Engineering topics

Walker, Anne

Publications and source records attributed to Walker, Anne.

4 records

DOE OSTI2023

Defect-Promoted Ni-Based Layer Double Hydroxides with Enhanced Deprotonation Capability for Efficient Biomass Electrooxidation

Ni-based hydroxides are promising electrocatalysts for biomass oxidation reactions, supplanting the oxygen evolution reaction (OER) due to lower overpotentials while producing value-added chemicals. The identification and subsequent engineering of their catalytically active sites are essential to facilitate these anodic reactions. Herein, the proportional relationship between catalysts’ deprotonation propensity and Faradic efficiency of 5-hydroxymethylfurfural (5-HMF)-to-2,5 furandicarboxylic acid (FDCA, FEFDCA) is revealed by thorough density functional theory (DFT) simulations and atomic-scale characterizations, including in situ synchrotron diffraction and spectroscopy methods. The deprotonation capability of ultrathin layer-double hydroxides (UT-LDHs) is regulated by tuning the covalency of metal (M)-oxygen (O) motifs through defect site engineering and selection of M 3+ co-chemistry. NiMn UT-LDHs show an ultrahigh FE FDCA of 99% at 1.37 V versus reversible hydrogen electrode (RHE) and retain a high FE FDCA of 92.7% in the OER-operating window at 1.52 V, about 2× that of NiFe UT-LDHs (49.5%) at 1.52 V. Ni–O and Mn–O motifs function as dual active sites for HMF electrooxidation, where the continuous deprotonation of Mn–OH sites plays a dominant role in achieving high selectivity while suppressing OER at high potentials. The results showcase a universal concept of modulating competing anodic reactions in aqueous biomass electrolysis by electronically engineering the deprotonation behavior of metal hydroxides, anticipated to be translatable across various biomass substrates.

36 MATERIALS SCIENCE↗

NASA NTRS2011

The Canadian Experiment for Freeze/Thaw in 2012 or 2013 CanEx-FT12 or FT13

General objectives of the experiment are: Pre-launch Calibration/Validation of SMAP Freeze/Thaw products and retrieval algorithms and rehearsal for Soil Moisture Active-Passive (SMAP) post launch validation. The basis of the radar freeze-thaw measurement is the large shift in dielectric constant and backscatter (dB) between predominantly frozen & thawed conditions. The Dielectric constant of liquid water varies with frequency, whereas that of pure ice is constant

permafrost↗

NASA NTRS2000

BOREAS HYD-4 Areal Snow Course Data

The Boreal Ecosystem-Atmosphere Study (BOREAS) Hydrology (HYD)-4 team focused on collecting data during the 1994 winter focused field campaign (FFCW) to improve the understanding of winter processes within the boreal forest. Knowledge of snow cover and its variability in the boreal forest is fundamental if BOREAS is to achieve its goals of understanding the processes and states involved in the exchange of energy and water. The development and validation of remote sensing algorithms will provide the means to extend the knowledge of these processes and states from the local to the regional scale. A specific thrust of the hydrology research is the development and validation of snow cover algorithms from airborne passive microwave measurements. Airborne remote sensing data (gamma, passive microwave) were acquired along a series of flight lines established in the vicinity of the BOREAS study areas. Ground snow surveys were conducted along selected sections of these aircraft flight lines. These calibration segments were typically 10-20 km in length, and ground data were collected at one to two kilometer intervals. The data are provided in tabular ASCII files. The HYD-04 areal snow course data are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).

Hall, Forrest G.↗

NASA NTRS2000

BOREAS HYD-4 Standard Snow Course Data

The Boreal Ecosystem-Atmosphere Study (BOREAS) Hydrology (HYD)-4 work was focused on collecting data during the winter focused field campaign (FFC-W) to improve the understanding of winter processes within the boreal forest. Knowledge of snow cover and its variability in the boreal forest is fundamental if BOREAS is to achieve its goals of understanding the processes and states involved in the exchange of energy and water. The development and validation of remote sensing algorithms will provide the means to extend the knowledge of these processes and states from the local to the regional scale. A specific thrust of the research is the development and validation of snow cover algorithms from airborne passive microwave measurements. Snow surveys were conducted at special snow courses throughout the 1993/94, 1994/95, 1995/96, and 1996/97 winter seasons. These snow courses were located in different boreal forest land cover types (i.e., old aspen, old black spruce, young jack pine, forest clearing, etc.) to document snow cover variations throughout the season as a function of different land cover. Measurements of snow depth, density, and water equivalent were acquired on or near the first and fifteenth of each month during the snow cover season. The data are provided in tabular ASCII files. The HYD-4 standard snow course data are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).

Metcalfe, John R.↗