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Wu, Christine J.

Publications and source records attributed to Wu, Christine J..

11 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Structural study of hcp and liquid iron under shock compression up to 275 GPa

Here we combine nanosecond laser shock compression with in situ picosecond x-ray diffraction to provide structural data on iron up to 275 GPa. We constrain the extent of hcp-liquid coexistence, the onset of total melt, and the structure within the liquid phase. Our results indicate that iron, under shock compression, melts completely by 258(8) GPa. A coordination number analysis indicates that iron is a simple liquid at these pressure-temperature conditions. We also perform texture analysis between the ambient body-centered-cubic (bcc) α, and the hexagonal-closed-packed (hcp) high-pressure ε-phase. We rule out the Rong-Dunlop orientation relationship (OR) between the α and ε - phase s. However, we cannot distinguish between three other closely related ORs: Burger's, Mao-Bassett-Takahashi, and Potter's OR. The solid-liquid coexistence region is constrained from a melt onset pressure of 225(3) GPa from previously published sound speed measurements and full melt [246.5(1.8)–258(8) GPa] from x-ray diffraction measurements, with an associated maximum latent heat of melting of 623 J/g. This value is lower than recently reported theoretical estimates and suggests that the contribution to the earth's geodynamo energy budget from heat release due to freezing of the inner core is smaller than previously thought. Melt pressures for these nanosecond shock experiments are consistent with gas gun shock experiments that last for microseconds, indicating that the melt transition occurs rapidly.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Fluid-phase helium: Shock-compression experiments, quantum molecular dynamics simulations, and development of an equation of state

Helium (He) plays a critical role in numerous areas ranging from the study of celestial objects like brown dwarfs and gas giants to modern-day technologies like nuclear energy and rocket propulsion. For many of these applications, it is essential to have a reliable equation of state (EOS) for He that yields an accurate representation of its thermodynamic behavior. To help constrain and develop such EOS models, we have performed a series of shock-compression experiments on cryogenic liquid He to pressures exceeding 100 GPa using a magnetically accelerated flyer plate on Sandia National Laboratories' Z-machine. We have also performed quantum molecular dynamics simulations that are consistent with our shock measurements. None of the previously available EOSs agree with our experimental and simulation results, motivating the development of a fluid-phase He EOS that we present in this study. Here, we show that our EOS yields good agreement with published data that span temperatures and pressures encountered across a diverse array of applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Atom-in-jellium predictions of the shear modulus at high pressure

Atom-in-jellium calculations of the Einstein frequency in condensed matter and of the equation of state were used to predict the variation of shear modulus from zero pressure to ~10 7 g/cm 3 , for several elements relevant to white dwarf stars and other self-gravitating systems. This is by far the widest range reported electronic structure calculation of shear modulus, spanning from ambient through the one-component plasma to extreme relativistic conditions. The predictions were based on a relationship between the Debye temperature and shear modulus, which we assess to be accurate at the o(10%) level, and is the first known use of atom-in-jellium theory to calculate a shear modulus. Finally, we assessed the overall accuracy of the method by comparing with experimental measurements and more detailed electronic structure calculations at lower pressures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Thermodynamics Modeling for Actinide Monocarbides and Mononitrides from First Principles

The high-temperature thermodynamical properties for the actinide monocarbides and mononitrides ThC, ThN, UC, UN, PuC, and PuN are calculated from first-principles electronic-structure theory. The electronic structure is modeled with density-functional theory (DFT) and is fully relativistic, including the spin-orbit interaction. Furthermore, the DFT is extended to account for orbital–orbital interactions, by means of a parameter-free orbital-polarization (OP) technique, that has proven to be essential for the 5f electrons in plutonium. Strong anharmonicity and the temperature dependence of the lattice vibrations are captured with the self-consistent ab initio lattice dynamics (SCAILD) method. The calculated free energies and heat capacities are compared to published results from quasi-harmonic (QH) theory, and experiments, where available. For the uranium and plutonium compounds, we make use of CALPHAD assessments to help evaluate the theory. Generally, our anharmonic relativistic approach compares well with both CALPHAD and experiments. For the thorium compounds, our theory is in good accord with QH modeling of the free energy at lower temperatures but for the heat capacity the comparison is less favorable.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Equation of state for a chemically dissociative, polyatomic system: Carbon dioxide

A notorious challenge in high-pressure science is to develop an equation of state (EOS) that explicitly treats chemical reactions. For instance, many materials tend to dissociate at high pressures and temperatures where the chemical bonds that hold them together break down. We present an EOS for carbon dioxide (CO 2 ) that allows for dissociation and captures the key material behavior in a wide range of pressure– temperature conditions. Carbon dioxide is an ideal prototype for the development of a wide-ranging EOS that allows for chemical-dissociation equilibria since it is one of the simplest polyatomic systems and because it is of great interest in planetary science and in the study of detonations. Here, we show that taking dissociation into account significantly improves the accuracy of the resulting EOS compared to other EOSs that either neglect chemistry completely or treat CO 2 dissociation in a more rudimentary way.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Hugoniot Models for Na and LiF from LEOS

In this document, we provide the Hugoniot for sodium from two models: LEOS table L110 and Lynx table 110. We also provide the Hugoniot for lithium fluoride from LEOS (L2240) and Lynx (2240). The Hugoniot pressures are supplied for temperatures between 338.0 and 1.16×10 9 Kelvin and densities between 0.968 and 11.5 g/cc. These LEOS models were developed by the quotidian EOS methodology, which is a widely used and robust method for producing tabular EOS data. Tables list the model data for LEOS 110, Lynx 110, LEOS 2240, and Lynx 2240. The Lynx models follow the same methodology as the LEOS models; however, the Purgatorio average-atom DFT code was used to compute the electron thermal part of the EOS. The models for Lynx are only listed at high compression due to known issues with the Lynx library at lower pressures.

36 MATERIALS SCIENCE↗