Integrating Band Structure Engineering with All-Scale Hierarchical Structuring for High Thermoelectric Performance in PbTe System
We investigated PbTe 1-x Se x -2%Na-y%SrTe system and report a high ZT of 2.3 at 923 K for PbTe 0.85 Se 0.15 -2%Na-4%SrTe. This is achieved by performing electronic band structures modifications as well as all-scale hierarchical structuring and combining the two effects. We find that high ZTs in PbTe 0.85 Se 0.15 -2%Na-4%SrTe are possible at all temperature from 300K to 873K with an average ZT ave of 1.23. The high performance in PbTe 1-x Se x -2%Na-y%SrTe could be achieved by either choosing PbTe-2Na-4SrTe or PbTe 0.85 Se 0.15 -2Na as a matrix. At room temperature the carrier mobility shows negligible variations as SrTe fraction is increased, however the lattice thermal conductivity is significantly reduced from ~ 1.1 Wm-1K-1 to ~ 0.82 Wm -1 K -1 when 5.0 % SrTe is added. The lattice thermal conductivity at 923 K decreases from ~ 0.59 Wm-1K-1 to ~ 0.43 Wm -1 K -1 . The power factor maxima of PbTe 1-x Se x -2Na-4SrTe shift systematically to higher temperature with rising Se fractions due to bands divergence. The maximum power factors reach ~ 27 μWcm -1 K -2 , ~ 30 μWcm -1 K -2 , ~ 31 μWcm -1 K -2 for the x = 0, 0.05, and 0.15 samples peak at 473K, 573K and 623K,