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Wilson, J. C.

Publications and source records attributed to Wilson, J. C..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Condensed-Phase Nitric Acid in a Tropical Subvisible Cirrus Cloud

In situ observations in a tropical subvisible cirrus cloud during the Costa Rica Aura Validation Experiment on 2 February 2006 show the presence of condensed-phase nitric acid. The cloud was observed near the tropopause at altitudes of 16.3-17.7 km in an extremely cold (183-191 K) and dry 5 ppm H2O) air mass. Relative humidities with respect to ice ranged from 150-250% throughout most of the cloud. Optical particle measurements indicate the presence of ice crystals as large as 90 microns in diameter. Condensed RN031H20 molar ratios observed in the cloud particles were 1-2 orders of magnitude greater than ratios observed previously in cirrus clouds at similar RN03 partial pressures. Nitric acid trihydrate saturation ratios were 10 or greater during much of the cloud encounter, indicating that RN03 may be present in the cloud particles as a stable condensate and not simply physically adsorbed on or trapped in the particles.

Popp, P. J.↗
NASA NTRS2006

Single-Particle Measurements of Midlatitude Black Carbon and Light-Scattering Aerosols from the Boundary Layer to the Lower Stratosphere

A single-particle soot photometer (SP2) was flown on a NASA WB-57F high-altitude research aircraft in November 2004 from Houston, Texas. The SP2 uses laser-induced incandescence to detect individual black carbon (BC) particles in an air sample in the mass range of approx.3-300 fg (approx.0.15-0.7 microns volume equivalent diameter). Scattered light is used to size the remaining non-BC aerosols in the range of approx.0.17-0.7 microns diameter. We present profiles of both aerosol types from the boundary layer to the lower stratosphere from two midlatitude flights. Results for total aerosol amounts in the size range detected by the SP2 are in good agreement with typical particle spectrometer measurements in the same region. All ambient incandescing particles were identified as BC because their incandescence properties matched those of laboratory-generated BC aerosol. Approximately 40% of these BC particles showed evidence of internal mixing (e.g., coating). Throughout profiles between 5 and 18.7 km, BC particles were less than a few percent of total aerosol number, and black carbon aerosol (BCA) mass mixing ratio showed a constant gradient with altitude above 5 km. SP2 data was compared to results from the ECHAM4/MADE and LmDzT-INCA global aerosol models. The comparison will help resolve the important systematic differences in model aerosol processes that determine BCA loadings. Further intercomparisons of models and measurements as presented here will improve the accuracy of the radiative forcing contribution from BCA.

Schwartz, J. P.↗
NASA NTRS2004

Dusty Disks, Diffuse Clouds, and Dim Suns: Galactic Science with the Infrared Spectrograph on the Spitzer Space Telescope

The Infrared Spectrograph (IRS) on the Spitzer Space Telescope has now been in routine science operations since Dec. 14,2003. The IRS Science Team has used a portion of their guaranteed time to pursue three major science themes in galactic astronomy: the evolution of protostellar disks and debris disks; the composition and evolution of diffuse matter and clouds in the interstellar medium; and the composition and structure of brown dwarfs and low-mass main-sequence stars. We report here on the results from the first five months of IRS observations in these programs. Full IRS Spectra have already been obtained for large samples of YSO/protoplanetary disks in the Taurus and TW Hya associations, and or debris disks around main-sequence stars, in which many aspects of the evolution of planetary systems can be addressed for the first time. As anticipated, the mid-infrared IRS observations of brown dwarfs have yielded important new information about their atmospheres, including the identification of NH3 and measurements of new methane features. This work is based on observations made with the Spitzer Space Telescope, which is operated by the Jet Propulsion Laboratory, California Institute of Technology under NASA contract 1407. Support for this work was provided by NASA's Office of Space Science.

Roellig, T. L.↗
NASA NTRS2001

Evidence for the Widespread Presence of Liquid-Phase Particles During the 1999-2000 Arctic Winter

In-situ Multi-Angle Spectrometer Probe (MASP) particle measurements have been analyzed to determine the typical behaviour of sulphate particles during the SOLVE campaign. The analysis has focussed on variations in the total particle concentration measured by MASP, which is a diagnostic that is primarily sensitive to the growth of small particles (those which are initially smaller than 0.2 micrometers in radius). At all levels of the stratosphere, the total MASP concentration varies continuously with temperature. This behaviour is well-reproduced by assuming that the sulphate aerosols are liquid ternary solutions, but cannot be reproduced if the aerosol is assumed to be frozen. This liquid-like behaviour is apparent for all measurements made during SOLVE, both inside and outside the vortex, and even at the coldest temperatures sampled during the campaign. The only anomalous measurements were made during the flight of January 14th, 2001; however, this midlatitude flight is very unlikely to contain SAT particles based on the recent warm temperatures experienced by the air. At the levels with the coldest measured temperatures, at least 90% of the particles grow as liquids. Therefore, the freezing that occurred during the 1999-2000 Arctic winter was selective, causing most of the particles to remain liquid even in the presence of a small number of frozen particles.

Drdla, K↗
NASA NTRS2000

Chance Encounter with a Stratospheric Kerosene Rocket Plume From Russia Over California

A high-altitude aircraft flight on April 18, 1997 detected an enormous aerosol cloud at 20 km altitude near California (37 N). Not visually observed, the cloud had high concentrations of soot and sulfate aerosol, and was over 180 km in horizontal extent. The cloud was probably a large hydrocarbon fueled vehicle, most likely from rocket motors burning liquid oxygen and kerosene. One of two Russian Soyuz rockets could have produced the cloud: a launch from the Baikonur Cosmodrome, Kazakhstan on April 6; or from Plesetsk, Russia on April 9. Parcel trajectories and long-lived trace gas concentrations suggest the Baikonur launch as the cloud source. Cloud trajectories do not trace the Soyuz plume from Asia to North America, illustrating the uncertainties of point-to-point trajectories. This cloud encounter is the only stratospheric measurement of a hydrocarbon fuel powered rocket.

Newman, P. A.↗
NASA NTRS1999

Chance Encounter with a Stratospheric Kerosene Rocket Plume from Russia over California

During a routine ER-2 aircraft high-altitude test flight on April 18, 1997, an unusual aerosol cloud was detected at 20 km altitude near the California coast at about 370 degrees N latitude. Not visually observed by the ER-2 pilot, the cloud was characterized bv high concentration of soot and sulfate aerosol in a region over 100 km in horizontal extent indicating that the source of the plume was a large hydrocarbon fueled vehicle, most likely a launch vehicle powered only by rocket motors burning liquid oxygen and kerosene. Two Russian Soyuz rockets could conceivably have produced the plume. The first was launched from the Baikonur Cosmodrome, Kazakhstan on April 6th; the second was launched from Plesetsk, Russia on April 9. Air parcel trajectory calculations and long-lived tracer gas concentrations in the cloud indicate that the Baikonur rocket launch is the most probable source of the plume. The parcel trajectory calculations do not unambiguously trace the transport of the Soyuz plume from Asia to North America, illustrating serious flaws in the point-to-point trajectory calculations. This chance encounter represents the only measurement of the stratospheric effects of emissions from a rocket powered exclusively with hydrocarbon fuel.

Newman, P. A.↗
NASA NTRS1995

FTIR studies of low temperature sulfuric acid aerosols

Sub-micrometer sized sulfuric acid H2SO4 particles were generated using a constant output atomizer source. The particles were then exposed to water vapor before being injected into a low temperature cell. Multipass transmission Fourier Transformation Infrared (FTIR) spectroscopy was used to determine the phase and composition of the aerosols as a function of time for periods of up to five hours. Binary H2SO4H2O aerosols with compositions from 35 to 95 wt % H2SO4 remained liquid for over 3 hours at room temperatures ranging from 189-240 K. These results suggest that it is very difficut to freeze SSAs via homogeneous nucleation. Attempts to form aerosols more dilute than 35 wt % H2SO4 resulted in ice formation.

Anthony, S. E.↗
NASA NTRS1995

Performance of a focused cavity aerosol spectrometer for measurements in the stratosphere of particle size in the 0.06-2.0-micrometer-diameter range

A focused cavity aerosol spectrometer aboard a NASA ER-2 high-altitude aircraft provided high-resolution measurements of the size of the stratospheric particles in the 0.06-2.0-micrometer-diameter range in flights following the eruption of Mount Pinatubo in 1991. Effects of anisokinetic sampling and evaporation in the sampling system were accounted for by means adapted and specifically developed for this instrument. Calibrations with monodisperse aerosol particles provided the instrument's response matrix, which upon inversion during data reduction yielded the particle size distributions. The resultant dataset is internally consistent and generally shows agreement to within a factor of 2 with comparable measurements simultaneously obtained by a condensation nuclei counter, a forward-scattering spectrometer probe, and aerosol particle impactors, as well as with nearby extinction profiles obtained by satellite measurements and with lidar measurements of backscatter.

Jonsson, H. H.↗
NASA NTRS1994

The Diurnal Variation of Hydrogen, Nitrogen, and Chlorine Radicals: Implications for the Heterogeneous Production of HNO2

In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunset in the lower stratosphere during SPADE are compared to results from a photochemical model constrained by observed concentrations of radical precursors and environmental conditions. Models allowing for heterogeneous hydrolysis of N205 on sulfate aerosols agree with measured concentrations of NO, NO2, and ClO throughout the day, but fail to account for high concentrations of OH and H02 observed near sunrise and sunset. The morning burst of [OH] and [HO2] coincides with the rise of [NO] from photolysis of N02, suggesting a new source of HO, that photolyzes in the near UV (350 to 400 nm) spectral region. A model that allows for the heterogeneous production of HN02 results in an excellent simulation of the diurnal variations of [OH] and [HO2].

Salawitch, R. J.↗
NASA NTRS1994

The Distribution of Hydrogen, Nitrogen, and Chlorine Radicals in the Lower Stratosphere: Implications for Changes in O3 due to Emission of NO(y) from Supersonic Aircraft

In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained in the lower stratosphere during the Stratospheric Photochemistry, Aerosols and Dynamics Expedition (SPADE) are compared to results from a photochemical model that assimilates measurements of radical precursors and environmental conditions. Models allowing for heterogeneous hydrolysis of N2O5 agree well with measured concentrations of NO and ClO, but concentrations of HO2 and OH are underestimated by 10 to 25%, concentrations of NO2 are overestimated by 10 to 30%, and concentrations of HCl are overestimated by a factor of 2. Discrepancies for [OH] and [HO2] are reduced if we allow for higher yields of O(sup 1)D) from 03 photolysis and for heterogeneous production of HNO2. The data suggest more efficient catalytic removal of O3 by hydrogen and halogen radicals relative to nitrogen oxide radicals than predicted by models using recommended rates and cross sections. Increases in [O3] in the lower stratosphere may be larger in response to inputs of NO(sub y) from supersonic aircraft than estimated by current assessment models.

Salawitch, R. J.↗
NASA NTRS1993

Interpretation of NO(x)/NO(y) observations from AASE-2 using a model of chemistry along trajectories

In situ measurements of NO and NO(y) are used to derive the ratio NO(x)/NO(y) along the flight track of the NASA ER-2 aircraft. Data are presented for two flights at midlatitudes in October 1991 during the Airborne Arctic Stratospheric Expedition-2 (AASE-2). Aerosol particle surface area was concurrently measured. The observations are compared with a photochemical model integrated along back trajectories from the aircraft flight track. Comparison of observations with the model run along trajectories and at a fixed position clearly and quantitatively demonstrates the importance of an air parcel's dynamic history in interpretation of local chemical observations. Comparison of the data with model runs under different assumptions regarding heterogeneous chemistry further reinforces the case for occurrence of the reaction of N2O5 + H2O on sulfate aerosol surfaces in the atmosphere. Finally, comparisons for which relative changes in the model and the data are not consistent caution that our ability to resolve all the observations is not yet complete.

Kawa, S. R.↗
NASA NTRS1993

Effects of Pinatubo aerosol on stratospheric ozone at mid-latitudes

Mid-latitude ozone data from ER-2 aircraft measurements in 1989, 1991, and 1992 were examined to determine how sulfate aerosols from the eruption of Mt. Pinatubo had affected ozone at about 18 km. N2O was used as a tracer to help distinguish between chemical and dynamical aerosol effects. At 20-45 deg N in February 1992, ozone was about 10-20% lower than February 1989 and 1991, with respect to N2O. Data from Aug. 1991 - Mar. 1992 showed changes in ozone with respect to N2O, but the magnitude of those changes was not correlated with the magnitude of the changes in aerosol surface area density.

Weaver, A.↗
NASA NTRS1993

In-situ measurements of changes in stratospheric aerosol and the N2O-aerosol relationship inside and outside of the polar vortex

Two optical particle counters on the ER-2, together covering a particle size diameter range from 0.1 microns to 23 microns, were used to measure the aerosol bulk quantities integral number, aerosol surface and volume, as well as detailed size distributions inside and outside of the polar vortex in the lower stratosphere. While AAES I (Arctic Airborne Stratospheric Expedition, (Dec. 88 - Feb. 89) was conducted in a period of relative volcanic quiescence, enhancements in aerosol number, surface and volume of factors around 10, 25 and 100 were observed during AASE 2 (Aug. 91 - Mar. 92) due to the eruption of Mt. Pinatubo. The changes in these bulk quantities as well as in the size distributions measured both outside and inside the polar vortex are presented and compared with those obtained in polar stratospheric cloud events (AASE I). Except for a shift towards larger aerosol mixing ratios the general shape of correlograms between the measured N2O and particle mixing ratios remain similar before and after the eruption. Similar correlograms are used to interpret data from vertical profiles inside and outside of the polar vortex.

Borrmann, S.↗
NASA NTRS1993

Effects of Pinatubo Aerosol on Stratospheric Zone at Mid-Lattiudes

Mid-latitude ozone data from ER-2 aircraft measurements in 1989, 1991 and 1992 were examined to determine how sulfate aerosols from the eruption of Mt. Pinatubo had affected ozone at about 18 km. N2O was used as a tracer to help distinguish between chemical and dynamical aerosol effects. At 20-45 deg N in February 1992, ozone was about 10-20% lower than February 1989 and 1991, with respect to N2O. Data from Aug.1991 - Mar. 1992 showed changes in ozone with respect to N2O, but the magnitude of those changes was not correlated with the magnitude of the changes in aerosol surface area density.

Weaver, A.↗
NASA NTRS1993

In-Situ Measurements of Changes in Stratospheric Aerosol and the N2O - Aerosol Relationship inside and outside of the Polar Vortex

Two optical particle counters on the ER-2, together covering a particle size diameter range from 0.1 micrometers to 23 micrometers, were used to measure the aerosol bulk quantities integral number, aerosol surface and volume, as well as detailed size distributions inside and outside of the polar vortex in the lower stratosphere. While AASE I (Arctic Airborne Stratospheric Expedition, (Dec. 1988 - Feb. 1989) was conducted in a period of relative volcanic quiescence, enhancements in aerosol number, surface and volume of factors around 10, 25 and 100 were observed during AASE II (Aug. 1991 - Mar. 1992) due to the eruption of Mt. Pinatubo. The changes in these bulk quantities as well as in the size distributions measured both outside and inside the the polar vortex are presented and compared with those obtained in polar stratospheric cloud events (AASE I). Except for a shift towards larger aerosol mixing ratios the general shape of correlograms between the measured N2O and particle mixing ratios remain similar before and after the eruption. Similar correlograms are used to interpret data from vertical profiles inside and outside of the polar vortex.

Borrmann, S.↗
NASA NTRS1993

In situ observations of aerosol and chlorine monoxide after the 1991 eruption of Mount Pinatubo - Effect of reactions on sulfate aerosol

Highly resolved aerosol size distributions measured from high-altitude aircraft can be used to describe the effect of the 1991 eruption of Mount Pinatubo on the stratospheric aerosol. In some air masses, aerosol mass mixing ratios increased by factors exceeding 100 and aerosol surface area concentrations increased by factors of 30 or more. Increases in aerosol surface area concentration were accompanied by increases in chlorine monoxide at mid-latitudes when confounding factors were controlled. This observation supports the assertion that reactions occurring on the aerosol can increase the fraction of stratospheric chlorine that occurs in ozone-destroying forms.

Wilson, J. C.↗
NASA NTRS1993

Chemical Loss of Ozone in the Arctic Polar Vortex in the Winter of 1991-1992

In situ measurements of chlorine monoxide, bromine monoxide, and ozone are extrapolated globally, with the use of meteorological tracers, to infer the loss rates for ozone in the Arctic lower stratosphere during the Airborne Arctic Stratospheric Expedition II (AASE II) in the winter of 1991-1992. The analysis indicates removal of 15 to 20 percent of ambient ozone because of elevated concentrations of chlorine monoxide and bromine monoxide. Observations during AASE II define rates of removal of chlorine monoxide attributable to reaction with nitrogen dioxide (produced by photolysis of nitric acid) and to production of hydrochloric acid. Ozone loss ceased in March as concentrations of chlorine monoxide declined. Ozone losses could approach 50 percent if regeneration of nitrogen dioxide were inhibited by irreversible removal of nitrogen oxides (denitrification), as presently observed in the Antarctic, or without denitrification if inorganic chlorine concentrations were to double.

Salawitch, R. J.↗