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West, Brian

Publications and source records attributed to West, Brian.

Solubility and volume swell of fuel system elastomers with ketone blends of E10 gasoline and blendstock for oxygenate blending (BOB)

The compatibility of key infrastructure elastomers with five ketone molecules was assessed via solubility studies and volume swell measurements. The elastomer materials included two fluorocarbons, six acrylonitrile butadiene rubbers (NBRs), and one each of fluorosilicone, neoprene, polyurethane, styrene butadiene rubber (SBR), and silicone. The ketone molecules included acetone, 2-butanone, 2-pentanone, 2-nonanone, and cyclopentanone. The ketones were added to gasoline containing 10% ethanol (E10) and a blendstock for oxygenate blending (BOB) in levels ranging from 0% to 30% by volume. The elastomers were exposed for 4 weeks in each test fluid. The solubility was modeled using Hansen solubility parameters and the volume change was determined for each material and test fuel. In general, the volume swell increased with ketone content and corresponded well to the predicted solubilities. In most cases, the highest level of swelling occurred with added cyclopentanone and acetone, while 2-nonanone produced the lowest levels of volume expansion. The chain length of the straight ketones was found to affect the volume swell behavior as volume expansion decreased with increasing chain length. This behavior is attributed to the reduction in polarity and hydrogen bonding with chain length. Neoprene, SBR, and silicone exhibited poor compatibility with the ketone molecules at all blend levels. Fluorocarbon and fluorosilicone also showed poor compatibility but may be suitable for use as static seals in very low blend levels with 2-nonanone. The results were more mixed for polyurethane and the NBRs. In general, better compatibility (low volume swell) was observed for mixtures containing BOB than for E10. This is due to the lower polarity and hydrogen bonding of the BOB.

10 SYNTHETIC FUELS↗

Elastomer Swell Behavior in 1-Propanol, Diisobutylene, Cyclopentanone, and a Furan Mixture Blended in E10 and a Blendstock for Oxygenate Blending (BOB)

The compatibility of four potential bio-derived blendstock molecules with infrastructure elastomers was determined by measuring the volume change following exposure. The blendstock molecules included 1-propanol, diisobutylene, cyclopentanone, and a furan mixture. The elastomers included two fluorocarbons, six nitrile rubbers (NBRs), and one each of fluorosilicone, neoprene, polyurethane, and silicone. The elastomers were exposed to the fuel molecules as blends ranging from 0 to 30 vol.% in both a blendstock for oxygenate blending (BOB) formulation and an E10 fuel. Silicone exhibited excessive swelling in each test fuel, while the other elastomers showed good compatibility (low swell) with diisobutylene, 1-propanol, and the furan mixture when BOB was used as the base fuel. The E10 base fuel produced high (>30%) swell in neoprene, polyurethane, and some nitrile rubbers. In most cases diisobutylene produced the least amount of volume expansion. In contrast, the addition of cyclopentanone produced unacceptably high swelling in each elastomer and is not considered suitable for use with these fuels. Analysis of the results showed that the swelling behavior is predominantly due to the polarity of the elastomer and test fuels.

03 NATURAL GAS↗

Top Ten Blendstocks Derived From Biomass For Turbocharged Spark Ignition Engines

More efficient engines enabled by better fuels derived from biomass could increase the fuel economy of the light duty (LD) fleet by 10% over current technology and planned developments. This report identifies top LD boosted spark ignition (BSI) biofuel candidates for further development and commercialization identified using a fuel property basis. The BSI merit function was used to evaluate the performance of candidate bio-blendstocks in improving engine efficiency. This report is aimed at biofuel researchers looking to better understand the efficiency implications of biofuels under development, as well as engine researchers who are interested in future biofuels with properties that enable more efficient engine design and operation.

09 BIOMASS FUELS↗

NASA's Approach to Additive Manufacturing Certification: Methodologies for Qualification of Additively Manufactured Aerospace Hardware

NASA's Approach to Additive Manufacturing Certification: Methodologies for Qualification of Additively Manufactured Aerospace Hardware. This course is intended to provide guidance and practical methodologies on how to establish a qualified process and deliver certifiable hardware per the requirements in MSFC-STD-3716 and MSFC-SPEC-3717. Course Objectives: Reinforce a basic understanding of AM processes; Become familiar with MSFC-STD-3716 and MSFC-SPEC-3717 requirements for metallic spaceflight hardware; Appreciate integrated path to Qualification and Certification; Understand products necessary to get you to Qualification and Certification.

West, Brian↗

U.S. Department of Energy Fuels & Lubricants Project on Lubricant Technology - Innovation, Discovery, Design, and Engineering (Final Report)

In 2016, the Vehicle Technologies Office (VTO) of the Department of Energy (DOE) issued a solicitation for the AOP Lab Call research in FY2017 on a number of topics related to vehicles. Topic 6A of the Lab Call focused on research related to advanced lubricants: '...(in) support of the lubricants program goal to, by 2020, demonstrate novel formulations for powertrain and driveline lubricants, compatible with new and legacy vehicles, to achieve at least a 4 percent real-world fuel economy improvement.' Argonne National Laboratory (ANL) in collaboration with Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) was awarded a 3-year multilab project on 'Lubricant Technology - Innovation, Discovery, Design, and Engineering.' Research on the project began in FY2017 at the three laboratories with industry participation; however, in FY2018, the project was terminated due to budgetary constraints. The following is the final report for the project and highlights progress made during the first year of research. The report is divided into sections that highlight the following: goals, objectives, milestones and deliverables; project highlights; outreach - publications, conferences, and reports; milestones accomplished; research progress.

30 DIRECT ENERGY CONVERSION↗

Development of a Cold Start Fuel Penalty Metric for Evaluating the Impact of Fuel Composition Changes on SI Engine Emissions Control

The U.S. Department of Energy’s Co-Optimization of Fuels and Engines initiative (Co-Optima) aims to simultaneously transform both transportation fuels and engines to maximize performance and energy efficiency. Researchers from across the DOE national laboratories are working within Co-Optima to develop merit functions for evaluating the impact of fuel formulations on the performance of advanced engines. The merit functions relate overall engine efficiency to specific measurable fuel properties and will serve as key tools in the fuel/engine co-optimization process. This work focused on developing a term for the Co-Optima light-duty boosted spark ignition (SI) engine merit function that captures the effects of fuel composition on emissions control system performance. For stoichiometric light-duty SI engines, the majority of NOx, NMOG, and CO emissions occur during cold start, before the three-way catalyst (TWC) has reached its “light-off” temperature. This light-off temperature depends on the exhaust composition, which changes with fuel formulation. Thus, the time to achieve light-off, and therefore the cold start emissions, depends on fuel composition. Since the time to reach light-off must be minimized to meet emissions regulations, modern vehicles employ cold start strategies that intentionally release fuel energy into the engine exhaust to heat the TWC above the light-off temperature as quickly as possible. The fuel penalty associated with catalyst heating during cold start provides a link between fuel properties, emissions performance, and engine efficiency. This paper describes the derivation of the Co-Optima SI engine merit function term for emissions control, which is based on the cold start fuel penalty for catalyst heating and the catalytic light-off temperature for a particular fuel composition. It also discusses the process used for extracting cold start fuel penalties from chassis dynamometer data sets previously collected at ORNL. The form of the merit function term is simple, but it is only intended as a starting point for comparing the potential impacts of changes in fuel formulation on emissions control system performance.

Pihl, Josh↗

Exploring Engine Oil Reactivity Effects on End Gas Knock in a Direct-Injection Spark Ignition Engine

An experimental study was conducted in a direct-injection (DI) spark-ignited engine to determine the extent to which oil reactivity impacts combustion phasing and knock propensity. Three engine oils were examined: a baseline 20W30 oil from conventional base stock, a 5W30 oil from a synthetic base stock, and a jet oil from a hindered ester base stock. The engine was operated at a constant fueling rate of 24.7 mg/injection for two engine speed conditions (1500 and 2000 rpm) using two cam profile conditions (high and low lift), for a total of four operating conditions. Spark timing sweeps were conducted at each of the four operating conditions. Results were analyzed for an engine oil impact on combustion phasing, cycle-to-cycle variability, combustion duration, knock propensity, and knock intensity. No correlation between engine oil type and any of these performance metrics could be identified. Measurements showed that the oil consumption rate for this engine is low and comparable to engines compliant with U.S. Tier 1 and Tier 2 emissions standards, consuming 1.4 g/kg of fuel consumed (150 g for 20 hours of operation). Finally, the lack of a correlation between the oil type and engine performance can be attributed to this low level of oil consumption, resulting in very little interaction between the oil and the combustion chamber contents.

42 ENGINEERING↗

Fuel Consumption Sensitivity of Conventional and Hybrid Electric Light-Duty Gasoline Vehicles to Driving Style

Aggressive driving is a very important topic for many reasons, one of which is higher energy used per unit distance traveled, potentially accompanied by an elevated production of greenhouse gases and other pollutants. Examining a large data set of self-reported fuel economy (FE) values revealed that the dispersion of FE values is quite large and is larger for hybrid electric vehicles (HEVs) than for conventional gasoline vehicles. This occurred despite the fact that the city and highway FE ratings for HEVs are generally much closer in value than for conventional gasoline vehicles. A study was undertaken to better understand this and better quantify the effects of aggressive driving, including reviewing past aggressive driving studies, developing and exercising a new vehicle energy model, and conducting a related experimental investigation. The vehicle energy model focused on the limitations of regenerative braking in combination with varying levels of driving-style aggressiveness to show that this could account for greater FE variation in an HEV compared to a similar conventional vehicle. A closely matched pair of gasoline-fueled sedans, one an HEV and the other having a conventional powertrain, was chosen for both modeling and chassis dynamometer experimental comparisons. Results indicate that the regenerative braking limitations could be a main contributor to the greater HEV FE variation under the range of drive cycles considered. Finally, the complete body of results gives insight into the range of fuel use penalties that results from aggressive driving and why the variation can be larger on a percent basis for an HEV compared to a similar conventional vehicle, while the absolute fuel use penalty for aggressive driving is generally larger for conventional vehicles than HEVs.

33 ADVANCED PROPULSION SYSTEMS↗

Modified Thermoresponsive Hyperbranched Polymers for Improved Viscosity and Enhanced Lubricity of Engine Oils

The manuscript captures the chronological succession of the molecular design progression through multiple architectures and topologies of the polymeric viscosity index improvers and their rheology bench test performance. Tribology testing was also performed on selected analogs and their friction and wear was evaluated. Finally, a top performing polymer was selected for engine testing, scaled-up, and its rheological performance in a complete formulation was assessed. The engine performance of the viscosity index improver was examined against an industry-established baseline.

02 PETROLEUM↗

Additive Manufacturing for Affordable Rocket Engines

Additive manufacturing (also known as 3D printing) technology has the potential to drastically reduce costs and lead times associated with the development of complex liquid rocket engine systems. NASA is using 3D printing to manufacture rocket engine components including augmented spark igniters, injectors, turbopumps, and valves. NASA is advancing the process to certify these components for flight. Success Story: MSFC has been developing rocket 3D-printing technology using the Selective Laser Melting (SLM) process. Over the last several years, NASA has built and tested several injectors and combustion chambers. Recently, MSFC has 3D printed an augmented spark igniter for potential use the RS-25 engines that will be used on the Space Launch System. The new design is expected to reduce the cost of the igniter by a factor of four. MSFC has also 3D printed and tested a liquid hydrogen turbopump for potential use on an Upper Stage Engine. Additive manufacturing of the turbopump resulted in a 45% part count reduction. To understanding how the 3D printed parts perform and to certify them for flight, MSFC built a breadboard liquid rocket engine using additive manufactured components including injectors, turbomachinery, and valves. The liquid rocket engine was tested seven times in 2016 using liquid oxygen and liquid hydrogen. In addition to exposing the hardware to harsh environments, engineers learned to design for the new manufacturing technique, taking advantage of its capabilities and gaining awareness of its limitations. Benefit: The 3D-printing technology promises reduced cost and schedule for rocket engines. Cost is a function of complexity, and the most complicated features provide the largest opportunities for cost reductions. This is especially true where brazes or welds can be eliminated. The drastic reduction in part count achievable with 3D printing creates a waterfall effect that reduces the number of processes and drawings, decreases the amount of touch labor required, and increases reliability. When certification is achieved, NASA missions will be able to realize these benefits.

West, Brian↗

Rack assembly for mounting solar modules

A rack assembly is provided for mounting solar modules over an underlying body. The rack assembly may include a plurality of rail structures that are arrangeable over the underlying body to form an overall perimeter for the rack assembly. One or more retention structures may be provided with the plurality of rail structures, where each retention structure is configured to support one or more solar modules at a given height above the underlying body. At least some of the plurality of rail structures are adapted to enable individual rail structures o be sealed over the underlying body so as to constrain air flow underneath the solar modules. Additionally, at least one of (i) one or more of the rail structures, or (ii) the one or more retention structures are adjustable so as to adapt the rack assembly to accommodate solar modules of varying forms or dimensions.

14 SOLAR ENERGY↗

Interfacing Ada and other languages

Interfacing two separately developed compilers is a complex task. The complexity arises because few design standards exist for compiler development. This, coupled with the many complicated design decisions inherent in compiler construction, usually guarantees noncompatibility. The interface subroutine which would link the two different run time environments would resolve as many of the dissimilarities as possible. The differences that could not be resolved would be responsible for the restrictions placed on the interface. Albeit restrictions would exist, the resulting interface may be well worthwhile.

Baffes, Paul↗