Drift velocities, diffusion coefficients, and temperatures of photoions in argon, nitrogen, and oxygen
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Engineering topics
Publications and source records attributed to Warneck, P..
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Photoions produced in methanol and formaldehyde by radiation in the spectral region 450-1150 A were analyzed mass spectrometrically, and their relative yields were determined as a function of wavelength. First ionization potentials were determined, and the ion yield curves were interpreted in terms of ionization processes in conjunction with other data. Fragment ions were detected on mass numbers of 31, 30, 29, 15, and 14 for methanol, and 29, 2, and 1 for formaldehyde. The associated appearance potentials were determined and were used to calculate heats of formation of the ions CH2OH(+) and HCO(+), and the radicals CH3, CH2, and HCO.
Photoionization mass spectrometry, considering application to appearance potentials determination, ion-neutral reactions and gas analysis
Improved spectrometer for gas analysis lessens the intensity problem that occurs in obtaining dispersed ultraviolet radiation. A filter, consisting of a selectively transmitting gas cell, a thin film or mirror, or a predispersing grating, alleviates problems of interference from higher-order spectral lines and from scattered ultraviolet light.
Analytical photoionization mass spectrometer with argon gas filter between light source and monochrometer
Mass spectrometry of gaseous trace contaminants
Trace gas analysis using photoionization mass spectrometer
Photoionization source with a vacuum UV monochromator is used in ion reaction kinetics. Monochromator passes only the photon energies near the threshold of the selected ionization process. Absence of electron impact alleviates creation of different type ions that result in ion fragmentation.
Photodetachment cross sections measured for selected negative ions present in upper atmospheric D-region
Major ions in chemi-ionization of hydrocarbon flames determined for heats of formation by photoionization mass spectrometer
Photodetachment of electrons from nitrogen dioxide ions by light in violet portion of visible spectrum, noting wavelength dependence
Techniques for use in mass spectrometry of gaseous trace contaminants
Sulfur trioxide production in photolysis of sulfur dioxide at 1849 angstroms, noting oxygen addition effect on quantum yield
Ultraviolet filter and monochromator for mass spectrometer employing photoionization source
Helium ions reactions with nitrogen and oxygen investigated by photoionization mass spectrometry, discussing rate coefficients
Ionospheric ion-neutral reactions studied by photoionization mass spectrometer, noting temperature independent reactions
Photolysis of mixtures of oxygen with nitrous oxide, nitrogen, and carbon dioxide, and relative reaction rates of 1 D oxygen atoms with admixed gases
Chemiluminescent reactions of atomic oxygen with carbonyl sulfide and hydrogen sulfide in flow system as function of reaction time and reactant concentrations