On the theory of combustion of initially unmixed gases
The chemical reaction of two substances (fuel and oxygen) accompanied by the formation of new substances of the products of combustion and the liberation of heat is considered.
Engineering topics
Publications and source records attributed to Zeldovich, Y B.
The chemical reaction of two substances (fuel and oxygen) accompanied by the formation of new substances of the products of combustion and the liberation of heat is considered.
The mechanism of flame propagation has been qualitatively formulated. In accordance with this formulation, the chemical reaction initiated in some layer brings about an increase in the temperature; because of the heat conduction, the temperature is raised in the neighboring layer where in turn the chemical reaction is initiated. In this manner the flame is propagated.
The existing theory of detonation is critically examined. It is shown that the considerations with which the steady value of the velocity of detonation is chosen are not convincing. In connection with the problem of the process of the chemical reaction in a detonation wave, the objections raised against the conceptions of Le Chatelier and Vieille of the 19th century with regard to the ignition of the gas by the shock wave are refuted. On the basis of this concept, it is possible to give a rigorous foundation for the existing method of computing the detonation velocity. The distributions of the temperature, the pressure, and the velocity in the detonation wave front as the chemical reaction proceeds, are considered. On the assumption of the absence of losses, the pure compression of the gas in the shock wave at the start of the chemical reaction develops a temperature that is near the temperature of combustion of the given mixture at constant pressure.