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Whitcanack, L. D.

Publications and source records attributed to Whitcanack, L. D..

36 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

An Update on the Performance of Li-Ion Rechargeable Batteries on Mars Rovers

NASA's Mars Rovers, Spirit and Opportunity have been exploring the surface of Mars for the last thirty months, far exceeding the primary mission life of three months, performing astounding geological studies to examine the habitability of Mars. Such an extended mission life may be attributed to impressive performances of several subsystems, including power subsystem components, i.e., solar array and batteries. The novelty and challenge for this mission in terms of energy storage is the use of lithium-ion batteries, for the first time in a major NASA mission, for keeping the rover electronics warm, and supporting nighttime experimentation and communications. The use of Li-ion batteries has considerably enhanced or even enabled these rovers, by providing greater mass and volume allocations for the payload and wider range of operating temperatures for the power subsystem and thus reduced thermal management. After about 800 days of exploration, there is only marginal change in the end-of discharge (EOD) voltages of the batteries or in their capacities, as estimated from in-flight voltage data and corroborated by ground testing of prototype batteries. Enabled by such impressive durability from the Li-ion batteries, both from a cycling and calendar life stand point, these rovers are poised to extend their exploration well beyond 1000 sols, though other components have started showing signs of decay. In this paper, we will update the performance characteristics of these batteries on both Spirit and Opportunity.

low temperatures↗
NASA NTRS2005

Ground testing of the Li-ion batteries in support of JPL's 2003 Mars Exploration Rover Mission

In early 2004, JPL successfully landed two Rovers, named Spirit and Opportunity, on the surface of Mars after traveling > 300 million miles over a 6-7 month period. In order to operate for extended duration on the surface of Mars, both Rovers are equipped with rechargeable Lithium-ion batteries, which were designed to aid in the launch, correct anomalies during cruise, and support surface operations in conjunction with a triple-junction deployable solar arrays. The requirements of the Lithium-ion battery include the ability to provide power at least 90 sols on the surface of Mars, operate over a wide temperature range (-20(deg)C to +4O(deg)C), withstand long storage periods (e.g., cruise period), operate in an inverted position, and support high currents (e.g., firing pyro events). In order to determine the viability of meeting these requirements, ground testing was performed on a Rover Battery Assembly Unit (RBAU), consisting of two 8-cell 8 Ah lithium-ion batteries connected in parallel. The RBAU upon which the performance testing was performed is nearly identical to the batteries incorporated into the two Rovers currently on Mars. The testing performed includes, (a) performing initial characterization tests (discharge capacity at different temperatures), (b) simulating the launch conditions, (c) simulating the cruise phase conditions (including trajectory corrections), (d) simulating the entry, decent, and landing pulse load profile (if required to support the pyros) (e) simulating the Mars surface operation mission simulation conditions, as well as, (f) assessing performance capacity loss and impedance characteristics as a function of temperature and life. As will be discussed, the lithium-ion batteries (fabricated by LithiodYardney, Inc.) were demonstrated to far exceed the requirements defined by the mission, and are projected to support an extended mission (> 2 years) with margin to spare.

Li-ion batteries↗
NASA NTRS2004

Lithium-Ion rechargeable batteries on Mars Rover

NASA's Mars Rovers, Spirit and Opportunity, have been roving on the surface of Mars, capturing impressive images of its terrain and analyzing the drillings from Martian rocks, to answer the ever -puzzling questions of life beyond Earth and origin of our planets. These rovers are being enabled by an advanced rechargeable battery system, lithium-ion, for the first time on a space mission of this scale, for keeping the rover electronics warm, and for supporting nighttime experimentation and communications. These rover Li-ion batteries are characterized by their unique low temperature capability, in addition to the usual advantages associated with Li-ion chemistry in terms of mass, volume and energy efficiency. To enable a rapid insertion of this advanced Li-ion chemistry into flight missions, we have performed several performance assessment studies on several prototype cells over the last few years. These tests mainly focused primarily on the long-term performance characteristics, such as cycling and storage, as described in our companion paper. In addition, various tests have been performed on MER cells and engineering and proto flight batteries; under conditions relevant to these missions. For example, we have examined the performance of the cells in: a) an inverted orientation, as during integration and launch, and b) conditions of low rate discharge, between 3.0-2.5 V to support the mission clock. Likewise, we have determined the impedance of the proto-flight Rover battery assembly unit in detail, with a view to asses whether a current-limiting resistor would be unduly stressed, in the event of a shorting induced by a failed pyro. In this paper we will describe these studies in detail, as well as the performance of Li-ion batteries in Spirit and Opportunity rovers, during cruise and on Mars.

2003 Mars Exploration Rover (MER)↗
NASA NTRS2004

Lithium-sulfur dioxide batteries on Mars rovers

NASA's 2003 Mars Exploration Rover (MER) missions, Spirit and Opportunity, have been performing exciting surface exploration studies for the past six months. These two robotic missions were aimed at examining the presence of water and, thus, any evidence of life, and at understanding the geological conditions of Mars, These rovers have been successfully assisted by primary lithium-sulfur dioxide batteries during the critical entry, descent, and landing (EDL) maneuvers. These batteries were located on the petals of the lander, which, unlike in the Mars Pathfinder mission, was designed only to carry the rover. The selection of the lithium-sulfur dioxide battery system for this application was based on its high specific energy and high rate discharge capability, combined with low heat evolution, as dictated by this application. Lithium-sulfur dioxide batteries exhibit voltage delay, which tends to increase at low discharge temperatures, especially after extended storage at warm temperatures, In the absence of a depassivation circuit, as provided on earlier missions, e.g., Galileo, we were required to depassivate the lander primary batteries in a unique manner. The batteries were brought onto a shunt-regulated bus set at pre-selected discharge voltages, thus affecting depassivation during constant discharge voltages. Several ground tests were preformed, on cells, cell strings and battery assembly with five parallel strings, to identify optimum shunt voltages and durations of depassivation. We also examined the repassivation of lithium anodes, subsequent to depassivation. In this paper, we will describe these studies, in detail, as well as the depassivation of the lander flight batteries on both Spirit and Opportunity rover prior to the EDL sequence and their performance during landing on Mars.

Lithium-SO2 batteries↗
NASA NTRS2004

Validation of Lithium-ion cell technology for JPL's 2003 Mars Exploration Rover Mission

n early 2004 JPL successfully landed two Rovers, named Spirit and Opportunity, on the surface of Mars after traveling >300 million miles over a 6-7 month period. In order to operate for extended duration on the surface of Mars, both Rovers are equipped with rechargeable Lithium-ion batteries, which were designed to aid in the launch, correct anomalies during cruise, and support surface operations in conjunction with a triple-junction deployable solar arrays. The requirements of the Lithium-ion battery include the ability to provide power at least 90 sols on the surface of Mars, operate over a wide temperature range (-20 C to +40 C), withstanding long storage periods (e.g., cruise period), operate in an inverted position, and support high currents (e.g., firing pyro events). In order to determine the viability of Lithium-ion technology to meet these stringent requirements, a comprehensive test program was implemented aimed at demonstrating the performance capability of prototype cells fabricated by Lithion, Inc. (Yardney Technical Products, Inc.). The testing performed includes, determining the (a) room temperature cycle life, (b) pulse capability as a function of temperature, (e) self-discharge and storage characteristics mission profile capability, (f) cycle life under mission simulation conditions, (g) impedance characteristics, (h) impact of cell orientation, and (i) performance in 8-cell engineering batteries. As will be discussed, the Lithium-ion prototype cells and batteries were demonstrated to meet, as well as, exceed the requirements defined by the mission.

2003 Mars Exploration Rover (MER)↗
NASA NTRS2004

High power, gel polymer lithium-ion cells with improved low temperature performance for NASA and DoD applications

Both NASA and the U.S. Army have interest in developing secondary energy storage devices that are capable of meeting the demanding performance requirements of aerospace and man-portable applications. In order to meet these demanding requirements, gel-polymer electrolyte-based lithium-ion cells are being actively considered, due to their promise of providing high specific energy and enhanced safety aspects.

high power li-ion batteries↗
NASA NTRS2003

Li-ion cells for terrestrial robots

SAFT prismatic wound 5 Ahr MP series cells were evaluated for potential application in a lithium ion battery designed for Tactical Mobile Robots (TMR). In order to satisfy battery design requirements, a 10 Ahr battery containing two parallel 8-cell strings was proposed. The proposed battery has a weight and volume of approximately 3.2kg and 1.6 liters, respectively. Cell qualification procedures include initial characterization, followed by charge/discharge cycling at 100% DOD with intermittent EIS measurements at various state of charge. Certain cells were also subjected to extreme operational temperatures for worst-case analysis. Excellent specific energy (>130 Whr/kg) was obtained with initial characterization cycles. Even at abusive thermal conditions, the cell capacity fade was less than Ahr after 300 cycles. Rate characterization showed good cell discharge behavior with minimal decrease in capacity. At various state of charge, impedance measurements suggest that the cathode play a more significant role in capacity. At various state of charge impedance measurements suggest that the cathode play a more significant role in capacity fade than the anode.

robots↗
NASA NTRS2003

Mars Mission Surface Operation Simulation Testing of Lithium-Ion Batteries

The objectives of this program are to 1) Assess viability of using lithium-ion technology for future NASA applications, with emphasis upon Mars landers and rovers which will operate on the planetary surface; 2) Support the JPL 2003 Mars Exploration Rover program to assist in the delivery and testing of a 8 AHr Lithium-Ion battery (Lithion/Yardney) which will power the rover; 3) Demonstrate applicability of using lithium-ion technologyfor future Mars applications: Mars 09 Science Laboratory (Smart Lander) and Future Mars Surface Operations (General). Mission simulation testing was carried out for cells and batteries on the Mars Surveyor 2001 Lander and the 2003 Mars Exploration Rover.

Smart, M. C.↗
NASA NTRS2002

Improved low temperature performance of lithium ion cells with quaternary carbonate-based electrolytes

In order to enable future missions involving the exploration of the surface of Mars with Landers and Rovers, NASA desires long life, high energy density rechargeable batteries which can operate well at very low temperature (down to 40(deg)C). Lithium-ion technology has been identified as being the most promising chemistry, due to high gravimetric and volumetric energy densities, as well as, long life characteristics. However, the state-of-art (SOA) technology is not sufficient to meet the needs of many applications that require excellent low temperature capabilities. To further improve this technology, work at JF'L has been focused upon developing electrolytes that result in lithium-ion cells with wider temperature ranges of operation. These efforts have led to the identification of a number of ternary and quaternary, all carbonate-based electrolytes that have been demonstrated to result in improved low temperature performance in experimental three-electrode MCMB carbon/LiNio.sCoo.zOz cells. A number of electrochemical characterization techniques were performed on these cells (i.e., Tafel polarization measurements, linear polarization measurements, and electrochemical impedance spectroscopy (EIS)) to further enhance our understanding of the performance limitations at low temperature. The most promising electrolyte formulations, namely 1 .O M LiPF6EC+DEC+DMC+EMC (1 : 1: 1 :2 v/v) and 1 .O M LiPF6 EC+DEC+DMC+EMC (1 : 1 : 1 :3 v/v), were incorporated into SAFT prototype DD-size (9 Ahr) lithium- cells for evaluation. A number of electrical tests were performed on these cells, including rate characterization as a function of temperature, cycle life characterization at different temperatures, as well as, many mission specific characterization test to determine their viability to enable future missions to Mars. Excellent performance was observed with the prototype DD-size cells over a wide temperature range (-50 to 4OoC), with high specific energy being delivered at very low temperatures (i.e, over 95 WHrKg being delivered at 40(deg)C using a C/10 discharge rate).

Li-ion low temperature electrolytes↗
NASA NTRS2002

Lithium-ion cell technology demonstration for future NASA applications

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to their attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including planetary orbiters, rovers and landers. For example, under the Mars Surveyor Program MSP 01 lithium-ion batteries were developed by Lithion (each being 28 V, 25 Ah, 8-cells. and 9 kg) and fully qualified prior to mission cancellation. In addition to the requirement of being able to supply at least 90 cycles on the surface of Mars, the battery demonstrated operational capability (both charge and discharge) over a large temperature range (-2O'C to +4OoC), with tolerance to non-operational excursions to -30nd 50Currently, JPL is implementing lithium-ion technology on the 2003 Mars Exploration Rover (MER), which will be coupled with a solar array. This mission has similar performance requirements to that of the 2001 Lander in that high energy density and a wide operating temperature range are necessitated. In addition to planetary rover and lander applications, we are also engaged in determining the viability of using lithium-ion technology for orbiter applications that require exceptionally long life (>20,000 cydes at partial depth of discharge). To assess the viabili of lithium-ion cells for these applications, a number of performance characterization tests have been performed (at the cell and battery level) on state-of-art prototype lihium- ion cells, induding: assessing the cycle life performance (at varying DODs), life characteristics at extreme temperatures (< -10nd >+4OoC), rate capability as a function of temperature (-30' to 4OoC), pulse capability, self-discharge and storage characteristics, as well as, mission profile capability. This paper will describe the current and future NASA missions that are considering lithium ion batteries and will contain results of the cell testing conducted to-date to validate the technology for these missions.

lithium-ion batteries Mars landers Mars rovers↗