Oxidative Electrochemical Coupling Between Bi and Mn in Rechargeable Alkaline MnO2 Cathodes
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36 MATERIALS SCIENCE↗
Engineering topics
Zhong, Zhong
Publications and source records attributed to Zhong, Zhong.
Filament-Induced Failure in Lithium-Reservoir-Free Solid-State Batteries
Not Available
36 MATERIALS SCIENCE↗
Elucidating the Discharge Behavior of Aqueous Zinc Sulfur Batteries in the Presence of Molybdenum(IV) Chalcogenide Catalyst: The Criticality of Interfacial Electrochemistry
The aqueous zinc-sulfur battery holds promise for significant capacity and energy density with low cost and safe operation based on environmentally benign materials. However, it suffers from the sluggish kinetics of the conversion reaction. Here, we highlight the efficacy of molybdenum(IV) sulfide (MoS 2 ) to reduce the overpotential of S-ZnS conversion in aqueous electrolytes and study the discharge products formed at the solid-solid and solid-liquid interfaces using experimental and theoretical approaches. Specifically, the MoS 2 -catalyzed electrochemical conversion reaction is characterized via ex situ X-ray diffraction (XRD), transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS), Raman spectroscopy, synchrotron-based Mo K-edge X-ray absorption spectroscopy (XAS), and in situ synchrotron-based X-ray computed tomography (XCT). Additionally, operando synchrotron-based S K-edge XAS and X-ray fluorescence (XRF) maps are collected to determine the spatial evolution of sulfur-based species at the electrode-electrolyte interface. Further, coupling the operando S K-edge XAS data with the simulated spectra and fitting the data suggested a possible ZnS 2 intermediate phase.
25 ENERGY STORAGE↗
Characterizing Hidden Structures at NSLS-II: Strongly Correlated Electron Systems, Functional Ceramics, Batteries, and Beyond
Brookhaven National Laboratory (New York) launched its highenergy X-ray science program at the inception of the National Synchrotron Light Source (NSLS), a U.S. Department of Energy (DOE) Office of Science User Facility. Built in the 1980s, the NSLS X17 beamline was the world’s first super-conducting wiggler facility and remained in service for more than 30 years. The NSLS facility was decommissioned in October 2014 and a third-generation synchrotron machine, DOE’s National Synchrotron Light Source II (NSLS-II), took over. Six years after completing construction, NSLS-II has a portfolio of 29 beamlines that includes two operating high-energy powder diffraction beamlines (XPD and PDF) and one high-energy imaging and diffraction beamline under construction (HEX).
36 MATERIALS SCIENCE↗
Hexagonal boron nitride (h-BN) irradiated with 140 MeV protons
Here, hexagonal boron nitride was irradiated with 140 MeV protons to a fluence of ~6 10 20 p/cm 2 at T irr ~200 °C. Isotropic graphite was also irradiated alongside h-BN under similar conditions and fluence to enable direct comparison of the two similar structures. The effects of proton irradiation on dimensional stability and microstructure were studied using precision dilatometry and energy dispersive Xray diffraction techniques revealing by direct comparison to graphite that h-BN can better resist radiation damage from bombardment when irradiated with protons impinging normal to the crystallographic planes or along the crystallographic c-axis. X-ray diffraction experiments also revealed a preferred orientation of the crystallites in bulk samples near the sample surface, an orientation influenced by irradiation. Thermal studies using differential scanning calorimetry and thermogravimetric analysis to 740 °C, augmented by precision dilatometry, provided evidence of subtle phase transitions attributed to residual w-BN in the matrix. Irradiation appears to induce shifting of such transitions.
36 MATERIALS SCIENCE↗
Radioactive Material Dynamics @ NSLS-II [Slides]
RMD @ NSLS-II helps pave the path to a DMMSC: Developing expertise in techniques and experimental methods for DMMSC science; Improving capabilities for models to become microstructurally aware; Workforce training and development; Help refine DMMSC scientific requirements; Complementary to DMMSC XFEL science (EDXD/EXAFS)
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
Fast Neutron Irradiation Embrittlement-ductilitization of an Iron-based Amorphous Alloy using In Situ Synchrotron X-ray Diffraction
Amorphous Fe-based nanostructured alloy coatings thermally sprayed on bcc steel substrate, were subjected to neutron irradiation doses up to 2 × 10 19 n/cm 2 . It is shown that the interplay between embrittlement and recovery of ductility is governed by amorphous to crystallization transition and phase decomposition in which temperature and irradiation dose have reciprocal effects. Microscopic (X-ray diffraction) observations on the behavior of the amorphous Fe-based alloy are correlated with relevant macroscopically observed mechanical behavior. It is shown that amorphous Fe-based alloy coatings maintain and even enhance their amorphous structure with irradiation, exhibit radiation-induced restoration of thermally-induced embrittlement and finally exhibit resistance to ductility loss up to the fluence of 2 × 10 18 n/cm 2 and good thermal stability up to 350 °C. The latter is deduced from X-ray diffraction experiments of in-situ tensile strain application on the irradiated coating.
36 MATERIALS SCIENCE↗