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Zhang, Xiaochen

Publications and source records attributed to Zhang, Xiaochen.

Rapid QSTS Simulations for High-Resolution Comprehensive Assessment of Distributed PV

The rapid increase in penetration of distributed energy resources on the electric power distribution system has created a need for more comprehensive interconnection modeling and impact analysis. Unlike conventional scenario-based studies, quasi-static time-series (QSTS) simulations can realistically model time-dependent voltage controllers and the diversity of potential impacts that can occur at different times of year. However, to accurately model a distribution system with all its controllable devices, a yearlong simulation at 1-second resolution is often required, which could take conventional computers a computational time of 10 to 120 hours when an actual unbalanced distribution feeder is modeled. This computational burden is a clear limitation to the adoption of QSTS simulations in interconnection studies and for determining optimal control solutions for utility operations. The solutions we developed include accurate and computationally efficient QSTS methods that could be implemented in existing open-source and commercial software used by utilities and the development of methods to create high-resolution proxy data sets. This project demonstrated multiple pathways for speeding up the QSTS computation using new and innovative methods for advanced time-series analysis, faster power flow solvers, parallel processing of power flow solutions and circuit reduction. The target performance level for this project was achieved with year-long high-resolution time series solutions run in less than 5 minutes within an acceptable error.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A stable low-temperature H 2 -production catalyst by crowding Pt on α-MoC

The water-gas shift (WGS) reaction is an industrially important source of pure hydrogen (H 2 ) at the expense of carbon monoxide and water. This reaction is of interest for fuel-cell applications, but requires WGS catalysts that are durable and highly active at low temperatures. Here we demonstrate that the structure (Pt 1 Pt n )/α-MoC, where isolated platinum atoms (Pt 1 ) and subnanometre platinum clusters (Pt-n) are stabilized on alpha-molybdenum carbide (α-MoC), catalyses the WGS reaction even at 313 kelvin, with a hydrogen-production pathway involving direct carbon monoxide dissociation identified. We find that it is critical to crowd the α-MoC surface with Pt 1 and Pt n species, which prevents oxidation of the support that would cause catalyst deactivation, as seen with gold/α-MoC, and gives our system high stability and a high metal-normalized turnover number of 4,300,000 moles of hydrogen per mole of platinum. We anticipate that the strategy demonstrated here will be pivotal for the design of highly active and stable catalysts for effective activation of important molecules such as water and carbon monoxide for energy production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗