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Zhou, Weijun

Publications and source records attributed to Zhou, Weijun.

The Polyhedral Specular Reflector: A Spectrum-Splitting Multijunction Design to Achieve Ultrahigh ( >50%) Solar Module Efficiencies

The most feasible pathway to record 50% efficiency photovoltaic devices is by utilizing many (>4) junctions to minimize thermalization and nonabsorption losses. Here we propose a spectrum-splitting design, the polyhedral specular reflector (PSR), that employs an optical architecture to divide and concentrate incident sunlight, allowing the incorporation of more junctions compared with traditional monolithic architectures. This paper describes the PSR design and indicates the requirements to achieve a 50% efficiency module by coupling robust cell, optical, and electrical simulations. We predict that a module comprised of the seven subcells with an average external radiative efficiency of at least 3%, an optical architecture capable of a splitting efficiency of at least 88% and 300× concentration, small (≤1 μm) metallic fingers for subcell contact, and a state-of-the-art power conditioning system (>98% efficiency) can achieve a module efficiency of 50%, a record for both multijunction cells and modules. We also discuss the flexibility of the design and explore how adjusting the size and type of concentrators can still yield record module efficiencies (>40%).

solar (photovoltaic), solid state lighting, phonon↗

Tunable Visibly Transparent Optics Derived from Porous Silicon

Visibly transparent porous silicon dioxide (PSiO 2 ) and PSiO 2 /titanium dioxide (TiO 2 ) optical elements were fabricated by thermal oxidation, or a combination of thermal oxidation and atomic layer deposition infilling, of an electrochemically etched porous silicon (PSi) structure containing an electrochemically defined porosity profile. The thermally oxidized PSiO 2 structures are transparent at visible wavelengths and can be designed to have refractive indices ranging from 1.1 to 1.4. The refractive index can be increased above 2.0 through TiO 2 infilling of the pores. Applying this oxidation and TiO 2 infilling methodology enabled tuning of a distributed Bragg reflector (DBR) formed from PSi across the visible spectrum. At the maximum filling, the DBR exhibited a transmission of 2% at 620 nm. Simulations match well with measured spectra. In addition to forming DBR filters, phase-shaping gradient refractive index (GRIN) elements were formed. As a demonstration, a 4 mm diameter radial GRIN PSiO 2 element with a parabolic, lens-like phase profile with a calculated focal length of 1.48 m was formed. The calculated focal length was reduced to 0.80 m upon the addition of TiO 2 . All the structures showed broad transparency in the visible and were stable to the materials conversion process.

36 MATERIALS SCIENCE↗

Porous Silicon Gradient Refractive Index Micro-Optics

We see the emergence and growth of transformation optics over the past decade has revitalized interest in how a gradient refractive index (GRIN) can be used to control light propagation. Two-dimensional demonstrations with lithographically defined silicon (Si) have displayed the power of GRIN optics and also represent a promising opportunity for integrating compact optical elements within Si photonic integrated circuits. Here, we demonstrate the fabrication of three-dimensional Si-based GRIN micro-optics through the shape-defined formation of porous Si (PSi). Conventional microfabrication creates Si square microcolumns (SMCs) that can be electrochemically etched into PSi elements with nanoscale porosity along the shape-defined etching pathway, which imparts the geometry with structural birefringence. Free-space characterization of the transmitted intensity distribution through a homogeneously etched PSi SMC exhibits polarization splitting behavior resembling that of dielectric metasurfaces that require considerably more laborious fabrication. Coupled birefringence/GRIN effects are studied by way of PSi SMCs etched with a linear (increasing from edge to center) GRIN profile. The transmitted intensity distribution shows polarization-selective focusing behavior with one polarization focused to a diffraction-limited spot and the orthogonal polarization focused into two laterally displaced foci. Optical thickness-based analysis readily predicts the experimentally observed phenomena, which strongly match finite-element electromagnetic simulations.

36 MATERIALS SCIENCE↗