West Coast are emphasized.

Viezee, W.↗
NASA NTRS1979

Relation between west coastal rainfall and Nimbus-6 SCAMS liquid water data over the northeastern Pacific Ocean

The application to rainfall prediction of cloud liquid water data obtained from the SCAMS experiment of Nimbus-6 is explored. The study area is the Pacific Northwest coast of the United States, where rainfall is produced by extratropical storms that approach from across the Pacific Ocean. The SCAMS data related to cloud liquid water over the ocean, and coastal rainfall data, are analyzed for 20 different storm systems in the northeastern Pacific Ocean; these produced significant rainfall from Washington to central California during the period October 1975 through March 1976. Results show that the distribution of storm cloud water analyzed from the SCAMS data over the ocean foreshadows the distribution of coastal rainfall accumulated from the storm at a later time. It is concluded that passive microwave sensor measurements of cloud water over the ocean, when used in conjunction with numerical and other objective guidance, can be used to enhance the accuracy of predictions of coastal rainfall distribution. Limitations in the SCAMS measurements and in the data analysis and interpretation are noted.

Viezee, W.↗
NASA NTRS1976

Lidar observations of the stratospheric aerosol - California, October 1972 to March 1974

The paper describes the results of a series of 30 observations of stratospheric aerosol made with a ground-based lidar on the North Pacific Coast during a period relatively uninfluenced by major volcanic penetrations and displaying a relative temporal minimum in particulate content. The objectives were to provide a record of aerosol behavior during this intervolcanic period, to compare this behavior with that revealed by previous studies using a variety of techniques, and to provide comparative data on the stratospheric aerosol by conducting joint lidar and aircraft observations. Determination of scattering profile ratios from lidar signal profiles and analysis of experimental errors are described. Analysis of the data shows that significant temporal variability of the aerosol was observed, probably of nonvolcanic origin. Much of the variability was confined to the 23-30 km height region, above the major peak in scattering ratio. The evidence is that this is not due to influxes of extraterrestrial material. Vertical motions of the centroid of the scattering ratio peak were recorded during the 1973 stratospheric warming, and illustrate the value of lidar's ability to monitor temporal variations of vertical structure.

Russell, P. B.↗
NASA NTRS1976

Lidar measurements of the post-fuego stratospheric aerosol

Fifteen lidar observations of the stratospheric aerosol were made between February and November 1975. All observations revealed the greatly increased particulate backscattering that followed the eruption of the volcano Fuego in October 1974. Vertical structure consisted initially of multiple layers, which later merged to form a single, broader peak. Essentially all of the increased scattering was confined to altitudes below 20 km. Hence, aerosol layer centroids in 1975 were typically several km below their altitude prior to the eruption. Radiative and thermal consequences of the measured post-Fuego layer were computed using several recently published models. The models predict a temperature increase of several K at the altitude of the layer, caused by the infrared absorption bands of the sulfuric acid particles. The surface temperature decrease predicted by the models is considerably smaller than 1 K, partly because of the small optical thickness of the volcanic layer, and partly because of its short residence time relative to the earth-ocean thermal response time.

Russell, P. B.↗
NASA NTRS1974

Lidar measurements of stratospheric aerosols over Menlo Park, California, October 1972 - March 1974

During an 18-month period, 30 nighttime observations of stratospheric aerosols were made using a ground based ruby lidar located near the Pacific coast of central California (37.5 deg. N, 122.2 deg. W). Vertical profiles of the lidar scattering ratio and the particulate backscattering coefficient were obtained by reference to a layer of assumed negligible particulate content. An aerosol layer centered near 21 km was clearly evident in all observations, but its magnitude and vertical distribution varied considerably throughout the observation period. A reduction of particulate backscattering in the 23- to 30-km layer during late January 1973 appears to have been associated with the sudden stratospheric warming which occurred at that time.

Russell, P. B.↗
NASA NTRS1973

Lidar measurements of the variability of stratospheric particulates

Laser radar observations were made to provide information on the distribution of particulate material in the stratosphere between 33,000 feet and 98,000 feet. The observations are part of a program to assess the impact of climatic changes that may result from perturbation of the upper atmosphere by a world high-altitude aircraft fleet. Results are presented as vertical profiles of the scattering ratio and the aerosol backscattering ratio.

Russell, P. B.↗
NASA NTRS1973

An investigation of mountain waves with lidar observations.

In March and April of 1969 and 1970, lidar (laser radar) observations of the atmospheric structure were made in the lee of the Sierra Nevada during the occurrence of mountain lee waves. Rawinsonde ascents and, on some occasions, research aircraft flights supported the lidar observations. The objective of the program was to explore the applicability of the lidar technique to atmospheric turbulence detection. The observations demonstrate that a ground-based lidar can delineate significant features of the atmospheric flow pattern by monitoring echoes from concentrations of particulate matter that characterize the airflow structure in the form of either visible or subvisible clouds and dust.

Viezee, W.↗
NASA NTRS1972

A sample computation of kinematic properties from cloud motion vectors.

Distributions of relative vorticity and balanced height have been computed from the cloud velocities associated with the cloud structure of an extratropical cyclone over the continental United States during a three-day period in March 1970. Cloud motions are assigned either to a 'mid-level,' or to a 'high level.' Derived vorticity and balanced height are compared with concurrent National Meteorological Center (NMC) analyses and also with similar kinematic quantities obtained from rawins at three constant-pressure levels. The computations of relative vorticity using mid-level cloud motion vectors show encouraging results. Patterns of computed cyclonic vorticity are related to the development, location, and movement of the surface cyclone. The analyses suggest that the 'mid-level' corresponds best to the 700-mb level. The vorticity analysis from the 'high-level' motion vectors presented difficulties.

Viezee, W.↗