Particle phase-state variability in the North Atlantic free troposphere during summertime is determined by atmospheric transport patterns and sources
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54 ENVIRONMENTAL SCIENCES↗
Engineering topics
Zhang, Bo
Publications and source records attributed to Zhang, Bo.
Self-Assembly of Partially Charged Diblock Copolymer-Homopolymer Ternary Blends
Ternary blends comprising of a diblock copolymer and the corresponding homopolymers provide ready access to a variety of morphologies, but the impact of charge on their phase behavior has not been studied extensively. Here, three partially charged ternary blends consisting of symmetric poly[(oligo(ethylene glycol) methyl ether methacrylate-co-oligo(ethylene glycol) propyl sodium sulfonate methacrylate)] (POEGMA#), polystyrene (PS), and POEGMA#-PS with different charge fractions were prepared, where # denotes the mole fraction of charged monomers in the POEGMA chain. Here, the phase behavior was systematically studied using small-angle X-ray scattering (SAXS), and isothermal phase diagrams at 120 °C were constructed. The resulting isothermal planes contain a wide lamellar (LAM) phase window with a slight deviation from symmetry for ion-containing ternary blends, due to the homopolymer size difference. Given the absence of any significant change in the phase diagrams as the charge fraction increases, the role of charge is primarily to increase the segregation strength in the ternary system, as in the case of partially charged diblock polymers. In addition, examination of the increase in domain size along the volumetrically symmetric isopleth reveals a “dry-brush” like swelling behavior of homopolymers in all three blends, presumably due to the space-filling nature of the oligomeric ethylene glycol side chains on POEGMA.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Hyperuniform Active Chiral Fluids with Tunable Internal Structure
Large density fluctuations observed in active systems and hyperuniformity are two seemingly incompatible phenomena. However, the formation of hyperuniform states has been recently predicted in nonequilibrium fluids formed by chiral particles performing circular motion with the same handedness. In this work, we report evidence of hyperuniformity realized in a chiral active fluid comprised of pear-shaped Quincke rollers of arbitrary handedness. We show that hyperunifonnity and large density fluctuations, triggered by dynamic clustering, coexist in this system at different length scales. The system loses its hyperuniformity as the curvature of particles' motion increases, transforming them into localized spinners. Our results experimentally demonstrate a novel hyperuniform active fluid and provide new insights into an interplay between chirality, activity, and hyperuniformity.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Assembling Portable In-Situ Workflow from Heterogeneous Components using Data Reorganization.
Abstract not provided.
Zhang, Bo↗
ROS-Ethereum: A Convenient Tool to Bridge ROS and Blockchain (Ethereum)
Robot Operating System (ROS) has received widespread utilization with the development of robotics, self-driving, etc., recently. Meanwhile, the other technology blockchain is frequently applied to various fields with its trustworthy characteristics and immutability in data storage. However, ROS has no ability to interact with the blockchain, which hinders research in related fields. Therefore, we wonder if we can develop a convenient tool to bridge ROS and blockchain. Inspired by this, we propose ROS-Ethereum. It bridges ROS and Ethereum, a widely used blockchain platform. ROS-Ethereum is based on the User Datagram Protocol (UDP) communication mechanism and the SM algorithm family along with Ethereum technology. Simply put, ROS-Ethereum allows users to invoke the contract when interacting with the blockchain, which makes this process easier and safer. We conduct experiments in real robots to verify the effectiveness of ROS-Ethereum and evaluate it from the following metrics: (1) the encryption efficiency and stability of the algorithm and (2) ROS-Ethereum transaction response time and packet loss rate.
Zhang, Shenhui↗
Nondestructive Photo-Cross-Linking of Microphase-Separated Diblock Polymers through Coumarin Dimerization
The effect of long-wavelength ultraviolet photocrosslinking on microphase-separated coumarin-containing block polymers was studied by photo-rheometry and small-angle X-ray scattering. This model system consisted of three photocrosslinkable diblock polymers of poly(methoxyethyl acrylate)-b-poly(hexyl methacrylate-co-coumarin methacrylate) with different volume fractions of the crosslinkable coumarin-containing block, which microphase separated into lamellar and cylindrical morphologies. All polymers stiffened upon exposure to 365 nm light, with much greater relative increases in moduli recorded for lamellae-forming polymers (ca. 3200% increase) compared to the cylinder-forming polymer (ca. 550% increase). Disordering transitions that were evident in uncrosslinked samples were no longer observed after crosslinking in the ordered state, and domain sizes were found to remain stable to heating. The photocrosslinking reaction only proceeded under active irradiation, indicating a high degree of spatiotemporal control over curing in this system. Finally, at constant concentration of couamarin within the crosslinkable block, the cure rate was largely independent of polymer composition, suggesting a constant local concentration of coumarin moieties within the segregated crosslinkable domains. Lastly, these findings establish a set of specific structure-property relationships governing the phase-selective photocrosslinking of diblock polymers that can guide the design of robust nanostructured materials.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Assembling Portable In-Situ Workflow from Heterogeneous Components using Data Reorganization.
Abstract not provided.
Zhang, Bo↗
Electric Grid Supply Chain Review: Large Power Transformers and High Voltage Direct Current Systems
The report “America’s Strategy to Secure the Supply Chain for a Robust Clean Energy Transition” lays out the challenges and opportunities faced by the United States in the energy supply chain as well as the federal government plans to address these challenges and opportunities. It is accompanied by several issue-specific deep dive assessments, including this one, in response to Executive Order 14017 “America’s Supply Chains,” which directs the Secretary of Energy to submit a report on supply chains for the energy sector industrial base. The Executive Order is helping the federal government to build more secure and diverse U.S. supply chains, including energy supply chains. The need to modernize and increase the capacity of the U.S. power grid is increasing due to growing population, aging infrastructure, grid resilience requirements, operational flexibility needs, and a growing portfolio of renewable energy. As part of the Paris Climate Agreement the United States has committed to reducing its net greenhouse gas emissions by 50 to 52 percent below 2005 levels in 2030 and has set a goal of 100 percent carbon pollution free electricity by 2035 (The United States of America Nationally Determined Contribution, 2021). Meeting these targets will require a significant expansion of the power system to integrate a large amount of new renewable resources (United States Department of State & United States Executive Office of the President, 2021). However, many critical components supporting the power grid have limited to no domestic manufacturing capacity and face complex challenges in supporting a rapid expansion of the grid to meet multiple objectives, including decarbonization goals. This report focuses on two key grid components: large power transformers (LPTs) and high-voltage direct current (HVDC) transmission.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Towards Optimal and Executable Distribution Grid Restoration Planning With a Fine-Grained Power-Communication Interdependency Model
Distribution service restoration (DSR) under natural disasters is always a critical and challenging problem for utility companies. An effective solution must not ignore the power-communication interdependency as various systems are getting increasingly connected in the Smart Grid era. In this paper, we propose a two-layer distribution system model with both power and communication components. Based on this model, we formulate the restoration process as a routing problem that schedules the path and action sequence of utility crews that involves repairing damaged components, closing power switches, and enabling communication paths between the control center and remote field devices. Further, we develop a simulation-based method to quantitatively evaluate the restoration process with public reference models of large-scale power systems. The experimental results show that our method improves the total restored energy up to 57.6% and reduces the recovery time up to 63% by considering the power-communication interdependency.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Guiding Self-Assembly of Active Colloids by Temporal Modulation of Activity
Self-organization phenomena in ensembles of self-propelled particles open pathways to the synthesis of new dynamic states not accessible by traditional equilibrium processes. The challenge is to develop a set of principles that facilitate the control and manipulation of emergent active states. In this study, we report that dielectric rolling colloids energized by a pulsating electric field self-organize into alternating square lattices with a lattice constant controlled by the parameters of the field. We combine experiments and simulations to examine spatiotemporal properties of the emergent collective patterns and investigate the underlying dynamics of the self-organization.We reveal the resistance of the dynamic lattices to compression and expansion stresses leading to a hysteretic behavior of the lattice constant. The general mechanism of pattern synthesis and control in active ensembles via temporal modulation of activity can be applied to other active colloidal systems.
36 MATERIALS SCIENCE↗
Polar state reversal in active fluids
Spontaneous emergence of correlated states such as flocks and vortices is a prime example of collective dynamics and self-organization observed in active matter. In geometrically confined systems, the formation of globally correlated polar states proceeds through the emergence of a macroscopic steadily rotating vortex, which spontaneously selects a clockwise or counterclockwise global chiral state. In this work, we reveal that a global vortex formed by colloidal rollers exhibits polar state reversal and that a subsequent formation of the collective states upon re-energizing the system is not random. We combine experiments and simulations to elucidate how a combination of hydrodynamic and electrostatic interactions leads to hidden asymmetries in the local particle positional order, reflecting the chiral state of the system. These asymmetries can be exploited to systematically command subsequent polar states of active liquids through temporal control of the activity.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Aerosol Composition, Mixing State, and Phase State of Free Tropospheric Particles and Their Role in Ice Cloud Formation
The prediction of ice cloud formation in the atmosphere remains challenging. Free tropospheric aerosols can act as ice nucleating particles (INPs), affecting cloud properties and precipitation. The physicochemical properties of free tropospheric particles are modified upon long-range transport by different atmospheric processes. These modifications affect the ice formation potential of individual particles. We investigated free tropospheric particles collected at the remote Pico Mountain Observatory at 2225m a.s.l. in the North Atlantic Ocean using multimodal microspectroscopy and chemical imaging techniques. We probed their ice nucleation activity using an ice nucleation stage interfaced with an environmental scanning electron microscope. Retroplume analysis, chemical imaging, and micro-spectroscopy analysis indicated that the size-resolved chemical composition, mixing state, and phase state of the articles with similar aging times but different transport patterns were substantially different. Relative humidity-dependent glass transition temperatures estimated from meteorological conditions were consistent with the observed organic component of the particles' phase. More viscous (solid and semi-solid-like) particles are more ice active in deposition mode at temperature ranging from 205-220 K than those less viscous particles. Finally, this study provides a better understanding of the phase and mixing state of long range transported free tropospheric aerosols and their role in ice cloud formation.
54 ENVIRONMENTAL SCIENCES↗
Aerosol responses to precipitation along North American air trajectories arriving at Bermuda
North American pollution outflow is ubiquitous over the western North Atlantic Ocean, especially in winter, making this location a suitable natural laboratory for investigating the impact of precipitation on aerosol particles along air mass trajectories. We take advantage of observational data collected at Bermuda to seasonally assess the sensitivity of aerosol mass concentrations and volume size distributions to accumulated precipitation along trajectories (APT). The mass concentration of particulate matter with aerodynamic diameter less than 2.5 µm normalized by the enhancement of carbon monoxide above background (PM 2.5 /ΔCO) at Bermuda was used to estimate the degree of aerosol loss during transport to Bermuda. Results for December–February (DJF) show that most trajectories come from North America and have the highest APTs, resulting in a significant reduction (by 53 %) in PM 2.5 /ΔCO under high-APT conditions (> 13.5 mm) relative to low-APT conditions (< 0.9 mm). Moreover, PM 2.5 /ΔCO was most sensitive to increases in APT up to 5 mm (–0.044 µg m –3 ppbv –1 mm –1 ) and less sensitive to increases in APT over 5 mm. While anthropogenic PM 2.5 constituents (e.g., black carbon, sulfate, organic carbon) decrease with high APT, sea salt, in contrast, was comparable between high- and low-APT conditions owing to enhanced local wind and sea salt emissions in high-APT conditions. The greater sensitivity of the fine-mode volume concentrations (versus coarse mode) to wet scavenging is evident from AErosol RObotic NETwork (AERONET) volume size distribution data. A combination of GEOS-Chem model simulations of the 210 Pb submicron aerosol tracer and its gaseous precursor 222 Rn reveals that (i) surface aerosol particles at Bermuda are most impacted by wet scavenging in winter and spring (due to large-scale precipitation) with a maximum in March, whereas convective scavenging plays a substantial role in summer; and (ii) North American 222 Rn tracer emissions contribute most to surface 210 Pb concentrations at Bermuda in winter (~75 %–80 %), indicating that air masses arriving at Bermuda experience large-scale precipitation scavenging while traveling from North America. A case study flight from the ACTIVATE field campaign on 22 February 2020 reveals a significant reduction in aerosol number and volume concentrations during air mass transport off the US East Coast associated with increased cloud fraction and precipitation. These results highlight the sensitivity of remote marine boundary layer aerosol characteristics to precipitation along trajectories, especially when the air mass source is continental outflow from polluted regions like the US East Coast.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Aerosol Composition, Mixing State, and Phase State of Free Tropospheric Particles and Their Role in Ice Cloud Formation
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54 ENVIRONMENTAL SCIENCES↗
LAMOST Time-Domain survey: first results of four K2 plates
From Oct. 2019 to Apr. 2020, LAMOST performed a time-domain (TD) spectroscopic survey of four K2 plates with both low- and medium-resolution observations. The low-resolution spectroscopic survey acquired 282 exposures ( ≈ 46.6 h) over 25 nights, yielding a total of about 767 000 spectra, and the medium-resolution survey took 177 exposures ( ≈ 49.1 h) over 27 nights, collecting about 478 000 spectra. More than 70%/50% of low-resolution/medium-resolution spectra have signal-to-noise ratio higher than 10. We determine stellar parameters (e.g., T eff , log g, [Fe/H]) and radial velocity (RV) with different methods, including LASP, DD-Payne and SLAM. In general, these parameter estimations from different methods show good agreement, and the stellar parameter values are consistent with those of APOGEE. We use the Gaia DR2 RV values to calculate a median RV zero point (RVZP) for each spectrograph exposure by exposure, and the RVZP-corrected RVs agree well with the APOGEE data. The stellar evolutionary and spectroscopic masses are estimated based on the stellar parameters, multi-band magnitudes, distances and extinction values. Finally, we construct a binary catalog including about 2700 candidates by analyzing their light curves, fitting the RV data, calculating the binarity parameters from medium-resolution spectra and cross-matching the spatially resolved binary catalog from Gaia EDR3. In conclusion, the LAMOST TD survey is expected to represent a breakthrough in various scientific topics, such as binary systems, stellar activity, stellar pulsation, etc.
79 ASTRONOMY AND ASTROPHYSICS↗
Quasi-Dynamic Electromagnetic Field Safety Analysis and Mitigation for High-Power Dynamic Wireless Charging of Electric Vehicles
Dynamic wireless charging of electric vehicles (EV) is an emerging charging technology to enable non-contact wireless charging while the vehicle is moving. Compared to stationary wireless charging, in-motion wireless charging involves dynamic processes in which an EV is passing over the charging pads (transmitters). This in motion process makes the dynamic electromagnetic (EM) environment more complicated, and EM safety needs to be ensured under all circumstances. This is due to the fact that the entire vehicle body may be exposed to magnetic fields while the vehicle moves over the energized transmitter. This paper investigates several typical charging scenarios when EVs approach, pass over, and move away from the charging pads. Quasi-dynamic models, which are preliminarily verified by coils’ inductance measurements, are developed to analyze the dynamic process. Based on the quasi-dynamic analysis, shielding solutions are also studied to ensure EM safety for the dynamic wireless charging processes.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Design and Performance of Kokkos Staging Space toward Scalable Resilient Application Couplings
With the growing number of applications designed for heterogeneous HPC devices, application programmers and users are finding it challenging to compose scalable workflows as ensembles of these applications, that are portable, performant and resilient. The Kokkos C++ library has been designed to simplify this cumbersome procedure by providing an intra-application uniform programming model and portable performance. However, assembling multiple Kokkos-enabled applications into a complex workflow is still a challenge. Although Kokkos enables a uniform programming model, the inter-application data exchange still remains a challenge from both performance and software development cost perspectives. In order to address this issue, we propose Kokkos data staging memory space, an extension of Kokkos' data abstraction (memory space) for heterogeneous computing systems. This new abstraction allows to express data on a virtual shared-space for multiple Kokkos applications, thus extending Kokkos to support inter-application data exchange to build an efficient application workflow. Additionally, we study the effectiveness of asynchronous data layout conversions for applications requiring different memory access patterns for the shared data. Our preliminary evaluation with a synthetic benchmark indicate the effectiveness of this conversion adapted to three different scenarios representing access frequency and use patterns of the shared data.
97 MATHEMATICS AND COMPUTING↗
Influence of Charge Fraction on the Phase Behavior of Symmetric Single-Ion Conducting Diblock Copolymers
A series of symmetric poly[(oligo(ethylene glycol) methyl ether methacrylate-co-oligo(ethylene glycol) propyl sodium sulfonate methacrylate)]-block-polystyrene (PsOEGMA-PS) diblock copolymers were synthesized as a model system to probe the effect of charge fraction on the phase behavior of charged-neutral single-ion conducting diblock copolymers. Small-angle X-ray scattering (SAXS) experiments showed that increasing the charge fraction does not alter the ordered phase morphology (lamellar) but increases the order–disorder transition temperature (T ODT ) significantly. Additionally, the effective Flory–Huggins interaction parameter (χ eff ) was found to increase linearly with the charge fraction, similar to the case of conventional salt-doped diblock copolymers. This indicates that the effect of counterion solvation, attributed to the significant mismatch between the dielectric constant of each block, provides the dominant effect in tuning the phase behavior of this charged diblock copolymer. Lastly, we therefore infer that electrostatic cohesion (local charge ordering induced by Coulombic interactions), which is predicted to suppress microphase separation and lead to asymmetric phase diagrams, only plays a minor role in this model system.
36 MATERIALS SCIENCE↗