Oxygen Vacancy-Induced Room Temperature Ferromagnetism in Rutile TiO{sub 2}
As oxygen vacancies play an important role in ferromagnetism of rutile TiO{sub 2}, a method of γ-ray irradiates rutile TiO{sub 2} single crystals was subtly proposed to study the effect of oxygen vacancies on magnetic properties. Remarkably, room temperature ferromagnetism was observed in γ-ray irradiated rutile TiO{sub 2} single crystals, and the saturation magnetization is the strongest when dose is 4 × 10{sup 4} Gy which assigned to ESR results. Since the displacement threshold energy of Ti atom is much bigger than that of O atom, the defects produced by γ-irradiation are mainly oxygen vacancies. After irradiation, XPS, PL spectra indicate the presence of oxygen vacancies(V{sub O}), Ti{sup 3+}, and V{sub O}-Ti{sup 3+} composite defects.