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NASA NTRS1990

Background, current status, and prognosis of the ongoing slush hydrogen technology development program for the NASP

Among the Hydrogen Projects at the NASA Lewis Research Center (NASA LeRC), is the task of implementing and managing the Slush Hydrogen (SLH2) Technology Program for the United States' National AeroSpace Plane Joint Program Office (NASP JPO). The objectives of this NASA LeRC program are to provide verified numerical models of fluid production, storage, transfer, and feed systems and to provide verified design criteria for other engineered aspects of SLH2 systems germane to a NASP. The pursuit of these objectives is multidimensional, covers a range of problem areas, works these to different levels of depth, and takes advantage of the resources available in private industry, academia, and the U.S. Government. A summary of the NASA LeRC overall SLH2 program plan, is presented along with its implementation, the present level of effort in each of the program areas, some of the results already in hand, and the prognosis for the effort in the immediate future.

Dewitt, R. L.↗

NASA NTRS1986

Vacuum chamber pressure effects on thrust measurements of low Reynolds number nozzles

Tests were conducted to investigate the effect of vacuum facility pressure on the performance of small thruster nozzles. Thrust measurements of two converging-diverging nozzles with an area ratio of 140 and an orifice plate flowing unheated nitrogen and hydrogen were taken over a wide range of vacuum facility pressures and nozzle throat Reynolds numbers. In the Reynolds number range of 2200 to 12,000 there was no discernable viscous effect on thrust below an ambient to total pressure ratio of 1000. In nearly all cases, flow separation occurred at a pressure ratio of about 1000. This was the upper limit for obtaining an accurate thrust measurement for a conical nozzle with an area ratio of 140.

Sovey, J. S.↗

NASA NTRS1986

Performance and endurance tests of a multipropellant resistojet for space station auxiliary propulsion

This paper presents the results of an effort to demonstrate the technology readiness of a long-life multipropellant resistojet for space station auxiliary propulsion. Experiments were performed to evaluate the compatibility of grain-stabilized platinum tubes at temperatures up to 1400 deg C in environments of CO2, CH4, NH3, H2O, and H2. All samples tested showed extrapolated lifetimes in excess of 10,000 hr based on 10 percent mass loss as end-of-life. However, samples tested in an ammonia atmosphere at 1400 deg C showed severe pitting, which raised concerns about the compatibility of grain-stabilized platinum with ammonia-containing atmospheres. Additional tests showed that reducing the metal temperature to about 900 deg C (+ or - 100 deg C) significantly reduced this adverse effect.

Morren, W. E.↗

NASA NTRS1986

Performance and endurance tests of a multipropellant resistojet for space station auxiliary propulsion

This paper presents the results of an effort to demonstrate the technology readiness of a long-life multipropellant resistojet for space station auxiliary propulsion. Experiments were performed to evaluate the compatibility of grain-stabilized platinum tubes at temperatures up to 1400 deg C in environments of CO2, CH4, NH3, H2O, and H2. All samples tested showed extrapolated lifetimes in excess of 10,000 hr based on 10 percent mass loss as end-of-life. However, samples tested in an ammonia atmosphere at 1400 deg C showed severe pitting, which raised concerns about the compatibility of grain-stabilized platinum with ammonia-containing atmospheres. Additional tests showed that reducing the metal temperature to about 900 deg C (+ or - 100 deg C) significantly reduced this adverse effect.

Morren, W. E.↗

NASA NTRS1985

Compatibility of grain-stabilized platinum with candidate propellants for resistojets

An examination is conducted into the suitability of grain-stabilized Pt as a resistojet thruster material for Space Station auxiliary propulsion. A series of 1000-hour tests was conducted in CO2, H2, and NH3 at 1400 C; another series was conducted at 500 C in CH4 for the same duration. SEM, Auger electron microscopy, and depth profiling analysis were used to determine the effects of propellants on the material surface as well as to evaluate possible material contamination and possible grain growth. Carbon deposition is noted on the surface of Pt/Y2O3 and Pt/ZrO2 in both the CO2 and CH4 environments.

Whalen, M. V.↗

NASA NTRS1985

Vacuum chamber pressure effects on thrust measurements

Tests were conducted to investigate the effect of vacuum facility pressure on the performance of small thruster nozzles. Thrust measurements of two converging-diverging nozzles with an area ratio of 140 and an orifice plate flowing unheated nitrogen and hydrogen were taken over a wide range of vacuum facility pressures and nozzle throat Reynolds numbers. In the Reynolds number range of 2200 to 12,000 there was no discernable viscous effect on thrust below an ambient to total pressure ratio of 1000. In nearly all cases, flow separation occurred at a pressure ratio of about 1000. This was the upper limit for obtaining an accurate thrust measurement for a conical nozzle with an area ratio of 140.

Sovey, J. S.↗

NASA NTRS1985

Compatibility experiments of facilities, materials, and propellants for electrothermal thrusters

Experiments were performed to determine the compatibility of materials and propellants for electro-thermal thrusters. Candidate propellants for resistojet propulsion include carbon dioxide, methane, hydrogen, ammonia, and hydrazine. The materials being examined are grain stabilized platinum for resistojets for space station and rhenium for high performance resistojets for satellites. Heater mass loss and deterioration of materials were evaluated. A coiled tube of platinum, with yttria dispersed throughout the base material to inhibit grain growth, was tested in carbon dioxide at 1300 C for 2000 hr. Post-test examination indicated the platinum-yttria heater would last over 100,000 hr with less than 10 percent mass loss. Short-term compatibility tests were conducted to test the integrity of the platinum-yttria in hydrogen, methane, carbon dioxide/methane mixtures and ammonia environments. In each of these 100 hr tests, the platinum-yttria mass change indicated a minimum coil life of 100,000 hr. Facility related effects were investigated in materials tests using rhenium heated to high temperatures. Vacuum facility water reduction was monitored using a mass spectrometer. In vacuum environments obtained using only diffusion pumping and those obtained with the assistance of cryogenic equipment there were mass gains in the rhenium heaters. These mass gains were the result of the high amount of oxygen and water contained in the gas. Propellant purity and preferred test facility environments are discussed.

Whalen, M. V.↗

NASA NTRS1985

Vacuum chamber pressure effects on thrust measurements of low Reynolds number nozzles

Tests were conducted to investigate the effect of vacuum facility pressure on the performance of small thruster nozzles. Thrust measurements of two converging-diverging nozzles with an area ratio of 140 and an orifice plate flowing unheated nitrogen and hydrogen were taken over a wide range of vacuum facility pressures and nozzle throat Reynolds numbers. In the Reynolds number range of 2200 to 12 000 there was no discernable viscous effect on thrust below an ambient to total pressure ratio of 1000. In nearly all cases, flow separation occurred at a pressure ratio of about 1000. This was the upper limit for obtaining an accurate thrust measurement for a conical nozzle with an area ratio of 140.

Sovey, J. S.↗

NASA NTRS1985

Compatibility experiments of facilities, materials, and propellants for electrothermal thrusters

Experiments were performed to determine the compatibility of materials and propellants for electro-thermal thrusters. Candidate propellants for resistojet propulsion include carbon dioxide, methane, hydrogen, ammonia, and hydrazine. The materials being examined are grain stabilized platinum for resistojets for Space station and rhenium for high performance resistojets for satellites. Heater mass loss and deterioration of materials were evaluated. A coiled tube of platinum, with yttria dispersed throughout the base material to inhibit grain growth, was tested in carbon dioxide at 1300 C for 2000 hr. Post-test examination indicated the platinum-yttria heater would last over 100 000 hr with less than 10 percent mass loss. Short-term compatibility tests were conducted to test the integrity of the platinum-yttria in hydrogen, methane, carbon dioxide/methane mixtures and ammonia environments. In each of these 100 hr tests, the platinum-yttria mass change indicated a minimum coil life of 100 000 hr. Facility related effects were investigated in materials tests using rhenium heated to high tempertures. Vacuum facility water reduction was monitored using a mass spectrometer. In vacuum environments obtained using only diffusion pumping and those obtained with the assistance of cryogenic equipment there were mass gains in the rhenium heaters. These mass gains were the result of the high amount of oxygen and water contained in the gas. Propellant purity and preferred test facility environments are discussed.

Whalen, M. V.↗

NASA NTRS1985

Compatibility of grain-stabilized platinum with candidate propellants for resistojets

Resistojets are candidates for space station auxiliary propulsion, and should be characterized by both long life and multipropellant operations, requirements limited by available materials. Grain stabilized platinum is examined for use as a resistojet thruster material. Use of platinum in other applications indicates it can be used at moderately high temperatures for extended periods of time. Past results indicate that grain-stabilized platinum should be sufficiently inert in candidate propellant environments. Therefore, compatibility of platinum-yttria (P/Y2O3) and platinum-zirconia (Pt/ZrO2) with carbon dioxide, methane, hydrogen and ammonia is examined. A series of 1000 hr tests in CO2, H2, and NH3 is conducted at 1400 C and a series of 1000 hr tests in CH4 is conducted at about 500 C. Scanning electron microscopy, Auger electron spectroscopy and depth profiling analysis are then used to determine the effects of propellants on the material surface, to evaluate possible material contamination and to evaluate grain growth. The results indicate that there is carbon deposition on the surface of the Pt/Y2O3 and Pt/ZrO2 in both the CO2 and CH4 environments. In the H2 environment, the Pt/Y2O3 and Pt/ZrO2 specimen surfaces are roughened. After exposure to the NH3 environment, the Pt/Y2O3 and Pt/ZrO2 are roughened and pitted over the entire heated area with some pitted areas along the grain boundaries. SEM photos show grain growth in cross-sectional views of all the Pt/Y2O3 samples and the Pt/ZrO2 samples, except that tested in methane. Mass loss measurements indicate that Pt/Y2O3 and Pt/ZrO2 would last in excess of 200,000 hr in each propellant environment. However, in NH3 both Pt/Y2O3 and Pt/ZrO2 are severely pitted, with voids up to 50 percent into the material. Pt/Y2O3 and Pt/ZrO2 are not recommended for high temperature service in NH3.

Whalen, M. V.↗