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Xu, Xin

Publications and source records attributed to Xu, Xin.

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

A reversible four-electron Sn metal aqueous battery

Sn is a promising metal anode for aqueous batteries, with up to four-electron redox available per atom (903 mAh g −1 Sn ). However, practically harnessing the four-electron Sn(OH) 6 2− /Sn reversibility remains challenging due to limited mechanistic understanding. Here, in this study, we reveal a kinetically asymmetric redox pathway involving a successive four-electron plating and a stepwise 2 + 2 electron stripping through a Sn(OH) 3 − intermediate. The crossover of Sn(OH) 3 − induces a reversible self-discharge that reduces Coulombic efficiency but does not impact cyclability, demonstrated by four-electron Sn-Ni full cells that sustain >800 h of stable cycling. By tuning the ion selectivity of the separator to suppress Sn(OH) 3 − crossover while allowing OH − transport, we further demonstrate high Sn utilization (67%) and high energy density (143.1 Wh L −1 cell). The results provide key understandings of the tradeoffs in engineering reversible multi-electron metal anodes and define a new benchmark for practical energy density that exceeds any Sn-based aqueous batteries to date.

SN anode↗
DOE OSTI2024

J-TEXT achievements in turbulence and transport in support of future device/reactor

Following the reconstruction of the TEXT tokamak at Huazhong University of Science and Technology in China, renamed as J-TEXT, a plethora of experimental and theoretical investigations has been conducted to elucidate the intricacies of turbulent transport within the tokamak configuration. These endeavors encompass not only the J-TEXT device's experimental advancements but also delve into critical issues pertinent to the optimization of future fusion devices and reactors. Here, the research includes topics on the suppression of turbulence, flow drive and damping, density limit, non-local transport, intrinsic toroidal flow, turbulence and flow with magnetic islands, turbulent transport in the stochastic layer, and turbulence and zonal flow with energetic particles or helium ash. Several important achievements have been made in the last few years, which will be further elaborated upon in this comprehensive review.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Overview of the recent experimental research on the J-TEXT tokamak

The J-TEXT capability is enhanced compared to two years ago with several upgrades of its diagnostics and the increase of electron cyclotron resonance heating (ECRH) power to 1 MW. With the application of electron cyclotron wave (ECW), the ECW assisted plasma startup is achieved; the tearing mode is suppressed; the toroidal injection of 300 kW ECW drives around 24 kA current; fast electrons are generated with toroidal injected ECW and the runaway current conversion efficiency increases with ECRH power. The mode coupling between 2/1 and 3/1 modes are extensively studied. The coupled 2/1 and 3/1 modes usually lead to major disruption. Their coupling can be either suppressed or avoided by external resonant magnetic perturbation fields and hence avoids the major disruption. It is also found that the 2/1 threshold of external field is significantly reduced by a pre-excited 3/1 mode, which can be either a locked island or an external kink mode. The disruption control is studied by developing prediction methods capable of cross tokamak application and by new mitigation methods, such as the biased electrode or electromagnetic pellet injector. The high-density operation and related disruptions are studied from various aspects. Approaching the density limit, the collapse of the edge shear layer is observed and such collapse can be prevented by applying edge biasing, leading to an increased density limit. The density limit is also observed to increase, if the plasma is operated in the poloidal divertor configuration or the plasma purity is increased by increasing the pre-filled gas pressure or ECRH power during the start-up phase.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Effect of H + Exchange and Surface Impurities on Bulk and Interfacial Electrochemistry of Garnet Solid Electrolytes

Contact loss and current constriction pose significant challenges at the Li metal interface of solid-state batteries. For garnet-structured Li 7 La 3 Zr 2 O 12 (LLZO), these effects are amplified by Li + /H + exchange and surface contamination reactions, which lead to conductivity losses and poor Li wetting. In this study, we utilize a variety of surface treatment processes across 37 cells to selectively induce proton exchange and contamination reactions in LLZO. The resulting bulk and surface chemistry is systematically characterized and correlated to changes in electrochemical properties. Additionally, we combine impedance analysis and finite element method modeling to deconvolute sources of impedance contributions at the Li metal interface. Specifically, we show that constriction impedance at the Li metal interface arises not solely from voids, but also from ionically-resistive surface contaminants. Further, these findings emphasize the connection between ionic conductivity and constriction, demonstrating that micron-scale ionically-resistive components increase constriction even with identical contact geometries. Finally, we leverage our comprehensive dataset to highlight unstable overpotential growth as a failure mechanism, additionally showing that the phase of a cell’s impedance is a sensitive indicator for the onset of interfacial instability. Overall, this study clarifies the impacts of proton exchange and surface contamination on electrochemical properties at the Li|solid electrolyte interface and elucidates insights that are generalizable to other solid-state battery systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

On how structures convey non-diffusive turbulence spreading

Abstract We report on comprehensive experimental studies of turbulence spreading in edge plasmas. These studies demonstrate the relation of turbulence spreading and entrainment to intermittent convective density fluctuation events or bursts (i.e. blobs and holes). The non-diffusive character of turbulence spreading is thus elucidated. The turbulence spreading velocity (or mean jet velocity) manifests a linear correlation with the skewness of density fluctuations, and increases with the auto-correlation time of density fluctuations. Turbulence spreading by positive density fluctuations is outward, while spreading by negative density fluctuations is inward. The degree of symmetry breaking between outward propagating blobs and inward propagating holes increases with the amplitude of density fluctuations. Thus, blob-hole asymmetry emerges as crucial to turbulence spreading. These results highlight the important role of intermittent convective events in conveying the spreading of turbulence, and constitute a fundamental challenge to existing diffusive models of spreading.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

The role of shear flow collapse and enhanced turbulence spreading in edge cooling approaching the density limit

Abstract Experimental studies of the dynamics of shear flow and turbulence spreading at the edge of tokamak plasmas are reported. Scans of line-averaged density and plasma current are carried out while approaching the Greenwald density limit on the J-TEXT tokamak. In all scans, when the Greenwald fraction f G = n ¯ / n G = n ¯ / ( I p / π a 2 ) increases, a common feature of enhanced turbulence spreading and edge cooling is found. The result suggests that turbulence spreading is a good indicator of edge cooling, indeed better than turbulent particle transport is. The normalized turbulence spreading power increases significantly when the normalized E × B shearing rate decreases. This indicates that turbulence spreading becomes prominent when the shearing rate is weaker than the turbulence scattering rate. The asymmetry between positive/negative (blobs/holes) spreading events, turbulence spreading power and shear flow are discussed. These results elucidate the important effects of interaction between shear flow and turbulence spreading on plasma edge cooling.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

A Minkowski difference-based advancing front packing technique for generating convex noncircular particles in complex domains

In this work, a Minkowski difference-based advancing front approach is proposed to generate convex and non-circular particles in a predefined computational domain. Two specific algorithms are developed to handle the contact conformity of generated particles with the boundaries of the computational domain. The first, called the open form, is used to handle the smooth contact of generated particles with (external) boundaries, while the other, called the closed form, is proposed to handle the internal boundaries of a computational domain with a complex cavity. The Gilbert-Johnson-Keerthi (GJK) method is used to efficiently solve the contact detection between the newly generated particle at the front and existing particles. Furthermore, the problem of one-sided particle lifting, which can cause some defects in the packing structure in existing advancing front methods during packing generation, is highlighted and an effective solution is developed. Several examples of increasing complexity are used to demonstrate the efficiency and applicability of the proposed packing generation approach. The numerical results show that the generated packing is not only more uniform, but also achieves a higher packing density than existing advancing front methods.

42 ENGINEERING↗
DOE OSTI2022

gC1qR/C1qBP/HABP-1: Structural Analysis of the Trimeric Core Region, Interactions With a Novel Panel of Monoclonal Antibodies, and Their Influence on Binding to FXII

The protein gC1qR/C1qBP/HABP-1 plays an essential role in mitochondrial biogenesis, but becomes localized at the cellular surface in numerous pathophysiological states. When this occurs on endothelial cells, surface-exposed gC1qR activates the classical pathway of complement. It also promotes assembly of a multi-protein complex comprised of coagulation factor XII (FXII), pre-kallikrein (PK), and high-molecular weight kininogen (HMWK) that activates the contact system and the kinin-generating system. Since surface-exposed gC1qR triggers intravascular inflammatory pathways, there is interest in identifying molecules that block gC1qR function. Here we further that objective by reporting the outcome of a structure/function investigation of gC1qR, its interactions with FXII, and the impact of a panel of monoclonal anti-gC1qR antibodies on FXII binding to gC1qR. Although deletion mutants have been used extensively to assess gC1qR function, none of these proteins have been characterized structurally. To that end, we determined a 2.2 Å resolution crystal structure of a gC1qR mutant lacking both of its acidic loops, but which retained nanomolar-affinity binding to FXII and FXIIa. This structure revealed that the trimeric gC1qR assembly was maintained despite loss of roughly thirty residues. Characterization of a novel panel of anti-gC1qR monoclonal antibodies identified several with biochemical properties distinct from previously described antibodies, as well as one which bound to the first acidic loop of gC1qR. Intriguingly, we found that each of these antibodies could partly inhibit binding of FXII and FXIIa to gC1qR. Based on these results and previously published studies, we offer new perspectives for developing gC1qR inhibitors.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Parameterizing Convective Organization Effects With a Moisture-PDF Approach in Climate Models: Concept and a Regional Case Simulation

We propose a parameterization scheme of convective organization effects based on a moisture-distribution approach, which can reflect aggregation of convective cells within a model grid as well as the interaction between convection and spatial heterogeneity in free-troposphere moisture. With this concept, convective cells in an aggregated state are surrounded by air that is moister than the grid-mean condition, which provides a “shielding” effect favorable for deeper convective updrafts. Such effects are represented quantitatively via utilizing a schematic diagram about the geometric interpretation of convective cluster, dry area, and their contact area, in which both the convective cluster size and dry area fraction increase during the development of convection. Our sensitivity analyses indicate that the new scheme performs well in capturing the mean precipitation features. Excluding the convective organization effects in the model leads to a considerable reduction in the simulated precipitation magnitude. Notably, there exists an inverse relationship between background mean moisture condition and sub-grid moisture variability for a given rain rate, suggesting that with a high spatial heterogeneity in free-troposphere moisture, convection can still develop and maintain its strength under relatively dry background conditions, consistent with the convection-permitting model simulation. Overall, our new parameterization of convective organization effects can successfully reproduce the relationship between precipitation and sub-grid moisture variability, which is a missing element in traditional convection parameterization schemes but important for the simulations of precipitation variability at various scales in climate models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Advances in physics and applications of 3D magnetic perturbations on the J-TEXT tokamak

In the last two years, three major technical improvements have been made on J-TEXT in supporting of the expanded operation regions and diagnostic capabilities. (1) The successful commission of the 105 GHz/500 kW/1 s electron cyclotron resonance heating (ECRH) system increasing the core electron temperature from 0.9 keV up to around 1.5 keV. (2) The poloidal divertor configuration with an X-point in the high-field side has been achieved. In particular, the 400 kW electron cyclotron wave has also been successfully injected into the diverted plasma. (3) A 256-channel electron cyclotron emission imaging diagnostic system and two sets of four-channel Doppler backscattering diagnostics have been successfully developed on J-TEXT, allowing detailed measurement of the electron temperature and density fluctuations for turbulence and MHD research. The locked mode (LM), especially the 2/1 LM, is one of the biggest threats to the plasma operation. Both the thresholds of 2/1 and 3/1 LM are observed to vary non-monotonically on electron density. The electrode biasing was applied successfully to unlock the LM from either a rotating or static resonant magnetic perturbation (RMP) field. In the presence of 2/1 LM, three kinds of standing wave (SW) structures have been observed to share a similar connection to the island structure, i.e. the nodes of the SWs locate around the O- or X-points of the 2/1 island. The control and mitigation of disruption is essential to the safe operation of ITER, and it has been systematically studied by applying a RMP field, massive gas injection (MGI) and shattered pellet injection on J-TEXT. When the RMP-induced 2/1 LM is larger than a critical width, the MGI shutdown process can be significantly influenced. If the phase difference between the O-point of LM and the MGI valve is +90° (or –90°), the penetration depth and the assimilation of impurities can be enhanced (or suppressed) during the pre-thermal quench (TQ) phase and result in a faster (or slower) TQ. A secondary MGI can also suppress the runaway electron (RE) generation, if the additional high-Z impurity gas arrives at the plasma edge before TQ. When the secondary MGI has been applied after the formation of the RE current plateau, the RE current can be dissipated, and the dissipation rate increases with the injected impurity quantity but saturates with a maximum of 28 MA s –1 . The non-local transport is experimentally observed in the ion transport channel. The electron thermal diffusivity significantly increases with the ECRH power. Theoretical work shows that significant intrinsic current can be driven by electromagnetic turbulence, and the robust formation mechanism of the E × B staircase is identified from the Hasegawa–Wakatani system.

divertor↗
DOE OSTI2021

Approximation of the Frequency-Amplitude Curve Using the Homotopy Analysis Method

The Frequency-Amplitude (F-A) curve on power system oscillation under a large disturbance characterizes how a natural oscillation mode transitions to nonlinear oscillations with growing amplitudes and decaying frequencies. The existing formulation of the F-A curve is derived by solving elliptical integrals on oscillation of a single-machine-infinite-bus equivalent about the targeted oscillation mode. The formula is in a form of infinite series and needs to sum a large number of terms for satisfactory accuracy. This paper introduces an explicit, approximate expression obtained from the Homotopy Analysis Method on the F-A curve. The proposed F-A curve expression is derived from an SMIB system and verified on the IEEE 3-machine 9-bus system to show how the oscillation frequency of a dominant mode varies with oscillation amplitude under large disturbances.

frequency-amplitude (F-A) curve↗
DOE OSTI2021

Multiscale Simulation of Precipitation Over East Asia by Variable Resolution CAM-MPAS

This study evaluates the precipitation over East Asia simulated by the variable resolution CAM-MPAS featuring the Model for Prediction Across Scales (MPAS) atmospheric dynamical core coupled with the physics parameterizations of the Community Atmosphere Model (CAM) version 5.4. Two CAM-MPAS experiments, one with a global quasi-uniform resolution mesh of 120 km (MPAS-UR) and the other with a variable resolution mesh of 30 to 120 km refined over East Asia (MPAS-VR), are conducted from 1989 to 2005 following the Atmospheric Model Intercomparison Project protocol. Two regional climate model simulations at ~25 km resolution from the Coordinated Regional Downscaling Experiment East Asia second plan are also analyzed for comparison. Results show that CAM-MPAS performs better than the selected regional models in simulating the precipitation climatology over East Asia. Compared with MPAS-UR, MPAS-VR with refinement over East Asia better simulates the precipitation over and around the Tibetan Plateau (TP), the frequency distribution of light, moderate, and heavy precipitation in various regions of China, and the interannual precipitation pattern associated with the East Asian summer monsoon. The improvements in MPAS-VR relative to MPAS-UR largely come from the decreased grid spacing rather than the use of finer-scale terrain information. Particularly, decreased grid spacing is more essential for simulating the precipitation magnitude over TP and the location of peak precipitation south of TP, likely due to the better resolved physical and dynamical processes associated with orographic precipitation. The 30-120 km CAM-MPAS model is shown to be a promising tool for precipitation simulation over East Asia.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Persistent and partially mobile oxygen vacancies in Li-rich layered oxides

Increasing the energy density of layered oxide battery electrodes is challenging as accessing high states of delithiation often triggers voltage degradation and oxygen release. Here we utilize transmission-based X-ray absorption spectromicroscopy and ptychography on mechanically cross-sectioned Li 1.18–x Ni 0.21 Mn 0.53 Co 0.08 O 2–δ electrodes to quantitatively profile the oxygen deficiency over cycling at the nanoscale. The oxygen deficiency penetrates into the bulk of individual primary particles (~200 nm) and is well-described by oxygen vacancy diffusion. Using an array of characterization techniques, we demonstrate that, surprisingly, bulk oxygen vacancies that persist within the native layered phase are indeed responsible for the observed spectroscopic changes. We additionally show that the arrangement of primary particles within secondary particles (~5 μm) causes considerable heterogeneity in the extent of oxygen release between primary particles. Finally, our work merges an ensemble of length-spanning characterization methods and informs promising approaches to mitigate the deleterious effects of oxygen release in lithium-ion battery electrodes.

25 ENERGY STORAGE↗
DOE OSTI2021

A Semi-Analytical Solution Approach for Solving Constant-Coefficient First-Order Partial Differential Equations

Simulation and control of many dynamic systems involve solving partial differential equations (PDE). This letter proposes a semi-analytical solution (SAS) approach for fast and high-quality solution of first-order PDEs. The region of interest of the studied PDE is divided into a grid, and an SAS is derived for each grid cell in the form of the multivariate polynomials, of which the coefficients are identified using initial value and boundary value conditions. The solutions are solved in a “time-stepping” manner, i.e. within one time step, the coefficients of the SAS are identified and the initial value of the next time step is evaluated. This approach achieves a significantly larger grid cell than the widely used finite difference method, and thus enhances the computational efficiency significantly. Furthermore, the simulation result on the natural gas pipeline model demonstrates the advantages of SAS in accuracy and computational efficiency.

97 MATHEMATICS AND COMPUTING↗