Engineering topics

Ziurys, L. M.

Publications and source records attributed to Ziurys, L. M..

45 records · Page 3

NASA NTRS1988

HCO emission from H II-molecular cloud interface regions

A survey of well-known molecular clouds in the four strongest HCO N(k-,k+) = 1(01)-O(60) hyperfine transitions has been carried out to determine the prevalence of HCO and to study its chemistry. HCO emission was observed in seven molecular clouds. Three of these, NGC 2264, W49, and NGC 7538, were not previously known sources of HCO. In addition, NGC 2024 and Sgr B2 were mapped and shown to have extensive HCO emission. The survey results show the HCO abundance to be enhanced in H II-molecular cloud interface regions and support a correlation between C(+) and HCO emission. The strength of the HCO emission in NGC 2024 is interpreted in terms of this enhancement and the source structure and proximity to Earth.

Schenewerk, M. S.↗

NASA NTRS1988

SiS in Orion-KL - Evidence for 'outflow' chemistry

The J = 6-5 and J = 5-4 rotational transitions at 91 and 109 GHz toward Orion-KL provide evidence for the presence of SiS at an LSR velocity of 7.5 km/sec and with a half-width at zero power of 36 km/sec. The estimated current density corresponds to a fractal abundance of about 4 x 10 to the -9th. The implied SiO/SiS ratio of about 60 is close to the cosmic O/S ratio of about 40 and is much less than that predicted by ion-molecule models. Other unidentified lines near 91 and 109 have been identified.

Ziurys, L. M.↗

NASA NTRS1988

Newly detected molecules in dense interstellar clouds

The last year or so has seen the identification of several new interstellar molecules, including C2S, C3S, C5H, C6H, and (probably) HC2CHO in the cold, dark cloud TMC-1, and the discovery of the first interstellar phosphorus-containing molecule, PN, in the Orion 'plateau' source. Further interesting results include the observations of (C-13))3H2 and C3HD, and the first detection of HCOOH (formic acid) in a (C-13)3H2 cold cloud.

Irvine, William M.↗

NASA NTRS1987

Detection of interstellar PN - The first phosphorus-bearing species observed in molecular clouds

Phosphorus nitride (PN) has been detected in the interstellar medium. The J = 2-1, 3-2, 5-4, and 6-5 rotational lines of this species have been observed toward Orion-KL, and the J = 2-1 transition in Sgr B2 and W51. The PN line profiles in Orion indicate that the molecule's emission arises from the 'plateau' or 'doughnut' region associated with the outflow from IRc2. The species is thus primarily present in hot, dense gas. Column densities derived for PN toward Orion-KL are (3-4) x 10 to the 13th/sq cm, but may be as high as 10 to the 14th/sq cm, if the species is located in a 10-arcsec region. These column densities imply a fractional abundance for PN in the Orion 'plateau' of (1-4) x 10 to the -10th. Such a large abundance for PN is not predicted by quiescent cloud ion-molecule chemistry and suggests that high-temperature processes are responsible for the synthesis of PN in the KL outflow.

Ziurys, L. M.↗

NASA NTRS1987

Observations of SiO toward OMC-1 - A new outflow source 1.5 arcmin south of Orion-KL?

Observations of the J = 2-1 transition of thermal SiO have been carried out toward OMC-1. Approximately 1.5 arcmin south of the KL nebula and IRc2, a new moderately strong source of SiO emission with T(a)-asterisk of about 1 K has been detected. The emission appears to be confined to a region 30 arcsec or less in size and shows evidence of high-velocity wings extending + or - 12-15 km/s from line center, which may indicate the presence of an embedded star in its early stages. The SiO J - 2-1 line was sought at other positions in OMC-1 but was not detected except at (3N, 1E), where a weak narrow line was observed. Derived column densities and abundances at the 1.5-arcmin S, (3N, 1E), and KL positions suggest that SiO formation is favored in regions where outflows and high temperatures are present.

Ziurys, L. M.↗

NASA NTRS1986

Studies of interstellar vibrationally-excited molecules

Several molecules thus far have been detected in the ISM in vibrationally-excited states, including H2, SiO, HC3N, and CH3CN. In order for vibrational-excitation to occur, these species must be present in unusually hot and dense gas and/or where strong infrared radiation is present. In order to do a more thorough investigation of vibrational excitation in the interstellar medium (ISM), studies were done of several mm-wave transitions originating in excited vibrational modes of HCN, an abundant interstellar molecule. Vibrationally-excited HCN was recently detected toward Orion-KL and IRC+10216, using a 12 meter antenna. The J=3-2 rotational transitions were detected in the molecule's lowest vibrational state, the bending mode, which is split into two separate levels, due to l-type doubling. This bending mode lies 1025K above ground state, with an Einstein A coefficient of 3.6/s. The J=3-2 line mode of HCN, which lies 2050K above ground state, was also observed toward IRC+10216, and subsequently in Orion-KL. Further measurements of vibrationally-excited HCN were done using a 14 meter telescope, which include the observations of the (0,1,0) and (0,2,0) modes towards Orion-KL, via their J=3-2 transitions at 265-267 GHz. The spectrum of the J=3-2 line in Orion taken with the 14 meter telescope, is shown, along with a map, which indicates that emission from vibrationally-excited HCN arises from a region probably smaller than the 14 meter telescope's 20 arcsec beam.

Ziurys, L. M.↗

NASA NTRS1986

Boundary conditions for the paleoenvironment: Chemical and Physical Processes in dense interstellar clouds

The present research includes searches for important new interstellar constituents; observations relevant to differentiating between different models for the chemical processes that are important in the interstellar environment; and coordinated studies of the chemistry, physics, and dynamics of molecular clouds which are the sites or possible future sites of star formation. Recent research has included the detection and study of four new interstellar molecules; searches which have placed upper limits on the abundance of several other potential constituents of interstellar clouds; quantitative studies of comparative molecular abundances in different types of interstellar clouds; investigation of reaction pathways for astrochemistry from a comparison of theory and the observed abundance of related species such as isomers and isotopic variants; studies of possible tracers of energenic events related to star formation, including silicon and sulfur containing molecules; and mapping of physical, chemical, and dynamical properties over extended regions of nearby cold molecular clouds.

Irvine, W. M.↗

NASA NTRS1986

HCNH(+) - A new interstellar molecular ion

The first interstellar detection of HCNH(+) is reported. The J = 1-0, 2-1, and 3-2 rotational transitions of this molecule at 74, 148, and 222 GHz have been observed toward Sgr B2. Using a large velocity gradient model calculation, the column density of HCNH(+) is found to be about 4 x 10 to the 14th/sq cm, about one order of magnitude less than that estimated for HCO(+) and HCN in this source. Such a column density implies a fractional abundance of at least one to several orders of magnitude larger than predicted by numerous ion-molecule models. Coupled with a relatively low abundance of HCN and a small HNC/HCN ratio, this suggests that HCNH(+) is not channeled into HCN or HNC as rapidly as thought.

Ziurys, L. M.↗

NASA NTRS1986

Detection of interstellar vibrationally excited HCN

The J = 3 - 2 rotational transitions of the l-doubled bending mode of HCN have been detected toward Orion-KL and IRC + 10216, representing the first interstellar medium observations of vibrationally excited HCN. The overall column density in the (0, 1, 0) mode exclusively sampling the hot core is 1.7 x 10 to the 16th/sq cm, and may be understood in terms of the doughnut model for Orion. The ground state HCN column density implied by the excited state observations is at least one order of magnitude greater than the column densities derived for HCN in its spike and plateau/doughnut components. The spectral profiles obtained have been modeled to yield abundances and excitation conditions throughout the expanding envelope.

Ziurys, L. M.↗