Yang, Sung-Chul | Search NASA

NASA NTRS1992

Generic grain size distribution for liquid phase sintering

In order to develop an empirical model to represent a generic grain size distribution for liquid phase sintering, experimental data and theoretical models are analyzed using the plot of standard normal vs normalized size. From the experimental 3D grain size plot, the most representative line is deduced. The line best fits the Lifshitz-Slyozov encounter modified model except for the small size ranges of the lower 15 percent of the distribution. It is shown that grain coalescence might be a cause for this departure from theory.

German, R. M.↗

NASA NTRS1991

Grain growth kinetics in liquid-phase-sintered zinc oxide-barium oxide ceramics

Grain growth of ZnO in the presence of a liquid phase of the ZnO-BaO system has been studied for temperatures from 1300 to 1400 C. The specimens were treated in boiling water and the grains were separated by dissolving the matrix phase in an ultrasonic bath. As a consequence 3D grain size measurements were possible. Microstructural examination shows some grain coalescence with a wide range of neck size ratios and corresponding dihedral angles, however, most grains are isolated. Lognormal grain size distributions show similar shapes, indicating that the growth mechanism is invariant over this time and temperature. All regressions between G exp n and time for n = 2 and 3 proved statistically significant. The rate constants calculated with the growth exponent set to n = 3 are on the same order of magnitude as in metallic systems. The apparent activation energy for growth is estimated between 355 and 458 kJ/mol.

Yang, Sung-Chul↗