Search NASASearch

Engineering topics

Warneck, P.

Publications and source records attributed to Warneck, P..

At least 19 records

Photoionization of methanol and formaldehyde

Photoions produced in methanol and formaldehyde by radiation in the spectral region 450-1150 A were analyzed mass spectrometrically, and their relative yields were determined as a function of wavelength. First ionization potentials were determined, and the ion yield curves were interpreted in terms of ionization processes in conjunction with other data. Fragment ions were detected on mass numbers of 31, 30, 29, 15, and 14 for methanol, and 29, 2, and 1 for formaldehyde. The associated appearance potentials were determined and were used to calculate heats of formation of the ions CH2OH(+) and HCO(+), and the radicals CH3, CH2, and HCO.

Warneck, P.

Improved photoionization mass spectrometer

Improved spectrometer for gas analysis lessens the intensity problem that occurs in obtaining dispersed ultraviolet radiation. A filter, consisting of a selectively transmitting gas cell, a thin film or mirror, or a predispersing grating, alleviates problems of interference from higher-order spectral lines and from scattered ultraviolet light.

Poshchenrieder, W. P.

Photoionization mass spectrometer

Photoionization source with a vacuum UV monochromator is used in ion reaction kinetics. Monochromator passes only the photon energies near the threshold of the selected ionization process. Absence of electron impact alleviates creation of different type ions that result in ion fragmentation.

Warneck, P.

Photodetachment of NO sub 2.

Photodetachment of electrons from nitrogen dioxide ions by light in violet portion of visible spectrum, noting wavelength dependence

Warneck, P.