Engineering topics

Wilson, D. Bruce

Publications and source records attributed to Wilson, D. Bruce.

10 records

NASA NTRS2000

The Presence of Excess Oxygen in Burning Metallic Materials

Early work on burning of iron rods under conditions of the ATSM/NASA flammability test showed that there was excess oxygen, that is, above stoichiometric requirements for iron(III) oxide, present in the molten product during burning. Since that work, this phenomenon has been confirmed for burning under microgravity conditions and has been observed for a wide range of metals under burning conditions of a single micro-drop at ambient pressures and 20-second microgravity tests under pressurized oxygen-enriched conditions. This paper reviews these experimental observations and discusses the possible thermodynamic analysis for the metals iron, aluminum, and cobalt. The excess oxygen in the burning molten iron oxide was represented as combined to form a series of ferrite ions. For aluminum the excess oxygen is represented as a bridging species and a similar explanation is postulated for the cobalt system.

Wilson, D. Bruce↗

NASA NTRS2000

Flammability: A Review and Analysis

With its founding in 1975, Committee G-4 of the American Society for Testing and Materials (ASTM) embarked on the process of defining the flammability of metallic materials in oxygen-enriched atmospheres. In this process, they are joined by the National Aeronautics and Space Administration (NASA), the National Fire Protection Association (NFPA), and the Compressed Gas Association (CGA). Although none of these organizations has explicitly defined flammability, the following definitions and statements provide a composite understanding of the concept: 1. "This Standard Guide (ASTM G94-92) is concerned primarily with the properties of a material associated with its relative susceptibility to ignition and propagation of combustion." 2. "A material is considered flammable at the maximum use pressure if at least one sample burns more than 6 in. (15.2 cm). At least, five samples must be tested." NASA 3. "Flammable: Capable, when ignited of maintaining combustion under the specified environmental conditions." NFPA 53. 4. "Combustion: A complex sequence of chemical reactions between a fuel and an oxidant accompanied by the evolution of heat, and usually, the emission of light." NFPA 53. and 5. "A safe oxygen-piping transmission or distribution system is one that is designed and installed in accordance with all applicable codes and regulations for the service conditions and locations involved and further meets the special requirements for oxygen services." CGA-G4 Flammability thus equates, after ignition, to propagation of combustion, synonymous with steady state burning, under specified environmental conditions. Properties for which quantitative values are given in ASTM G94-92 and which are used to describe metals flammability consistent with the concept of steady state burning are either system independent properties, such as, enthalpies of reaction, burn ratios, flame temperatures, thermal conductivity, and heat release; or system dependent properties, such as, oxygen index, promoted combustion, threshold pressure and burn rates. Each property is reviewed and analyzed as to whether it provides an absolute or relative measure for flammability. It is shown that burn ratio, as applied to the actual steady state combustion condition, approaches the desired absolute measure of flammability.

Wilson, D. Bruce↗

NASA NTRS2000

A Model For The Burning of Teflon

Teflon has been identified as suitable material for use in oxygen-enriched atmospheres because of its low specific enthalpy of combustion that is, less than 1500 cal/gram. However, once ignited, Teflon burns in a heterogeneous reaction until total consumption or depletion of oxygen occurs. A model is developed for the burning of Teflon in pure, high-pressure oxygen, 3.4 to 68.9 MPa. The Teflon polymer chain dissociates via monomer units due to pyrolysis. These monomer units diffuse to the surface due to free convection. The model consists of coupled mass and energy balances for the polymer and an energy balance for the free convection of product gases. The model is used to obtain appropriate kinetic parameters for the dissociation and surface reactions. The model is validated against experimental measurements of Teflon discs supported on aluminum rods (2216) at oxygen pressures of 3.4, 6.8, 34.4, and 68.9 MPa. The model simulates the temperature distribution in the product gases above burning Teflon.

Waller, Jess M.↗

NASA NTRS2000

Polymer-Oxygen Compatibility Testing: Effect of Oxygen Aging on Ignition and Combustion Properties

The oxygen compatibility of six polymers used in oxygen service was evaluated after exposure for 48 hours to oxygen pressures ranging from 350 to 6200 kPa (50 to 900 psia), and temperatures ranging from 50 to 250 C (122 to 302 F). Three elastomers were tested: CR rubber (C873-70), FKM fluorocarbon rubber (Viton A), and MPQ silicone rubber (MIL-ZZ-765, Class 2); and three thermoplastics were tested: polyhexamethylene adipamide (Zytel 42), polytetrafluoroethylene (Teflon TFE), and polychlorotrifluoroethylene (Neoflon CTFE M400H). Post-aging changes in mass, dimensions, tensile strength, elongation at break, and durometer hardness were determined. Also, the compression set was determined for the three elastomers. Results show that the properties under investigation were more sensitive to oxygen pressure at low to moderate temperatures, and more sensitive to temperature at low to moderate oxygen pressures. Inspection of the results also suggested that both chain scissioning and cross-linking processes were operative, consistent with heterogeneous oxidation. Attempts are underway to verify conclusively the occurrence of heterogeneous oxidation using a simple modulus profiling technique. Finally, the effect of aging at 620 kpa (90 psia) and 121 C (250 F) on ignition and combustion resistance was determined. As expected, aged polymers were less ignitable and combustible (had higher AlTs and lower heats of combustion). Special attention was given to Neoflon CTFE. More specifically, the effect of process history (compression versus extrusion molding) and percent crystallinity (quick- versus slow-quenched) on the AIT, heat of combustion, and impact sensitivity of Neoflon CTFE was investigated. Results show the AIT, heat of combustion, and impact sensitivity to be essentially independent of Neoflon CTFE process history and structure.

Waller, Jess M.↗

NASA NTRS2000

Isentropic Compression of Multicomponent Mixtures of Fuels and Inert Gases

In selected aerospace applications of the fuels hydrazine and monomethythydrazine, there occur conditions which can result in the isentropic compression of a multicomponent mixture of fuel and inert gas. One such example is when a driver gas such as helium comes out of solution and mixes with the fuel vapor, which is being compressed. A second example is when product gas from an energetic device mixes with the fuel vapor which is being compressed. Thermodynamic analysis has shown that under isentropic compression, the fuels hydrazine and monomethylhydrazine must be treated as real fluids using appropriate equations of state. The appropriate equations of state are the Peng-Robinson equation of state for hydrazine and the Redlich-Kwong-Soave equation of state for monomethylhydrazine. The addition of an inert gas of variable quantity and input temperature and pressure to the fuel compounds the problem for safety design or analysis. This work provides the appropriate thermodynamic analysis of isentropic compression of the two examples cited. In addition to an entropy balance describing the change of state, an enthalpy balance is required. The presence of multicomponents in the system requires that appropriate mixing rules are identified and applied to the analysis. This analysis is not currently available.

Barragan, Michelle↗

NASA NTRS2000

Adiabatic Compression of Oxygen: Real Fluid Temperatures

The adiabatic compression of oxygen has been identified as an ignition source for systems operating in enriched oxygen atmospheres. Current practice is to evaluate the temperature rise on compression by treating oxygen as an ideal gas with constant heat capacity. This paper establishes the appropriate thermodynamic analysis for the common occurrence of adiabatic compression of oxygen and in the process defines a satisfactory equation of state (EOS) for oxygen. It uses that EOS to model adiabatic compression as isentropic compression and calculates final temperatures for this system using current approaches for comparison.

Barragan, Michelle↗

NASA NTRS2000

Thermodynamic Analysis of the Combustion of Metallic Materials

Two types of computer codes are available to assist in the thermodynamic analysis of metallic materials combustion. One type of code calculates phase equilibrium data and is represented by CALPHAD. The other type of code calculates chemical reaction by the Gordon-McBride code. The first has seen significant application for alloy-phase diagrams, but only recently has it been considered for oxidation systems. The Gordon-McBride code has been applied to the combustion of metallic materials. Both codes are limited by their treatment of non-ideal solutions and the fact they are limited to treating volatile and gaseous species as ideal. This paper examines the significance of these limitations for combustion of metallic materials. In addition, the applicability of linear-free energy relationships for solid-phase oxidation and their possible extension to liquid-phase systems is examined.

Wilson, D. Bruce↗

NASA NTRS2000

Analysis of the NASA White Sands Test Facility (WSTF) Test System for Friction-Ignition of Metallic Materials

Friction is a known ignition source for metals in oxygen-enriched atmospheres. The test system developed by the NASA White Sands Test Facility in response to ASTM G-94 has been used successfully to determine the relative ignition from friction of numerous metallic materials and metallic materials pairs. These results have been ranked in terms of a pressure-velocity product (PV) as measured under the prescribed test conditions. A high value of 4.1(exp 8) watts per square meter for Inconel MA 754 is used to imply resistance to friction ignition, whereas a low value of 1.04(exp 8) watts per square meter for stainless steel 304 is taken as indicating material susceptible to friction ignition. No attempt has been made to relate PV values to other material properties. This work reports the analysis of the WSTF friction-ignition test system for producing fundamental properties of metallic materials relating to ignition through friction. Three materials, aluminum, titanium, and nickel were tested in the WSTF frictional ignition instrument system under atmospheres of oxygen or nitrogen. Test conditions were modified to reach a steady state of operation, that is applied, the force was reduced and the rotational speed was reduced. Additional temperature measurements were made on the stator sample. The aluminum immediately galled on contact (reproducible) and the test was stopped. Titanium immediately ignited as a result of non-uniform contact of the stator and rotor. This was reproducible. A portion of the stator sampled burned, but the test continued. Temperature measurements on the stator were used to validate the mathematical model used for estimating the interface (stator/rotor) temperature. These interface temperature measurements and the associate thermal flux into the stator were used to distinguish material-phase transitions, chemical reaction, and mechanical work. The mechanical work was used to analyze surface asperities in the materials and to estimate a coefficient of fiction. The coefficient of fiction was analyzed in terms of material properties that is, hardness, Young's modulus and elasticity/plasticity of the material.

Shoffstall, Michael S.↗

NASA NTRS1999

A Multiphase Equation of State for Hydrazine and Monomethylhydrazine

The objective of this work was to obtain a validated equation of state for hydrazine and monomethylhydrazine (MMH) and use this equation to calculate thermodynamic properties. The approach was based on using both reliable critical property values and a value of the acentric factor in the Soave Redlich Kwong and the Peng Robinson model equations of state. These equations were validated by comparing calculated molar volumes for phase equilibrium with published experimental values and comparing calculated vapor pressures with published experimental values over the temperature range appropriate for the corresponding state equations. The equation of state giving the best results was used to calculate enthalpy and entropy departure functions and fugacity values. Additional thermodynamic property calculations were performed to produce partial Mollier diagrams and thermodynamic properties containing internal energy, enthalpy, and entropy values for hydrazine and MMH. The analyses of systems in which either adiabatic or near-adiabatic compression of liquid or vapor hydrazine or low velocity detonations occur require a validated equation of state for representing occurring molar volumes and for energy calculations. Other calculations for thermodynamic properties of hydrazine are available, but the values are for a strict ideal gas state. This work characterized destructive events using hydrazine by calculating for isentropic compression temperatures. The final temperatures were calculated and compared using the ideal and real gas fluid equations of state.

Barragan, Michelle↗

NASA NTRS1993

Metals combustion in normal gravity and microgravity

The study of the combustion characteristics of metallic materials has been an ongoing area of research at the NASA White Sands Test Facility (WSTF). This research has been in support of both government and industrial operations and deals not only with the combustion of specific metallic materials but also with the relative flammabilities of these materials under similar conditions. Since many of the metallic materials that are characterized at WSTF for aerospace applications are to be used in microgravity environments, it was apparent that the testing of these materials needed to proceed in a microgravity environment. It was believed that burning metallic materials in a microgravity environment would allow the evaluation of the validity of applying normal gravity combustion tests to characterize metallic materials to be used in microgravity environments. It was also anticipated that microgravity testing would provide insight into the general combustion process of metallic materials. The availability of the NASA Lewis Research Center's (LeRC) 2.2-second drop tower provided the necessary facility to accomplish the microgravity portion of the testing while the normal gravity testing was conducted at NASA WSTF. The tests, both at LeRC and WSTF, were conducted in the same instrumented system and utilized the standard metal flammability test of upward propagation burning of cylindrical rod samples.

Steinberg, Theodore A.↗