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Find NASA NTRS and DOE OSTI reports about batteries and energy storage. Search electrode materials, lithium-ion batteries and storage systems in indexed report metadata.

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NASA NTRS2022

Exploration of an Adaptive Routine for Battery Modeling

The purpose of this document is to explore the use of adaptive routines in battery modeling. The adaptive routines consist of real-time state estimators combined with battery parameter model components that are adjusted in real-time as battery data becomes available. Several aspects are explored. It is shown that model parameter identification is possible for simple battery models using available input/output data measurements. The online system identification used is recursive least squares. Model identification may be combined with a state observer such as the extended Kalman filter or the unscented Kalman filter to form an adaptive model combined with state estimation. However, such a combination is found to be problematic due to uncertainty, observability and stability issues. This paper is organized as follows. Section 1 introduces adaptive routines and possible roles they play in battery modeling. In Section 2 real-time parameter identification is described with results based on battery data. Section 3 reviews various state estimators and results using a simple battery model. In Section 4 parameter identification and state estimation are combined to form an adaptive routine. Finally, in Section 5 conclusions are drawn and future work is suggested.

Adaptive↗

NASA NTRS2024

Performance of Two Battery Prognostic Applications used by Two Octocopters for Safe Low Altitude Autonomous Flight Operations

This paper addresses the problem of building trust in online predictions of the remaining available flying time for two different electric Unmanned Aerial Vehicles (eUAVs) powered by lithium-ion-polymer batteries. Flight tests for various automation research missions for the two vehicles were monitored using two on-board battery health management applications to make predictions of the remaining flying time (RFT) for each eUAV and to predict the state of the battery. Playback of the voltage, current and temperature profiles of the battery discharge were used to assess the accuracy of the estimation of the voltage and the charge states of the models as well as the estimate of the RFT. The reference ground truth values were the observed landing time and the measured battery pack resting pack voltage 20 minutes after the flight. The predicted RFT, state of charge (SoC), and state of energy (SoE) were compared with the observed results. Noise values of one standard deviation from the mean values of the internal charge states of the battery model during a reference run were used to vary the states during simulation. One application used an equivalent circuit model of the electrical dynamics of the battery pack, and the other application used a reduced-order electrochemistry model. The variation of the model state components was compared to the variation in the estimate of the RFT and the variation in the SoE to estimate a confidence factor. Variation in the estimates caused by factors affecting the off-line laboratory parameter identification experiments is considered. Variation in the estimates due to environmental factors are discussed.

Assurance↗

NASA NTRS2023

Long Life Molten Salt Battery for NASA Venus Application

A development program is being conducted at Advanced Thermal Batteries (ATB) to create a low discharge rate, long life, molten salt battery for a NASA Venus surface probe. Battery goals are 60 days continuous operation at +25V +0/-6 volts and -25V +6/-0 Volts under severe environments of 465°C, 92 atm pressure, and corrosive sulfur dioxide in a super critical carbon dioxide atmosphere. Conveniently, molten salt thermal battery electrochemistry starts to operate efficiently at 330°C. However, a major barrier to direct application of existing thermal battery technology is the high self-discharge rate, resulting in lifetimes in only minutes, not days. The best performance to date, which meets the required voltage regulation, has been a lithium silicon (LiSi) alloy anode discharging through all three voltage plateau versus an iron monosulfide (FeS) cathode. In order to perform reproducibly, additional engineering controls within the battery design are required to limit cell–to–cell parasitic discharge mechanisms. Results of these trials have improved the efficiency and manufacturability of the design.

Thermal Battery↗

DOE OSTI2023

Impacts of Dispatch Strategies and Forecast Errors on the Economics of Behind-the-Meter PV-Battery Systems: Preprint

To assess the economic value of batteries in hybrid PV-battery systems, one must create a dispatch profile for the battery. Many analyses of battery value assume perfect forecasts of PV generation and load, determining an upper limit on the value of the battery. Prior work that accounts for forecast uncertainty often does so in the context of a single dispatch algorithm, which does not provide a baseline for comparison. Furthermore, when multiple dispatch algorithms are assessed with uncertainty, the benefits considered are for diesel generation in a microgrid, not retail rate savings. This work addresses the gaps in the literature by comparing the performance of both heuristic and optimal dispatch algorithms for retail rate savings under forecast uncertainty, and provides comparisons of the robustness of these algorithms and their associated estimates of economic value. We find that using a perfect forecast can overestimate the value of hybrid PV-battery systems between 1% and 8% compared to the reality of using a day-ahead forecast, depending on the dispatch algorithm used. Thus, accounting for forecast uncertainty in system design and analysis will significantly improve the accuracy of modeled system values.

batteries↗

DOE OSTI2016

Poly(vinylidene fluoride-hexafluoropropylene) polymer electrolyte for paper-based and flexible battery applications

Paper-based batteries represent a new frontier in battery technology. However, low-flexibility and poor ionic conductivity of solid electrolytes have been major impediments in achieving practical mechanically flexible batteries. This work discuss new highly ionic conductive polymer gel electrolytes for paper-based battery applications. In this paper, we present a poly(vinylidene fluoride-hexafluoropropylene) (PVDH-HFP) porous membrane electrolyte enhanced with lithium bis(trifluoromethane sulphone)imide (LiTFSI) and lithium aluminum titanium phosphate (LATP), with an ionic conductivity of 2.1 × 10{sup −3} S cm{sup −1}. Combining ceramic (LATP) with the gel structure of PVDF-HFP and LiTFSI ionic liquid harnesses benefits of ceramic and gel electrolytes in providing flexible electrolytes with a high ionic conductivity. In a flexibility test experiment, bending the polymer electrolyte at 90° for 20 times resulted in 14% decrease in ionic conductivity. Efforts to further improving the flexibility of the presented electrolyte are ongoing. Using this electrolyte, full-cell batteries with lithium titanium oxide (LTO) and lithium cobalt oxide (LCO) electrodes and (i) standard metallic current collectors and (ii) paper-based current collectors were fabricated and tested. The achieved specific capacities were (i) 123 mAh g{sup −1} for standard metallic current collectors and (ii) 99.5 mAh g{sup −1} for paper-based current collectors. Thus, the presented electrolyte has potential to become a viable candidate in paper-based and flexible battery applications. Fabrication methods, experimental procedures, and test results for the polymer gel electrolyte and batteries are presented and discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2019

Characterization of mechanical properties of thin-film Li-ion battery electrodes from laser excitation and measurements of zero group velocity resonances

The mechanical properties of thin-film Li-ion battery electrodes are controlled by the microstructure of the constituent materials. In this work, a noncontact and nondestructive measurement of the mechanical properties of electrode films is performed by measurement of zero-group velocity (ZGV) resonances. Theoretical models are used to quantify the sensitivity of the ZGV resonances to changes in mechanical properties. The ZGV Lamb modes of a solid bilayer consisting of a thin metallic layer and a thin compliant coating layer are shown to be dependent on Young’s moduli, thicknesses, densities, and Poisson’s ratios of the layers. Experimental ZGV resonances are excited using a pulsed infrared laser and detected using a laser interferometer. Commercial-grade battery films with different coating materials, densities, and thicknesses are measured. Young’s moduli of the battery electrode layers are estimated using the combination of a theoretical model and experimental results. The effect of the calendering process on the battery materials is also investigated. Results suggest that Young’s modulus of the electrode coating increases drastically after the battery films are calendered. This technique can be used to quantitatively study the mechanical properties of Li-ion battery electrodes in order to improve overall battery performance.

Yao, Jing (ORCID:0000000209348842)↗

DOE OSTI2026

A Reverse Logistics Tool For Ev Battery Recycling And Repurposing,

The demand for electric vehicles (EVs) in the United States is projected to rise significantly, with sales expected to reach approximately 4.1 million units by 2030. However, the U.S. remains heavily reliant on imports for the batteries and critical raw materials—such as lithium, cobalt, and nickel—that power these vehicles. As of 2024, around 70% of these imports originate from China. This dependency has become even more precarious following China’s imposition of export restrictions in April 2025, a retaliatory move against U.S. tariffs. These developments highlight the strategic vulnerabilities posed by China’s dominant position in the critical materials market. Compounding the issue, decades of intensive extraction have severely depleted global reserves of critical materials, widening the gap between supply and growing demand. This situation underscores the urgent need for the U.S. and other nations to diversify their sources of critical materials and enhance domestic capabilities to secure these resources—an essential step toward ensuring long-term energy security. At the end of their lifecycle—whether due to the battery’s degradation or the retirement of the vehicle—EV batteries are often improperly disposed of or sent to landfills. However, many of these batteries still retain usable capacity and can follow one of three alternative pathways: (a) Re-used: deployed in another vehicle with a shorter driving range, (b) Re-purposed: utilized act as a backup storage/power for data centers, solar panels, and e-scotters or (c) Recycled: broken down to recover the critical materials. To that end, the proposed tool (REBORN) is designed to optimize the reverse logistics network for battery repurposing and recycling. Its goal is to minimize associated costs while identifying optimal locations for battery collection and processing. Ultimately, REBORN ensures that each battery is used to its fullest potential.

Srinivas, SrikarV. [Idaho National Laboratory (INL↗

NASA NTRS1974

Experimental investigation and model development of the Skylab ATM secondary nickel-cadmium batteries

The performance of a Ni-Cd battery was evaluated and the cyclic battery controls to be used on the ATM batteries were determined. Cell and battery performance models were developed which to predict the performance of the secondary Ni-Cd batteries on the ATM. Capacity degradation and charge acceptance characteristics were considered. Mathematical models for each of these operating areas were developed based on data from two separate test programs. The capacity degradation model describes the expected usable battery capacity as a function of time, temperature, and depth-of-discharge. The charge acceptance model describes the cell charge acceptance as a function of charge rate, temperature, and state of charge. The models were designed for computer use and to facilitate possible battery modification. They can be used to predict expected performance or to compare real time performance during flight.

Kirsch, W. W.↗

NASA NTRS1977

A nickel-cadmium battery reconditioning circuit

The circuit presented is simple and small enough to be included in a typical battery charge/power control assembly, yet provides the advantage of a complete ground-type battery reconditioning discharge. Test results on the circuit when used to recondition two 24 cell, 20 A-h nickel-cadmium batteries are given. These results show that a battery reconditioned with this circuit returns to greater than 90 percent of its original capacity (greater than nameplate capacity) and follows a typical new battery degradation curve even after over 20,000 simulated orbital cycles for a 4 year period. Applications of the circuit are considered along with recommendations relative to its use. Its application in low voltage (22 to 36 Vdc) power systems and in high voltage (100 to 150 Vdc) power systems is discussed. The implications are that the high voltage systems have a greater need for battery reconditioning than their low voltage counterparts, and that using these circuit techniques, the expected life of a battery in low Earth orbit can be up to 5 years.

Lanier, R.↗

NASA NTRS1979

Dynamic analysis of a photovoltaic power system with battery storage capability

A photovolataic power system with a battery storage capability is analyzed. A dual battery current control concept is proposed, which enables the battery to either supply or accept power depending upon system environment and load conditions. A simulation of the power system, including the battery current control, is developed and evaluated. The evaulation demonstrate the visbility of the battery control concept of switch the battery from a charge to discharge mode and back as required by load and environmental conditions. An acceptable system operation is demonstrated over the entire insolation range. Additionally, system sensitivity, bandwidth, and damping characteristics of the battery control are shown to be acceptable for a projected hardware implementation.

Merrill, W. C.↗

NASA NTRS1984

Results of electric-vehicle propulsion system performance on three lead-acid battery systems

Three types of state of the art 6 V lead acid batteries were tested. The cycle life of lead acid batteries as a function of the electric vehicle propulsion system design was determined. Cycle life, degradation rate and failure modes with different battery types (baseline versus state of the art tubular and thin plate batteries were compared. The effects of testing strings of three versus six series connected batteries on overall performance were investigated. All three types do not seem to have an economically feasible battery system for the propulsion systems. The tubular plate batteries on the load leveled profile attained 235 cycles with no signs of degradation and minimal capacity loss.

Ewashinka, J. G.↗

NASA NTRS1984

Laboratory discharge studies of a 6 V alkaline lantern-type battery Eveready Energizer no. 528, under various ambient temperatures (-15 deg C and + 22 deg C) and loads (30 omega and 60 omega)

The voltages of two Eveready No. 528 batteries, one the test battery, the other the control battery, were simultaneously recorded as they were discharged across 30 omega loads using a dual chart recorder. The test battery was initially put in a freezer at -15 + or - 3 C. After its voltage had fallen to .6 V, it was brought back out into the room at 22 + or - 3 C. A second run was made with 60 omega loads. Assuming a 3.0 V cut-off, the total energy output of the test battery at -15 C was 26 WHr 30 omega and 35 WHr 60 omega, and the corresponding numbers for the control battery at 22 C were 91 WHr and 100 WHr. When the test battery was subsequently allowed to warm up, the voltage rose above 4 V and the total energy output rose to 80 WHr 30 omega and 82 WHR 60 omega.

Ahrens, S. T.↗

NASA NTRS1984

Special Test Methods for Batteries

Various methods are described for measuring heat generation in primary and secondary batteries as well as the specific heat of batteries and cell thermal conductance. Problems associated with determining heat generation in large batteries are examined. Special attention is given to monitoring temperature gradients in nickel cadmium cells, the use of auxiliary electrodes for conducting tests on battery charge control, evaluating the linear sweep of current from charge to discharge, and determining zero current voltage. The fast transient behavior of batteries in the microsecond range, and the electrical conductance of nickel sinters in the thickness direction are also considered. Mechanical problems experienced in the vibration of Ni-Cd batteries and tests to simulate cyclic fatigue of the steel table connecting the plates to the comb are considered. Methods of defining the distribution of forces when cells are compressed during battery packaging are also explored.

Gross, S.↗

NASA NTRS1984

Nickel-iron battery system safety

The generated flow rates of gaseous hydrogen and gaseous oxygen from an electrical vehicle nickel-iron battery system were determined and used to evaluate the flame quenching capabilities of several candidate devices to prevent flame propagation within batteries having central watering/venting systems. The battery generated hydrogen and oxygen gases were measured for a complete charge and discharge cycle. The data correlates well with accepted theory during strong overcharge conditions indicating that the measurements are valid for other portions of the cycle. Tests confirm that the gas mixture in the cells is always flammable regardless of the battery status. The literature indicated that a conventional flame arrestor would not be effective over the broad spectrum of gassing conditions presented by a nickel-iron battery. Four different types of protective devices were evaluated. A foam-metal arrestor design was successful in quenching gaseous hydrogen and gaseous oxygen flames, however; the application of this flame arrestor to individual cell or module protection in a battery is problematic. A possible rearrangement of the watering/venting system to accept the partial protection of simple one-way valves is presented which, in combination with the successful foam-metal arrestor as main vent protection, could result in a significant improvement in battery protection.

Saltat, R. C.↗

NASA NTRS1983

High voltage battery cell scanner development

Battery cell voltage scanners have been previously used in low voltage spacecraft applications. In connection with future missions involving an employment of high-power high voltage power subsystems and/or autonomous power subsystem management for unattended operation, it will be necessary to utilize battery cell voltage scanners to provide battery cell voltage information for early detection of impending battery cell degradation/failures. In preparation for such missions, a novel battery cell voltage scanner design has been developed. The novel design makes use of low voltage circuit modules which can be applied to high voltage batteries in a building block fashion. A description is presented of the design concept and test results of the high voltage battery cell scanner, and its operation with an autonomously managed power subsystem is discussed.

Lepisto, J. W.↗

NASA NTRS1984

Results of electric-vehicle propulsion system performance on three lead-acid battery systems

Three types of state of the art 6 V lead acid batteries were tested. The cycle life of lead acid batteries as a function of the electric vehicle propulsion system design was determined. Cycle life, degradation rate and failure modes with different battery types (baseline versus state of the art tubular and thin plate batteries) were compared. The effects of testing strings of three versus six series connected batteries on overall performance were investigated. All three types do not seem to have an economically feasible battery system for the propulsion systems. The tubular plate batteries on the load leveled profile attained 235 cycles with no signs of degradation and minimal capacity loss.

Ewashinka, J. G.↗

NASA NTRS1991

Hubble Space Telescope nickel-hydrogen flight spare battery test

For several years, MSFC has been engaged in a series of battery tests in support of the Hubble Space Telescope (HST) Program. Now that the HST is in orbit, many of these tests will continue in order to give those responsible for the HST a reasonable prediction on the performance of the flight batteries. These tests will also be a source of needed low earth orbit (LEO) data for nickel hydrogen (Ni-H2) batteries and cells. One of the tests currently in progress at MSFC is a mission simulation test on a 22-cell Ni-H2 battery. This battery is composed of spare cells taken from the lot of cells out of which the Flight Spare Module was assembled. This module is one of two modules launched on the HST. This battery has been on test since Jun. 1989 and has completed nearly 8000 LEO cycles. A series of characterization tests were run prior to the start of the mission simulation and a launch scenario test was run in Feb. and Mar. 1990 to test the behavior of the cells through a simulated launch. The results from these tests as well as the overall performance of the battery as it continues to cycle are reported.

Brewer, Jeffrey C.↗

NASA NTRS1994

Nickel cadmium battery operations and performance

The Earth Radiation Budget Satellite (ERBS), Compton Gamma Ray Observatory (CGRO), Upper Atmosphere Research Satellite (UARS), and Extreme Ultraviolet Explorer (EUVE) spacecraft are operated from NASA's Goddard Space Flight Center (GSFC) in Greenbelt, Maryland. On-board power subsystems for each satellite employ NASA Standard 50 Ampere-hour (Ah) nickel-cadmium batteries in a parallel configuration. To date, these batteries have exhibited degradation over periods from several months (anomalous behavior, UARS and CGRO (MPS-1); to little if any, EUVE) to several years (old age, normal behavior, ERBS). Since the onset of degraded performance, each mission's Flight Operations Team (FOT), under the direction of their cognizant GSFC Project Personnel and Space Power Application Branch's Engineers has closely monitored the battery performance and implemented several charge control schemes in an effort to extend battery life. Various software and hardware solutions have been developed to minimize battery overcharge. Each of the four sections of this paper covers a brief overview of each mission's operational battery management and its associated spacecraft battery performance. Also included are new operational procedures developed on-orbit that may be of special interest to future mission definition and development.

Rao, Gopalakrishna↗