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Yamaguchi, A.

Publications and source records attributed to Yamaguchi, A..

30 records · Page 2

Mineralogy of Inverted Pigeonite and Plagioclase in Cumulate Eucrites Y-980433 and Y-980318 with Reference to Early Crust Formation of the Vesta-Like Body

On July 16, the Dawn spacecraft became the first probe to enter orbit around asteroid 4 Vesta and will study the asteroid for a year before departing for Ceres. The Vesta-HED link is directly tied to the observed and inferred mineralogy of the asteroid and the mineralogy of the meteorites [1]. Pieters et al. [2] reported reflectance spectra of the Yamato- (Y-)980318 cumulate eucrite as a part of their study on the Asteroid-Meteorite Links in connection with the Dawn Mission. Pyroxenes and calcic plagioclase are the dominant minerals present in HED meteorites and provide multiple clues about how the parent body evolved [1]. The differentiation trends of HED meteorites are much simpler than those of the lunar crust

Takeda, H.↗

Sm-Nd and Ar-Ar Studies of DHO 908 and 489: Implications for Lunar Crustal History

It is widely assumed that ferroan anorthosites (FANs) formed as flotation cumulates on a global lunar magma ocean (LMO). A corollary is that all FANs are approximately contemporaneous and formed with the same initial Nd-143/Nd-144 ratio. Indeed, a whole rock isochron for selected FANs (and An93 anorthosite) yields an isochron age of 4.42 +/- 0.13 Ga and initial Nd-143/Nd-144, expressed in epsilon-units, of epsilon(sub Nd,CHUR) = 0.3+/-0.3 relative to the CHondritic Uniform Reservoir , or epsilon(sub Nd,HEDPB)=-0.6+/-0.3 relative to the HED Parent Body. These values are in good agreement with the age (T) = 4.47+/-0.07 Ga, and epsilon(sub Nd,HEDPB) =-0.6 +/- 0.5 for FAN 67075. We also have studied anorthositic clasts in the Dhofar 908 and 489 lunar highland meteorites containing clasts of magnesian anorthosites (MAN) with Mg# approximately 75. Because of their relatively high Mg#, magnesian anorthosites should have preceded most FANs in crystallization from the LMO if both are LMO products. Thus, it is important to determine whether the Nd-isotopic data of MAN and FAN are consistent with a co-magmatic origin. We previously reported Sm-Nd data for white clast Dho 908 WC. Mafic minerals in this clast were too small to be physically separated for an isochron. However, we estimated initial Nd-143/Nd-144 for the clast by combining its bulk ("whole rock") Sm-Nd data with an Ar-39-Ar-40 age of 4.42+/-.04 Ga. Here we report additional Sm-Nd data for bulk samples of Dho 908 and its pair Dho 489.

Nyquist, L. E.↗

Comparisons of Mineralogy Between Cumulate Eucrites and Lunar Meteorites Possibly from the Farside Anorsothitic Crust

Anorthosites composed of nearly pure anorthite (PAN) at many locations in the farside highlands have been observed by the Kaguya multiband imager and spectral profiler [1]. Mineralogical studies of lunar meteorites of the Dhofar 489 group [2,3] and Yamato (Y-) 86032 [4], all possibly from the farside highlands, showed some aspects of the farside crust. Nyquist et al. [5] performed Sm-Nd and Ar-Ar studies of pristine ferroan anorthosites (FANs) of the returned Apollo samples and of Dhofar 908 and 489, and discussed implications for lunar crustal history. Nyquist et al. [6] reported initial results of a combined mineralogical/chronological study of the Yamato (Y-) 980318 cumulate eucrite with a conventional Sm-Nd age of 4567 24 Ma and suggested that all eucrites, including cumulate eucrites, crystallized from parental magmas within a short interval following differentiation of their parent body, and most eucrites participated in an event or events in the time interval ~4400- 4560 Ma in which many isotopic systems were partially reset. During the foregoing studies, we recognized that variations in mineralogy and chronology of lunar anorthosites are more complex than those of the crustal materials of the HED parent body. In this study, we compared the mineralogies and reflectance spectra of the cumulate eucrites, Y-980433 and 980318, to those of the Dhofar 307 lunar meteorite of the Dhofar 489 group [2]. Here we consider information from these samples to gain a better understanding of the feldspathic farside highlands and the Vesta-like body.

Takeda, H.↗

Implications for Lunar Crustal Evolution from Y-86032 and Dho 908

We have studied anorthositic clasts in the Y-86032 and Dhofar 908 meteorites by the Rb-Sr, Sm-Nd, and Ar-39-Ar-40 techniques combining isotopic studies with mineralogical/petrological studies of the same clasts. As a result of these studies, we conclude that the lunar crust is composed of a variety of anorthosites, at least some of which must have formed as plutons in the earliest formed ferroan anorthosite crust.

Nyquist, L. E.↗

Lunar Crustal History from Isotopic Studies of Lunar Anorthosites

Anorthosites occur ubiquitously within the lunar crust at depths of approx.3-30 km in apparent confirmation of the Lunar Magma Ocean (LMO) hypothesis. [1]. We will present recent chronological studies of anorthosites [2] that are relevant both to the LMO hypothesis and also to the lunar cataclysm hypothesis. Old (approx.4.4 Ga) Sm-Nd ages have been determined for some Apollo 16 anorthosites, and primitive initial Sr-87/Sr-86 ratios have been measured for several, but well-defined Rb-Sr ages concordant with the Sm-Nd ages have not been determined until now. Lunar anorthosite 67075, a Feldspathic Fragmental Breccia (FFB) collected near the rim of North Ray Crater, has concordant Sm-Nd and Rb-Sr ages of 4.47+/-0.07 Ga and 4.49+/-0.07 Ga, respectively. Initial Nd-143/Nd-144 determined from the Sm-Nd isochron corresponds to E(sub Nd,CHUR) = 0.3+/-0.5 compared to a Chondritic Uniform Reservoir, or E(sub Nd,HEDPB) = -0.6+/-0.5 compared to the initial Nd-143/Nd-144 of the HED Parent Body [3]. Lunar anorthosites tend to have E(sub Nd) > 0 when compared to CHUR, apparently inconsistent with derivation from a single lunar magma ocean. Although E(sub Nd) < 0 for some anorthosites, if lunar initial Nd-143/Nd-144 is taken equal to HEDR for the HED parent body [3], enough variability remains among the anorthosite data alone to suggest that lunar anorthosites do not derive from a single source, i.e., they are not all products of the LMO. An anorthositic clast from desert meteorite Dhofar 908 has an Ar-39-Ar-40 age of 4.42+/-0.04 Ga, the same as the 4.36-4.41+/-0.035 Ga Ar-39-Ar-40 age of anorthositic clast Y-86032,116 in Antarctic meteorite Yamato- 86032 [3,4]. Conclusions: (i) Lunar anorthosites come from diverse sources. Orbital geochemical studies confirm variability in lunar crustal composition [1, 5]. We suggest that the variability extends to anorthosites alone as shown by the Sm-Nd data (Fig. 2) and the existence of magnesian anorthosites (MAN, [6]) and "An93 anorthosites" [3,4]. (ii) Anorthositic clasts in lunar meteorites retain "high" Ar-Ar ages compared to Apollo anorthosites. This is perhaps a hint that "cataclysmic" impacts were on average less energetic in the mostly farside source regions of these meteorites than on the lunar nearside.

Nyquist, Laurence E.↗

Lunar Crustal History Recorded in Lunar Anorthosites

Anorthosites occur ubiquitously within the lunar crust at depths of ~3-30 km in apparent confirmation of the Lunar Magma Ocean (LMO) hypothesis. We have dated lunar anorthosite 67075, a Feldspathic Fragmental Breccia (FFB) collected near the rim of North Ray Crater by the Sm-Nd and Rb-Sr techniques. We also have dated an anorthositic white clast (WC) in lunar meteorite Dhofar 908 by the Ar-39-Ar-40 technique and measured whole rock (WR) Sm-Nd data for a companion sample. We discuss the significance of the ages determined for these and other anorthosites for the early magmatic and bombardment history of the moon.

Nyquist, Laurence E.↗

Basaltic Clasts in Y-86032 Feldspathic Lunar Meteorite: Ancient Volcanism far from the Procellarum Kreep Terrane

Lunar meteorite, Y-86032 is a fragmental or regolith breccia enriched in Al2O3 (28-31 wt%) and having very low concentrations of REEs and Th, U [e.g., 1]. Nyquist et al. [2] suggested that Y- 86032 contains a variety of lithologies not represented by the Apollo samples. They found clasts with old Ar-Ar ages and an ancient Sm-Nd age, and negative Nd indicating a direct link to the primordial magma ocean. Importantly, the final lithification of the Y-86032 breccia was likely >3.8-4.1 Ga ago. Therefore, any lithic components in the breccia formed prior to 3.8 Ga, and lithic components in breccia clasts in the parent breccia formed even earlier. Here we report textures and mineralogy of basaltic and gabbroic clasts in Y- 86032 to better understand the nature of ancient lunar volcanism far from the Procellarum KREEP Terrain (PKT) [3] and the central nearside.

Yamaguchi, A.↗

Feldspathic Clasts in Yamato 86032: Remnants of the Lunar Crust with Implications for its Formation and Impact History

Yamato (Y)-86032 is a relatively large, feldspathic lunar highlands meteorite composed of a variety of highland lithologies. Low bulk contents of Th and Fe indicated that it came from a region of the moon far distant from the Procellarum KREEP Terrain (PKT) and the Apollo landing sites, perhaps from the farside. A large (5.2 x 3.6 cm) slab was cut from Y-86032 . We report results from coordinated textural, mineralogical-petrological, chemical, and isotopic studies of lithologies identified in the slab, emphasizing the results of Ar-39/Ar-40, Rb-Sr, and Sm-Nd chronological studies as well as Sm-isotopic studies. These studies characterize the history of Y-86032 and its precursors in the farside mega-regolith, leading to inferences about the formation and evolution of the lunar crust. Textural studies establish that the Y-86032 breccia is composed of a variety of highland components including feldspathic breccias, and other components, such as possible VLT mare basalts. Impact melt veins smoothly abut the other lithologies. Thus, Y-86032 experienced at least two impact events. These impacts occurred on a predominantly feldspathic protolith, which formed 4.43+/-0.03 Ga ago as determined from a Sm-Nd isochron for mineral clasts separated from the two dominant lithologies. Initial Nd-143/Nd-144 in the protolith at that time was -0.64+/-0.13 epsilon-units below Nd-143/Nd-144 in reservoirs having chondritic Sm/Nd ratios, consistent with prior fractionation of mafic cumulates from the LMO. Although the mineral chemistry of these clasts differs in detail from that of minerals in Apollo 16 Ferroan Anorthosites (FANs), the Rb-Sr studies establish that the initial Sr-87/Sr-86 in them was the same as in the FANs.

Nyquist, L.↗

Rb-Sr and Sm-Nd Isotopic Studies of Lunar Highland Meteorite Y86032 and Lunar Ferroan Anorthosites 60025 and 67075

Lunar meteorite Yamato (Y) 86032 is a feldspathic breccia containing anorthositic fragments similar to ferroan anorthosite (FAN) clasts commonly found in Apollo 16 highland rocks. Previous Ar-39-Ar-40 analyses of a grey anorthositic clast (,116 GC) in Y86032 revealed an old degassing age of 4.39 plus or minus 0.06 Ga, which is as old as crystallization ages of some FANs e.g. 60025, 67016 and 67215, as determined by the more robust Sm-Nd radiometric method. The calculated initial Nd value for the clast is -1.8 plus or minus 0.3 for the age. The old age and its negative initial Nd value indicate that Y86032 contains components of the primitive lunar crust related to the lunar magma ocean (LMO). We undertook further Rb-Sr and Sm-Nd isotopic investigation of three major lithologies in the meteorite as described in the mineralogical and petrological studies. Ar-39-Ar-40 analyses of these component lithologies are presented in this volume. Also, we analyzed two Apollo 16 FANs, 60025 and 67075, to compare their ages and isotopic signatures to Y86032. Y86032 probably came from a feldspathic highland terrane (FHT) on the northern farside highlands, a locality not sampled by the Apollo and Luna missions.

Shih, C.-Y.↗

The Origin and Impact History of Lunar Meteorite Yamato 86032

Yamato (Y) 86032 is a feldspathic lunar highland breccia having some characteristics of regolith breccia. The absence of KREEP components in the matrix in Y86032 indicates that these meteorites came from a long distance from Mare Imbrium, perhaps from the far-side of the moon. One ferroan anorthosite (FAN) clast in Y86032 has a very old Ar-Ar age of approximately 4.35-4.4 Ga. The negative Nd of this clast may suggest a direct link with the primordial magma ocean. The facts indicate that Y86032 contains components derived from a protolith of the original lunar crust. Detailed petrologic characterization of each component in this breccia is essential to understand the early impact history and origin of the lunar highland crust. We made a large slab (5.2 x 3.6 cm x 3-5 mm) of Y86032 to better understand the relationship of various lithologies and their petrologic origin.

Yamaguchi, A.↗

Carbonates in fractures of Martian meteorite Allan Hills 84001: petrologic evidence for impact origin

Carbonates in Martian meteorite Allan Hills 84001 occur as grains on pyroxene grain boundaries, in crushed zones, and as disks, veins, and irregularly shaped grains in healed pyroxene fractures. Some carbonate disks have tapered Mg-rich edges and are accompanied by smaller, thinner and relatively homogeneous, magnesite microdisks. Except for the microdisks, all types of carbonate grains show the same unique chemical zoning pattern on MgCO3-FeCO3-CaCO3 plots. This chemical characteristic and the close spatial association of diverse carbonate types show that all carbonates formed by a similar process. The heterogeneous distribution of carbonates in fractures, tapered shapes of some disks, and the localized occurrence of Mg-rich microdisks appear to be incompatible with growth from an externally derived CO2-rich fluid that changed in composition over time. These features suggest instead that the fractures were closed as carbonates grew from an internally derived fluid and that the microdisks formed from a residual Mg-rich fluid that was squeezed along fractures. Carbonate in pyroxene fractures is most abundant near grains of plagioclase glass that are located on pyroxene grain boundaries and commonly contain major or minor amounts of carbonate. We infer that carbonates in fractures formed from grain boundary carbonates associated with plagiociase that were melted by impact and dispersed into the surrounding fractured pyroxene. Carbonates in fractures, which include those studied by McKay et al. (1996), could not have formed at low temperatures and preserved mineralogical evidence for Martian organisms.

Carbonates/analysis↗

Inhomogeneous distribution of materials in lodranites-acapulcoites and IAB irons and their common formation processes

The two-dimensional chemical mapping analysis (CMA) techniques of EPMA and XRF were applied to a new polished thin section (PTS) of EET84302,28, Acapulco and a 5x3 cm slice of Caddo County to find heterogeneous regional distribution of low temperature fractions in the lodranite-acapulcoite groups and silicate inclusions in the IAB irons. A region richer in metal-plagioclase was found in EET84302,28 and Caddo County. The mineralogy of EET84302,28 is not much different from coarse-grained, metal-rich acapulcoite-like mineral assemblage in EET84302,19, which has chromite-orthopyroxene segregation. Nearly uniform Mg/Fe ratios of silicates modified by reduction at regional oxygen fugacity and large difference in modal abundances of minerals in this meteorite group can be explained by regional concentration of materials when the source materials were partly melted.

Takeda, Hiroshi↗