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Zolensky, M. E.

Publications and source records attributed to Zolensky, M. E..

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Mineralogy, Three Dimensional Structure, and Oxygen Isotope Ratios of Four Crystalline Particles from Comet 81P/Wild 2

Preliminary examinations of small dust particles from comet 82P/Wild 2 revealed many expected and unexpected features. Among them the most striking feature is the presence of abundant crystalline material in the comet. Synchrotron radiation X-ray diffraction and microtomography are the most efficient methods to detect and describe bulk mineralogical features of crystalline cometary particles. In the present study, in addition to these two non-destructive techniques, electron microscopy and ion-probe mass spectrometry were carried out on the four crystalline particles.

Nakamura, T.↗
NASA NTRS2007

STARDUST Curation and Science at JSC

Dust particles released from comet 81P/Wild-2 were captured in silica aerogel on-board the STARDUST spacecraft and returned to Earth on January 15, 2006. STARDUST recovered thousands of particles ranging in size from 1 to 100 micrometers. During the six month Preliminary Examination period an international consortium of 180 scientists investigated their mineralogy/petrology, organic/inorganic chemistry, optical properties and isotopic compositions. Stardust samples are now available for research by the entire research community.

Nakamura-Messenger, K.↗
NASA NTRS2007

Effects of Short-Term Thermal Alteration on Organic Matter in Experimentally-Heated Tagish Lake Observed by Raman Spectroscopy

Carbonaceous chondrites exhibit a wide range of aqueous and thermal alteration characteristics. Examples of the thermally metamorphosed carbonaceous chondrites (TMCCs) include the C2-ung/CM2TIVs Belgica (B)-7904 and Yamato (Y) 86720. The alteration extent is the most complete in these meteorites and thus they are considered typical end-members of TMCCs exhibiting complete dehydration of matrix phyllosilicates [1, 2]. The estimated heating conditions are 10 to 10(sup 3) days at 700 C to 1 to 100 hours at 890 C, i.e. short-term heating induced by impact and/or solar radiation [3]. The chemical and bulk oxygen isotopic compositions of the matrix of the carbonate (CO3)-poor lithology of the Tagish Lake (hereafter Tag) meteorite bears similarities to these TMCCs [4]. We investigated the experimentally-heated Tag with the use of Raman spectroscopy to understand how short-term heating affects the maturity of insoluble organic matter (IOM) in aqueously altered meteorites.

Chan, Q. H. S.↗
NASA NTRS2007

A New Modal Analysis Method to put Constraints on the Aqueous Alteration of CR Chondrites and Estimate the Unaltered CR Composition

CR carbonaceous chondrites are of the major interest since they contain one of the most primitive organic matters. However, aqueous alteration has more or less overprinted their original features in a way that needed to be assessed. That was done in the present study by comparing the mineralogy of the most altered CR1 chondrite, GRO 95577, to a less altered CR2, Renazzo. Their modal analyses were achieved thanks to a new method, based on X-ray elemental maps acquired on electron microprobe, and on IDL image treatment. It allowed the collection of new data on the composition of Renazzo and confirmed the classification of GRO 95577 as a CR1. New alteration products for CRs, vermiculite and clinochlore, were observed. The homogeneity of the Fe-poor clays in the CR1 and the distinctive matrix composition in the two chondrites suggest a wide-range of aqueous alteration on CRs. The preservation of the outlines of the chondrules in GRO 95577 and the elemental transfers of Al, Fe and Ca throughout the chondrule and of Fe and S from the matrix to the chondrule favor the idea of an asteroidal location of the aqueous alteration. From their mineralogical descriptions and modal abundances, the element repartitions in Renazzo and GRO 95577 were computed. It indicates a possible relationship between these two chondrites via an isochemical alteration process. Knowing the chemical reactions that occurred during the alteration, it was thus possible to decipher the mineralogical modal abundances in the unaltered CR body.

Perronnet, M.↗
NASA NTRS2007

Stardust Curation at Johnson Space Center: Photo Documentation and Sample Processing of Submicron Dust Samples from Comet Wild 2 for Meteoritics Science Community

Dust particles released from comet 81P/Wild-2 were captured in silica aerogel on-board the STARDUST spacecraft and successfully returned to the Earth on January 15, 2006. STARDUST recovered thousands of particles ranging in size from 1 to 100 micrometers. The analysis of these samples is complicated by the small total mass collected ( < 1mg), its entrainment in the aerogel collection medium, and the fact that the cometary dust is comprised of submicrometer minerals and carbonaceous material. During the six month Preliminary Examination period, 75 tracks were extracted from the aerogel cells , but only 25 cometary residues were comprehensively studied by an international consortium of 180 scientists who investigated their mineralogy/petrology, organic/inorganic chemistry, optical properties and isotopic compositions. These detailed studies were made possible by sophisticated sample preparation methods developed for the STARDUST mission and by recent major advances in the sensitivity and spatial resolution of analytical instruments.

Nakamura-Messenger, K.↗
NASA NTRS2007

The Aqueous Alteration of CR Chondrites: Experiments and Geochemical Modeling

CR carbonaceous chondrites are of major interest since they contain some of the most primitive organic matter known. However, aqueous alteration has more or less overprinted their original features in a way that needs to be assessed. This study was initiated by comparing the mineralogy and modal abundances of the most altered CR1 chondrite, GRO 95577, to a less altered CR2. Calculated element distributions imply that GRO 95577 may result from aqueous alteration of Renazzo by an isochemical process on their parent asteroid, whose mineralogical composition was estimated ( Unaltered CR shown included table).

Perronnet, M.↗
NASA NTRS2007

A New Modal Analysis Method to put Constraints on the Aqueous Alteration of CR Chondrites and Estimate the Unaltered CR Composition

carbonaceous chondrites are of the major interest since they contain one of the most primitive organic matters. However, aqueous alteration has more or less overprinted their original features in a way that needed to be assessed. That was done in the present study by comparing the mineralogy of the most altered CR1 chondrite, GRO 95577, to a less altered CR2, Renazzo. Their modal analyses were achieved thanks to a new method, based on X-ray elemental maps acquired on electron microprobe, and on IDL image treatment. It allowed the collection of new data on the composition of Renazzo and confirmed the classification of GRO 95577 as a CR1. New alteration products for CRs, vermiculite and clinochlore, were observed. The homogeneity of the Fe-poor clays in the CR1 and the distinctive matrix composition in the two chondrites suggest a wide-range of aqueous alteration on CRs. The preservation of the outlines of the chondrules in GRO 95577 and the elemental transfers of Al, Fe and Ca throughout the chondrule and of Fe and S from the matrix to the chondrule favor the idea of an asteroidal location of the aqueous alteration. From their mineralogical descriptions and modal abundances, the element repartitions in Renazzo and GRO 95577 were computed. It indicates a possible relationship between these two chondrites via an isochemical alteration process. Knowing the chemical reactions that occurred during the alteration, it was thus possible to decipher the mineralogical modal abundances in the unaltered CR body.

Perronnet, M.↗
NASA NTRS2005

Experimental Shock Decomposition of Siderite to Magnetite

The debate about fossil life on Mars includes the origin of magnetites of specific sizes and habits in the siderite-rich portions of the carbonate spheres in ALH 84001 [1,2]. Specifically [2] were able to demonstrate that inorganic synthesis of these compositionally zoned spheres from aqueous solutions of variable ion-concentrations is possible. They further demonstrated the formation of magnetite from siderite upon heating at 550 C under a Mars-like CO2-rich atmosphere according to 3FeCO3 = Fe3O4 + 2CO2 + CO [3] and they postulated that the carbonates in ALH 84001 were heated to these temperatures by some shock event. The average shock pressure for ALH 84001, substantially based on the refractive index of diaplectic feldspar glasses [3,4,5] is some 35-40 GPa and associated temperatures are some 300-400 C [4]. However, some of the feldspar is melted [5], requiring local deviations from this average as high as 45-50 GPa. Indeed, [5] observes the carbonates in ALH 84001 to be melted locally, requiring pressures in excess of 60 GPa and temperatures > 600 C. Combining these shock studies with the above inorganic synthesis of zoned carbonates it seems possible to produce the ALH 84001 magnetites by the shock-induced decomposition of siderite.

Bell, M. S.↗
NASA NTRS2005

An Achondritic Micrometeorite from Antarctica: Expanding the Solar System Inventory of Basaltic Asteroids

Micrometeorites with sizes below 1 mm are collected in a diversity of environments such as deep-sea sediments and polar caps. Chemical, mineralogical and isotopic studies indicate that micrometeorites are closely related to primitive carbonaceous chondrites that amount to only approximately 2% of meteorite falls. While thousands of micrometeorites have been studied in detail, no micrometeorite has been found so far with an unambiguous achondritic composition and texture. One melted cosmic spherule has a low Fe/Mn ratio similar to that of eucrites, the most common basaltic meteorite group. Here we report on the texture, mineralogy, Rare Earth Elements (REEs) abundance and oxygen isotopic composition of the unmelted Antarctic micrometeorite 99-21-40 that has an unambiguous basaltic origin.

Gounelle, M.↗
NASA NTRS2005

Meteorite WIS91600: A New Sample Related to a D- or T-type Asteroid

Since the Tagish Lake meteorite fell in January 2000, the assumed one-of-the-kind meteorite has become the hottest issue among a diversity of scientists. Meanwhile, as the physical origin of the meteorite in our solar system, D or T asteroids have been suggested by Hiroi et al. based on comparison of their visible-near-infrared (VNIR) reflectance spectra. While it is probably still true that the Tagish Lake meteorite is possibly the first recovered sample from a D or T asteroid as a meteorite fall, we report in this paper that the meteorite WIS91600 may actually be the first recovered sample from one of those asteroids as a meteorite find.

Hiroi, T.↗
NASA NTRS2005

In-Situ Heating Decrease Kinetics of Aliphatic Hydrocarbons in Tagish Lake Meteorite by Micro-FTIR

Carbonaceous chondrites are known to contain up to 3wt.% C, the major part of which corresponds to a macromolecular organic fraction. Chondritic organic matter is based on small aromatic units, cross-linked by short aliphatic chains rather than large clusters of polyaromatic structures. Two main characteristic features of those organics measured by FTIR are: (1) an equivalent intensity of the asymmetric stretching mode absorptions for CH3 (2960/cm) and CH2 (2920/cm) and (2) a lack of aromatic CH-stretching mode (3040/cm). Tagish Lake is a new type of water- and carbon-rich type 2 carbonaceous chondrite. Its total carbon content is approx. 5 wt%, of which the organic carbon content reaches approx. 1.3 wt%. Tagish Lake may have never experienced temperatures higher than 120 C after formation of organics based on the disappearance of infrared (IR) organic peaks in step heating experiments. Here we report in-situ kinetic heating experiments of organics in Tagish Lake by micro-FTIR to characterize the nature of aliphatic hydrocarbons and their thermal stabilities.

Kebukawa, Y.↗
NASA NTRS2005

Porphyritic Olivine-Pyroxene Clast in Kaidun: First Discovery of an Ordinary Chondrite Clast?

Kaidun is an enigmatic meteorite showing a micro-brecciated texture composed of variable kinds of lithic clasts and mineral fragments. The constituent components range from primitive chondritic materials to differentiated achondritic materials, and thus believed to have originated from a large parent body accumulating materials from many different bodies in the asteroid belt. One of the interesting observations is that no ordinary chondrite component has been found yet, although C and E chondrites components are abundant. In this abstract, we report mineralogy of the clast (Kaidun #15415- 01.3.13a) showing a porphyritic olivine-pyroxene chondrule-like texture similar to those found in unequilibrated ordinary chondrites.

Mikouchi, T.↗
NASA NTRS2005

Infrared Micro-Spectroscopy of Organic and Hydrous Components in Some Antarctic Micrometeorites

Micrometeorites extracted from Antarctic ice are a major source of extraterrestrial materials available for study in the laboratory. Materials in this size range are important because the peak in the mass flux distribution of extraterrestrial particles accreted by the Earth occurs for particles approximately 200 microns in diameter with a mass accretion rate estimated at approximately 40 x 10(exp 6) kilograms per year. It has been suggested that micrometeorites may have contributed much pre-biotic organic matter to the early Earth, but the types and abundances of organic material in micrometeorites are poorly known. We have conducted infrared (IR) micro-spectrocopy of small micrometeorites (about 100 microns in size) in order to characterize organic matter that is present in the particles. The obtained results were compared with IR signatures of representative carbonaceous chondrites.

Suzuki, A.↗
NASA NTRS2005

Compositions of Partly Altered Olivine and Replacement Serpentine in the CM2 Chondrite QUE93005

Some phyllosilicates in CM carbonaceous chondrites formed by aqueous alteration of anhydrous precursor phases. Although broad trends in the compositions of hydrous phyllosilicates are recognized and believed to be related to trends in degree of aqueous alteration, details of the reactions that formed specific secondary minerals remain obscure. This paper reports compositional relationships between remnants of partially pseudomorphically (or alteromorphically) replaced silicates and their alteration products (serpentine) in the CM2 chondrite QUE93005 and compares it with previously published results for ALH81002. Reactants and products were characterized by optical petrography, backscattered scanning electron microscopy (BSEM), and electron microprobe. By focusing on serpentine formed from known reactants (olivines), and on only those instances in which some of the reactant silicate remains, direct compositional relationships between reactants and products, and the elemental mobility required by the reactions, can be established. Additional information is included in the original extended abstract.

Velbel, M. A.↗
NASA NTRS2005

What is the Water (OH) Content of the E Asteroids?

Attempts to match the E asteroids with enstatite-rich meteorites universally conclude that the aubrites or enstatite chondrites are natural candidates, and accordingly conclude that E asteroids as a class are very water-poor. Accordingly, the highly reduced nature of typical enstatite-rich meteorites suggests that aqueous alteration was an improbable process on any E asteroid. However, there are spectroscopic observations of several E-class asteroids that suggest the presence there of hydrated phases. Examination of the Kaidun meteorite reveals the true situation.

Zolensky, M. E.↗
NASA NTRS2004

Stardust Encounters Comet 81P/Wild 2

Stardust successfully encountered comet 81P/Wild 2 on 2 January 2004 at a distance of 236.4 +/- 1 km. All encounter investigations acquired valuable new and surprising findings. The time-of-flight spectrometer registered 29 spectra during flyby and measured the first negative ion mass spectra of cometary particles. The dust detectors recorded particles over a broad mass range, 10(exp -11) to 10(exp -4) g. Unexpectedly, the dust distribution along Stardust's flight path was far from uniform, but instead occurred in short 'bursts', suggesting in-flight breakup of fragments ejected from the nucleus. High-resolution, stunning images of the Wild 2 surface show a diverse and complex variety of landforms not seen from comets 1P/Halley and 19P/Borrelly or icy satellites of the outer solar system. Longer-exposure images reveal large numbers of jets projected nearly around the entire perimeter of the nucleus, many of which appear to be highly collimated. A triaxial ellipsoidal fit of the Wild 2 nucleus images yields the principal nucleus radii of 1.65 X 2.00 X2.75 km (+/- 0.05 km). The orientations and source locations on the nucleus surface of 20 highly collimated and partially overlapping jets have been traced. There is every indication that the expected samples were successfully collected from the Wild 2 coma and are poised for a return to Earth on 15 January 2006.

Stardust mission↗
NASA NTRS2004

Stardust Sample Collection at Wild 2 and Its Preliminary Examination

The primary objective of STARDUST is to collect coma samples from 81P/Wild 2. This was made on January 2, 2004. Before the encounter three significant model predictions existed for the number and size of samples to be captured. Three investigations during the Wild 2 encounter (Dust Flux Monitor, Comet and Interstellar Dust Analyzer and Dynamic Science) made in situ measurements of the dust. Spectacular images were captured of the Wild 2 nucleus and dust jets. This abstract compares the model predictions with the in situ measurements and Wild 2 images and assesses the likely samples to be returned for analysis on January 15, 2006. To give some lead time for sample analysts to prepare for the analyses of the returned samples, the organization of the Preliminary Examination is presented.

Tsou, P.↗