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Wang, Zhuo

Publications and source records attributed to Wang, Zhuo.

Machine learning unifies flexibility and efficiency of spinodal structure generation for stochastic biomaterial design

Abstract Porous biomaterials design for bone repair is still largely limited to regular structures (e.g. rod-based lattices), due to their easy parameterization and high controllability. The capability of designing stochastic structure can redefine the boundary of our explorable structure–property space for synthesizing next-generation biomaterials. We hereby propose a convolutional neural network (CNN) approach for efficient generation and design of spinodal structure—an intriguing structure with stochastic yet interconnected, smooth, and constant pore channel conducive to bio-transport. Our CNN-based approach simultaneously possesses the tremendous flexibility of physics-based model in generating various spinodal structures (e.g. periodic, anisotropic, gradient, and arbitrarily large ones) and comparable computational efficiency to mathematical approximation model. We thus successfully design spinodal bone structures with target anisotropic elasticity via high-throughput screening, and directly generate large spinodal orthopedic implants with desired gradient porosity. This work significantly advances stochastic biomaterials development by offering an optimal solution to spinodal structure generation and design.

59 BASIC BIOLOGICAL SCIENCES↗

Modulation of North Atlantic Polar Low Activity and Associated Flow Patterns by Sudden Stratospheric Warmings

Abstract Polar lows (PLs) are intense maritime mesoscale cyclones that can pose hazards to coastal communities and marine operation in the Arctic. This study examines the impacts of sudden stratospheric warmings (SSWs) on PL activity in the subarctic North Atlantic. The 20 days following SSWs are characterized by tropospheric circulation anomalies resembling the negative phase of the North Atlantic Oscillation. PL activity decreases significantly over the Labrador Sea, which can be attributed to the infrequent occurrence of low static stability and strong environmental baroclinicity, as well as reduced surface turbulent heat fluxes. These results suggest that a skillful prediction of SSWs can improve the extended-range forecast of PL activity over the Labrador Sea. For the Nordic seas, the results imply that the spatial structure of an SSW event is important for the PL modulation through different tropospheric circulation patterns. Situations with increased PL frequency in the Nordic seas are characterized by SSWs centered close to northern Greenland occurring over a smaller area, and a tropospheric response featuring enhanced cold-air outbreaks over the Norwegian Sea. Conversely, PL activity is suppressed over the Nordic seas when the SSW favors the formation of a tropospheric anticyclone above Greenland and Scandinavia. Significance Statement This study investigates the relationships between polar lows (PLs) and sudden stratospheric warmings (SSWs) over the subarctic North Atlantic. A better understanding of the effect of SSWs on PL development has the potential to improve extended-range forecasts of PLs. It is shown that SSWs are responsible for the significantly suppressed regional PL activity over the Labrador Sea, suggesting that SSWs can serve as a predictor for the extended-range forecast of PLs over this region. Following SSW events, the thermodynamic state of atmosphere becomes more stable over the Labrador Sea and hinders the convective development of PLs. For the northern Nordic seas, the impacts of SSWs on PL activity are sensitive to the spatial structure of stratospheric warming.

Chang, Chuan-Chieh↗

Enhanced Electrocatalytic Hydrogen Evolution Activity in Single-Atom Pt-Decorated VS 2 Nanosheets

Enhancing catalytic activity by decorating noble metals in catalysts provides an opportunity for promoting the electrocatalytic hydrogen evolution reaction (HER) application. However, there are few systematic studies on regulating the structures of noble metals in catalytic materials and investigating their influence on HER. Herein, Pt catalysts with different structures including single atoms (SAs), clusters, and nanoparticles well-controllably anchored on VS 2 nanosheets through a cost-effective optothermal method are reported, and their HER performance is studied. The most efficient Pt-decorated VS 2 catalyst (with both Pt SAs and clusters) delivers an overpotential of 77 mV at 10 mA cm –2 , close to that of Pt/C (48 mV). However, the optimal mass activity of Pt (normalizing to Pt content) is obtained from only SA Pt-decorated VS 2 (i.e., 22.88 A mg Pt –1 at 200 mV) and is 12 times greater than that of the Pt/C (1.87 A mg Pt –1 ), attributed to the greatly enhanced Pt utilization. Additionally, the theoretical simulations reveal that Pt SA decoration makes the adsorption free energy of H* closer to the thermoneutral value and improves the charge-transfer kinetics, significantly enhancing HER activity. Furthermore, this work offers a pathway to prepare the desired catalyst based on synergy of Pt structures and VS 2 and reveals the intrinsic mechanism for enhancing catalytic activity, which is important for HER applications.

36 MATERIALS SCIENCE↗

Data Assimilation Enhancements to Air Force Weather’s Land Information System

The United States Air Force (USAF) has a proud and storied tradition of enabling significant advancements in the area of characterizing and modeling land state information. 557th Weather Wing (557 WW; DoD’s Executive Agent for Land Information) provides routine geospatial intelligence information to warfighters, planners, and decision makers at all echelons and services of the U.S. military, government and intelligence community. 557 WW and its predecessors have been home to the DoD’s only operational regional and global land data analysis systems since January 1958. As a trusted partner since 2005, Air Force Weather (AFW) has relied on the Hydrological Sciences Laboratory at NASA/GSFC to lead the interagency scientific collaboration known as the Land Information System (LIS). LIS is an advanced software framework for high performance land surface modeling and data assimilation of geospatial intelligence (GEOINT) information.

Wegiel, Jerry↗

Application of the Marsupial Paradigm to Tropical Cyclone Formation from Northwestward-Propagating Disturbances

A wave-tracking algorithm is developed for northwestward-propagating waves that, on occasion, play a role in tropical cyclogenesis over the western oceans. To obtain the Lagrangian flow structure, the frame of reference is translated obliquely at the same propagation speed with the precursor disturbance. Trajectory analysis suggests that streamlines in the obliquely translated frame of reference can be used to approximate flow trajectories. The algorithm was applied to Super Typhoon Nakri (2008), Tropical Cyclone Erika (2009), and a few other examples. Diagnoses of meteorological analyses and satellite-derived moisture and precipitation fields show that the marsupial framework for tropical cyclogenesis in tropical easterly waves is relevant also for northwestward-propagating disturbances as are commonly observed in the tropical western Atlantic, the Gulf of Mexico, and the western North Pacific. Finally, it is suggested that analysis of the global model data and satellite observations in the marsupial framework can provide useful guidance on early tropical cyclone advisories.

Wang, Zhuo↗

Genesis of Pre-Hurricane Felix (2007): The Role of the Easterly Wave Critical Layer - Part 1

The formation of pre Hurricane Felix (2007) in a tropical easterly wave is examined in a two-part study using the Weather Research and Forecasting (WRF) model with a high-resolution nested grid configuration that permits the representation of cloud system processes. The simulation commences during the wave stage of the precursor African easterly-wave disturbance. Here the simulated and observed developments are compared, while in Part II of the study various large-scale analyses, physical parameterizations, and initialization times are explored to document model sensitivities. In this first part the authors focus on the wave/vortex morphology, its interaction with the adjacent intertropical convergence zone complex, and the vorticity balance in the neighborhood of the developing storm. Analysis of the model simulation points to a bottom-up development process within the wave critical layer and supports the three new hypotheses of tropical cyclone formation proposed recently by Dunkerton, Montgomery, and Wang. It is shown also that low-level convergence associated with the ITCZ helps to enhance the wave signal and extend the "wave pouch" from the jet level to the top of the atmospheric boundary layer. The region of a quasi-closed Lagrangian circulation within the wave pouch provides a focal point for diabatic merger of convective vortices and their vortical remnants. The wave pouch serves also to protect the moist air inside from dry air intrusion, providing a favorable environment for sustained deep convection. Consistent with the authors' earlier findings, the tropical storm forms near the center of the wave pouch via system-scale convergence in the lower troposphere and vorticity aggregation. Components of the vorticity balance are shown to be scale dependent, with the immediate effects of cloud processes confined more closely to the storm center than the overturning Eliassen circulation induced by diabatic heating, the influence of which extends to larger radii.

Wang, Zhuo↗