Search NASA⌕ Search

Engineering topics

Wang, Zhangwei

Publications and source records attributed to Wang, Zhangwei.

Oxidation resistant high-entropy alloys

Disclosed herein are new face-centered cubic (f.c.c.) high-entropy alloys with compositions (in atomic %) of Fe.sub.aNi.sub.bMn.sub.cAl.sub.dCr.sub.eC.sub.f where a is between 37-43 atomic %, b is between 8-14 atomic %, c is between 32-38 atomic %, d is 4.5-10.5 atomic %, e is between 2.5-9 atomic % and f is between 0-2 atomic %. The undoped alloy has strength of 159 MPa and 40% elongation to failure, but the doped, carbon-containing alloy having 1.1 atomic percent carbon has yield strength of 360 MPa, an ultimate tensile strength (UTS) of 1200 MPa and 50% elongation to failure at room temperature. At 700.degree. C., the yield strength is 214 MPa with 24% elongation to failure. Thus, the present alloy may replace austenitic stainless steels in applications where better strength is needed at both room temperature and elevated temperature in an oxidation resistant alloy.

Baker, Ian↗

Microband induced plasticity and the temperature dependence of the mechanical properties of a carbon-doped FeNiMnAlCr high entropy alloy

Highlights: • A superior fcc HEA with the strength of 1.5 GPa at the cryogenic condition is developed. • The strengthening mechanisms of HEAs at different temperatures are clarified. • The temperature dependence of MBIP effect is revealed. - Abstract: The uniaxial mechanical properties of the high entropy alloy (HEA) Fe{sub 40.4}Ni{sub 11.3}Mn{sub 34.8}Al{sub 7.5}Cr{sub 6} doped with 1.1 at.% C have been determined for both the as-cast and recrystallized states at temperatures from 77 to 973 K. Very high yield strengths were obtained at 77 K of 928 MPa for the as-cast HEA and 1037 MPa for the recrystallized HEA. The yield strength decreased sharply to 293 K and more slowly to 973 K, where it was ~200 MPa [11] in both conditions. The lattice friction stress, which results from the increase of the Peierls barrier, was the major contributor to the large yield strength at 77 K. On the other hand, the grain boundaries lose their strengthening ability at a high temperature, which largely accounts for the sharp drop in yield strength of the fine-grained (5 μm) recrystallized HEA at 973 K. The elongation to failure was highest at 293 K and 673 K with the lowest values at 77 K. Transmission electron microscopy was used to study the effects of temperature on the deformation mechanisms of the HEAs, especially the temperature dependence of the microband-induced plasticity effect. At temperatures ranging from 77 K to 673 K microbands form in the as-cast HEA, while dislocation clusters were observed in the recrystallized HEA over this temperature range. Only tangled dislocations were found at 973 K for both the as-cast and recrystallized HEA due to thermally-activated deformation.

36 MATERIALS SCIENCE↗

Effect of boron and carbon addition on microstructure and mechanical properties of the aged gamma-prime strengthened alumina-forming austenitic alloys [Effect of boron and carbon addition on microstructure and mechanical properties of the aged gamma-prime alumina-forming austenitic alloys]

Here, the goal of this work was to understand the effects of aging at 800 °C on the microstructures and mechanical properties of two recently-developed AFA stainless steels based on Fe-14Cr-32Ni-3Nb-3Al-2Ti (wt.%), one of which contained small additions of boron and carbon. To that end both the size distributions and growth kinetics of the B2, Laves phase, L1 2 precipitates present were quantified. While the lattice parameter, morphology, size and coarsening behavior of the L1 2 precipitates was the same in both AFA alloys, the B and C enhanced the grain boundary coverage by both Laves phase and B2-NiAl precipitates, but suppressed their coarsening. These interstitial additions also suppressed the formation of twins and discontinuous precipitation, which were observed in the B and C-free material. It is shown that the yield strength at 700 °C is largely controlled by the size of the L1 2 precipitates, with the largest strengthening effect obtained after aging for 2.4 h for both AFA alloys. Longer aging time led to a loss of strength mainly due to the coarsening of the L1 2 precipitates.

36 MATERIALS SCIENCE↗

The effect of carbon on the microstructures, mechanical properties, and deformation mechanisms of thermo-mechanically treated Fe 40.4 Ni 11.3 Mn 34.8 Al 7.5 Cr 6 high entropy alloys

We investigated the effects of cold rolling followed by annealing on the mechanical properties and dislocation substructure evolution of undoped and 1.1 at. % carbon-doped Fe 40.4 Ni 11.3 Mn 34.8 Al 7.5 Cr 6 high entropy alloys (HEAs). X-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and atom probe tomography (APT) were employed to characterize the microstructures. The as-cast HEAs were coarse-grained and single phase f.c.c., whereas the thermo-mechanical treatment caused recrystallization (to fine grain sizes) and precipitation (a B2 phase for the undoped HEA; and a B2 phase, and M 23 C 6 and M 7 C 3 carbides for the C-doped HEA). Carbon, which was found to have segregated to the grain boundaries using APT, retarded recrystallization. The reduction in grain size resulted in a sharp increase in strength, while the precipitation, which produced only a small increase in strength, probably accounted for the small decrease in ductility for both undoped and C-doped HEAs. For both undoped and C-doped HEAs, the smaller grain-sized material initially exhibited higher strain hardening than the coarse-grained material but showed a much lower strain hardening at large tensile strains. Wavy slip in the undoped HEAs and planar slip in C-doped HEAs were found at the early stages of deformation irrespective of grain size. At higher strains, dislocation cell structures formed in the 19 μm grain-sized undoped HEA, while microbands formed in the 23 μm grain-sized C-doped HEA. Conversely, localized dislocation clusters were found in both HEAs at the finest grain sizes (5 μm). The inhibition of grain subdivision by the grain boundaries and precipitates lead to the transformation from regular dislocation configurations consisting of dislocation-cells and microbands to irregular dislocation configurations consisting of localized dislocation clusters, which further account for the decrease in ductility. Our investigation of the formation mechanism and strain hardening of dislocation cells and microbands could benefit future structural material design.

36 MATERIALS SCIENCE↗

The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe 40.4 Ni 11.3 Mn 34.8 Al 7.5 Cr 6 high entropy alloys

A systematic study of the effects of up to 1.1 at. % carbon on the mechanical properties and evolution of the dislocation substructure in a series of a high entropy alloys (HEA) based on Fe40.4Ni11.3Mn34.8Al7.5Cr6 is presented. Transmission electron microscopy (TEM), synchrotron X-ray diffraction (XRD) and atom probe tomography (APT) were used to show that all the alloys are single-phase f.c.c. random solid solutions. The lattice constant, determined from synchrotron XRD measurements, increases linearly with increasing carbon concentration, which leads to a linear relationship between the yield strength and the carbon concentration. The dislocation substructures, as determined by a TEM, show a transition from wavy slip to planar slip and, at higher strains, and from cell-forming structure (dislocations cells, cell blocks and dense dislocation walls) to non-cell forming structure (Taylor lattice, microbands and domain boundaries) with the addition of carbon, features related to the increase in lattice friction stress. The stacking fault energy (measured via weak-beam imaging of the separation of dislocation partials) decreases with increasing carbon content, which also contributes to the transition from wavy slip to planar slip. The formation of non-cell forming structure induced by carbon leads to a high degree of strain hardening and a substantial increase in the ultimate tensile strength. The consequent postponement of necking due to the high strain hardening, along with the plasticity accommodation arising from the formation of microbands and domain boundaries, result in an increase of ductility due to the carbon addition. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Dislocation structures↗

Effect of Ti content on the microstructure and mechanical behavior of (Fe 36 Ni 18 Mn 33 Al 13 ) 100–x Ti x high entropy alloys

The microstructure and mechanical properties studies of a series of two-phase f.c.c./B2 (ordered b.c.c.) lamellar-structured, high entropy alloys (HEA) Fe 36 Ni 18 Mn 33 Al 13 Ti x with x up to 6 at. % Ti have been investigated. X-ray microanalysis in a TEM showed that the Ti resided mostly in the B2 phase. The lamellar spacing decreased significantly with increasing Ti content from 1.56 μm for the undoped alloy to 155 nm with an addition of 4 at. % Ti, leading to a sharp increase in room-temperature yield strength,σ y , from 270 MPa to 953 MPa, but with a concomitant decrease in ductility from 22% elongation to 2.3%. Annealing at 1173 K for 20 h greatly increased the lamellar spacing of Fe 36 Ni 18 Mn 33 Al 13 Ti 4 to 577 nm, producing a corresponding decrease in σy to 511 MPa. The yield strengths of all the doped alloys decreased significantly when tensile tested at 973 K with a concomitant increase in ductility due to softening of the B2 phase. The fracture mode changed from cleavage at room temperature to a ductile dimple-type rupture at 973 K. Lastly, the results are discussed in terms of the Hall-Petch-type relationship.

36 MATERIALS SCIENCE↗