Engineering topics

Yang, Bin

Publications and source records attributed to Yang, Bin.

3 records

DOE OSTI2024

A simultaneous depolymerization and hydrodeoxygenation process to produce lignin-based jet fuel in continuous flow reactor

Economical production of lignin-based jet fuel (LJF) can improve the sustainability of sustainable aviation fuels (SAFs) as well as can reduce the overall greenhouse gas emissions. However, the challenge lies in converting technical lignin polymer from biorefinery directly to jet fuel in a continuous operation. In this work, we demonstrate a simultaneous depolymerization and hydrodeoxygenation (SDHDO) process to produce lignin-based jet fuel from the alkali corn stover lignin (ACSL) using engineered Ru-HY-60-MI catalyst in a continuous flow reactor at first time. The maximum carbon yield of LJF of 17.9wt% was obtained, and it comprised of 60.2wt% monocycloalkanes, and 21.6wt% polycycloalkanes. Catalyst characterization of Ru-HY-60-MI suggested there was no significant change in HY zeolite structure and its crystallinity after catalyst engineering. Catalyst characterizations performed post the SDHDO experiments indicate presence of carbon and K content in the catalyst. K content presence in the spent catalyst was due to K + ion was exchanged between lignin solution and HY-60 while carbon presence validated the SDHDO chemistry on the catalyst surface. Tier a fuel property testing indicates that LJF production using SDHDO chemistry can offer SAF with high compatibility, good sealing properties, low emissions, and high energy density for aircraft.

09 BIOMASS FUELS↗

DOE OSTI2024

Selective phosphate removal with manganese oxide composite anion exchange membranes in membrane capacitive deionization

The discharge of excessive phosphorous into water bodies can lead to serious eutrophication threatening aquatic ecosystem. Membrane capacitive deionization (MCDI) is an effective platform for deionizing aqueous streams; however, conventional MCDI is unable to selectively remove targeted ions from a liquid mixture. Here, in this work, we fabricated manganese oxide composite anion exchange membranes (AEMs) for MCDI to enhance phosphate removal selectivity from sodium chloride-sodium dihydrogen phosphate (10:1 M ratio) aqueous mixtures. We systematically investigated several critical factors, such as constant current or voltage operation, applied voltage amount, process stream pH, and manganese oxide (Mn 2 O 3 ) content in the AEM, on phosphate removal efficiency and phosphate selectivity. A trade-off was observed between phosphate removal and selectivity when increasing the cell voltage. Under the best conditions, a MCDI unit with a 20 wt% Mn 2 O 3 composite AEM and a bipolar membrane facilitated high phosphate removal efficiency of ≥ 31.8 % and a phosphate over chloride selectivity of 1.1 while showing stability for at least 30 cycles. To help understand how Mn 2 O 3 composite AEM boosts phosphate selectivity, static electronic structure calculations were performed, and they revelated that hydrogen phosphate absorption on Mn 2 O 3 composite AEM was 314 kcal/mol more exothermic than that on pristine AEM while chloride adsorption on Mn 2 O 3 composite AEM was 2.2 kcal/mol less exothermic than that on a pristine AEM. Overall, this work presents an effective strategy for selectively removing phosphate from model wastewater solutions and the mechanistic understanding that governs ion selectivity in composite ion-exchange membranes used in MCDI.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2018

Implications of Whole-Disc DSCOVR EPIC Spectral Observations for Estimating Earth's Spectral Reflectivity Based on Low-Earth-Orbiting and Geostationary Observations

Earth's reflectivity is among the key parameters of climate research. National Aeronautics and Space Administration (NASA)'s Earth Polychromatic Imaging Camera (EPIC) onboard National Oceanic and Atmospheric Administration (NOAA)'s Deep Space Climate Observatory (DSCOVR) spacecraft provides spectral reflectance of the entire sunlit Earth in the near backscattering direction every 65 to 110 min. Unlike EPIC, sensors onboard the Earth Orbiting Satellites (EOS) sample reflectance over swaths at a specific local solar time (LST) or over a fixed area. Such intrinsic sampling limits result in an apparent Earth's reflectivity. We generated spectral reflectance over sampling areas using EPIC data. The difference between the EPIC and EOS estimates is an uncertainty in Earth's reflectivity. We developed an Earth Reflector Type Index (ERTI) to discriminate between major Earth atmosphere components: clouds, cloud-free ocean, bare and vegetated land. Temporal variations in Earth's reflectivity are mostly determined by clouds. The sampling area of EOS sensors may not be sufficient to represent cloud variability, resulting in biased estimates. Taking EPIC reflectivity as a reference, low-earth-orbiting-measurements at the sensor-specific LST tend to overestimate EPIC values by 0.8% to 8%. Biases in geostationary orbiting approximations due to a limited sampling area are between −0.7% and 12%. Analyses of ERTI-based Earth component reflectivity indicate that the disagreement between EPIC and EOS estimates depends on the sampling area, observation time and vary between −10% and 23%.

DSCOVR↗