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Find NASA NTRS and DOE OSTI reports about batteries and energy storage. Search electrode materials, lithium-ion batteries and storage systems in indexed report metadata.

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DOE OSTI2023

Impacts of Dispatch Strategies and Forecast Errors on the Economics of Behind-the-Meter PV-Battery Systems: Preprint

To assess the economic value of batteries in hybrid PV-battery systems, one must create a dispatch profile for the battery. Many analyses of battery value assume perfect forecasts of PV generation and load, determining an upper limit on the value of the battery. Prior work that accounts for forecast uncertainty often does so in the context of a single dispatch algorithm, which does not provide a baseline for comparison. Furthermore, when multiple dispatch algorithms are assessed with uncertainty, the benefits considered are for diesel generation in a microgrid, not retail rate savings. This work addresses the gaps in the literature by comparing the performance of both heuristic and optimal dispatch algorithms for retail rate savings under forecast uncertainty, and provides comparisons of the robustness of these algorithms and their associated estimates of economic value. We find that using a perfect forecast can overestimate the value of hybrid PV-battery systems between 1% and 8% compared to the reality of using a day-ahead forecast, depending on the dispatch algorithm used. Thus, accounting for forecast uncertainty in system design and analysis will significantly improve the accuracy of modeled system values.

batteries↗

DOE OSTI2015

A class of polysulfide catholytes for lithium-sulfur batteries: energy density, cyclability, and voltage enhancement

Liquid-phase polysulfide catholytes are attracting much attention in lithium-sulfur (Li-S) batteries as they provide a facile dispersion and homogeneous distribution of the sulfur active material in the conductive matrix. However, the organic solvents used in lithium-polysulfide (Li-PS) batteries play an important role and have an impact on the physico-chemical characteristics of polysulfides. For instance, significantly higher voltages (similar to 2.7 V) of the S/S-n(2-) (4 <= n <= 8) redox couple are observed in Li-PS batteries with dimethyl sulfoxide (DMSO) and N-methyl-2-pyrrolidone (NMP) solvents. Accordingly, high power Li-PS batteries are presented here with the catholyte prepared with NMP solvent and operated with the highly reversible sulfur/long-chain polysulfide redox couple. On the other hand, a remarkable cyclability enhancement of the Li-PS battery is observed with the long-chain, ether-based tetraglyme (TEGDME) solvent. The voltage enhancement and the cyclability enhancement of the Li-PS batteries are attributed to the solvation effect, viscosity, and volatility of the solvents. Finally, highly concentrated polysulfide catholytes are successfully synthesized, with which high energy density Li-PS batteries are demonstrated by employing a multi-walled carbon nanotube (MWCNT) fabric electrode.

Yu, XW↗

DOE OSTI2015

Electrochemical-acoustic time of flight: in operando correlation of physical dynamics with battery charge and health

We demonstrate that a simple acoustic time-of-flight experiment can measure the state of charge and state of health of almost any closed battery. An acoustic conservation law model describing the state of charge of a standard battery is proposed, and experimental acoustic results verify the simulated trends; furthermore, a framework relating changes in sound speed, via density and modulus changes, to state of charge and state of health within a battery is discussed. Regardless of the chemistry, the distribution of density within a battery must change as a function of state of charge and, along with density, the bulk moduli of the anode and cathode changes as well. The shifts in density and modulus also change the acoustic attenuation in a battery. Experimental results indicating both state-of-charge determination and irreversible physical changes are presented for two of the most ubiquitous batteries in the world, the lithium-ion 18650 and the alkaline LR6 (AA). Overall, a one-or two-point acoustic measurement can be related to the interaction of a pressure wave at multiple discrete interfaces within a battery, which in turn provides insights into state of charge, state of health, and mechanical evolution/degradation.

Hsieh, AG↗

DOE OSTI2020

Assembling Si 2 BN nanoribbons into a 3D porous structure as a universal anode material for both Li- and Na-ion batteries with high performance

The development of anode materials is critical to the success of sodium ion batteries (SIBs). Because of the size difference between Li and Na, the commercial anode material graphite in Li-ion batteries does not work for Na-ion batteries. Thus, it will be ideal if some universal anode materials could work for both Li- and Na-ion batteries with high performance. Inspired by a recent study on the high performance of a 2D-Si 2 BN sheet as an anode material for Li-ion batteries, we design a three dimensional (3D) porous structure by using the nanoribbons of a Si 2 BN sheet as building blocks. Based on the state-of-the-art ab initio calculations, we find that the resulting 3D porous Si 2 BN structure is stable chemically, dynamically and thermally, exhibiting a high specific capacity of 512.42 (341.61 mA h g -1 ), a low voltage of 0.27 V (0.15 V), a small volume expansion of 2.5% (2.7%), and a low migration energy barrier of 0.44 eV (0.19 eV) for Li- (Na-) ion batteries. Finally, these intriguing features, together with the light mass and rich abundance of Si, B and N, suggest that the 3D porous Si2BN structure is a promising candidate for the anode material of both Li- and Na-ion batteries.

36 MATERIALS SCIENCE↗

DOE OSTI2016

Poly(vinylidene fluoride-hexafluoropropylene) polymer electrolyte for paper-based and flexible battery applications

Paper-based batteries represent a new frontier in battery technology. However, low-flexibility and poor ionic conductivity of solid electrolytes have been major impediments in achieving practical mechanically flexible batteries. This work discuss new highly ionic conductive polymer gel electrolytes for paper-based battery applications. In this paper, we present a poly(vinylidene fluoride-hexafluoropropylene) (PVDH-HFP) porous membrane electrolyte enhanced with lithium bis(trifluoromethane sulphone)imide (LiTFSI) and lithium aluminum titanium phosphate (LATP), with an ionic conductivity of 2.1 × 10{sup −3} S cm{sup −1}. Combining ceramic (LATP) with the gel structure of PVDF-HFP and LiTFSI ionic liquid harnesses benefits of ceramic and gel electrolytes in providing flexible electrolytes with a high ionic conductivity. In a flexibility test experiment, bending the polymer electrolyte at 90° for 20 times resulted in 14% decrease in ionic conductivity. Efforts to further improving the flexibility of the presented electrolyte are ongoing. Using this electrolyte, full-cell batteries with lithium titanium oxide (LTO) and lithium cobalt oxide (LCO) electrodes and (i) standard metallic current collectors and (ii) paper-based current collectors were fabricated and tested. The achieved specific capacities were (i) 123 mAh g{sup −1} for standard metallic current collectors and (ii) 99.5 mAh g{sup −1} for paper-based current collectors. Thus, the presented electrolyte has potential to become a viable candidate in paper-based and flexible battery applications. Fabrication methods, experimental procedures, and test results for the polymer gel electrolyte and batteries are presented and discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2019

Characterization of mechanical properties of thin-film Li-ion battery electrodes from laser excitation and measurements of zero group velocity resonances

The mechanical properties of thin-film Li-ion battery electrodes are controlled by the microstructure of the constituent materials. In this work, a noncontact and nondestructive measurement of the mechanical properties of electrode films is performed by measurement of zero-group velocity (ZGV) resonances. Theoretical models are used to quantify the sensitivity of the ZGV resonances to changes in mechanical properties. The ZGV Lamb modes of a solid bilayer consisting of a thin metallic layer and a thin compliant coating layer are shown to be dependent on Young’s moduli, thicknesses, densities, and Poisson’s ratios of the layers. Experimental ZGV resonances are excited using a pulsed infrared laser and detected using a laser interferometer. Commercial-grade battery films with different coating materials, densities, and thicknesses are measured. Young’s moduli of the battery electrode layers are estimated using the combination of a theoretical model and experimental results. The effect of the calendering process on the battery materials is also investigated. Results suggest that Young’s modulus of the electrode coating increases drastically after the battery films are calendered. This technique can be used to quantitatively study the mechanical properties of Li-ion battery electrodes in order to improve overall battery performance.

Yao, Jing (ORCID:0000000209348842)↗

DOE OSTI2026

A Reverse Logistics Tool For Ev Battery Recycling And Repurposing,

The demand for electric vehicles (EVs) in the United States is projected to rise significantly, with sales expected to reach approximately 4.1 million units by 2030. However, the U.S. remains heavily reliant on imports for the batteries and critical raw materials—such as lithium, cobalt, and nickel—that power these vehicles. As of 2024, around 70% of these imports originate from China. This dependency has become even more precarious following China’s imposition of export restrictions in April 2025, a retaliatory move against U.S. tariffs. These developments highlight the strategic vulnerabilities posed by China’s dominant position in the critical materials market. Compounding the issue, decades of intensive extraction have severely depleted global reserves of critical materials, widening the gap between supply and growing demand. This situation underscores the urgent need for the U.S. and other nations to diversify their sources of critical materials and enhance domestic capabilities to secure these resources—an essential step toward ensuring long-term energy security. At the end of their lifecycle—whether due to the battery’s degradation or the retirement of the vehicle—EV batteries are often improperly disposed of or sent to landfills. However, many of these batteries still retain usable capacity and can follow one of three alternative pathways: (a) Re-used: deployed in another vehicle with a shorter driving range, (b) Re-purposed: utilized act as a backup storage/power for data centers, solar panels, and e-scotters or (c) Recycled: broken down to recover the critical materials. To that end, the proposed tool (REBORN) is designed to optimize the reverse logistics network for battery repurposing and recycling. Its goal is to minimize associated costs while identifying optimal locations for battery collection and processing. Ultimately, REBORN ensures that each battery is used to its fullest potential.

Srinivas, SrikarV. [Idaho National Laboratory (INL↗

DOE OSTI2013

Potential use of battery packs from NCAP tested vehicles.

Several large electric vehicle batteries available to the National Highway Traffic Safety Administration are candidates for use in future safety testing programs. The batteries, from vehicles subjected to NCAP crashworthiness testing, are considered potentially damaged due to the nature of testing their associated vehicles have been subjected to. Criteria for safe shipping to Sandia is discussed, as well as condition the batteries must be in to perform testing work. Also discussed are potential tests that could be performed under a variety of conditions. The ultimate value of potential testing performed on these cells will rest on the level of access available to the battery pack, i.e. external access only, access to the on board monitoring system/CAN port or internal electrical access to the battery. Greater access to the battery than external visual and temperature monitoring would likely require input from the battery manufacturer.

Lamb, Joshua↗

NASA NTRS1974

Experimental investigation and model development of the Skylab ATM secondary nickel-cadmium batteries

The performance of a Ni-Cd battery was evaluated and the cyclic battery controls to be used on the ATM batteries were determined. Cell and battery performance models were developed which to predict the performance of the secondary Ni-Cd batteries on the ATM. Capacity degradation and charge acceptance characteristics were considered. Mathematical models for each of these operating areas were developed based on data from two separate test programs. The capacity degradation model describes the expected usable battery capacity as a function of time, temperature, and depth-of-discharge. The charge acceptance model describes the cell charge acceptance as a function of charge rate, temperature, and state of charge. The models were designed for computer use and to facilitate possible battery modification. They can be used to predict expected performance or to compare real time performance during flight.

Kirsch, W. W.↗

NASA NTRS1979

Dynamic analysis of a photovoltaic power system with battery storage capability

A photovolataic power system with a battery storage capability is analyzed. A dual battery current control concept is proposed, which enables the battery to either supply or accept power depending upon system environment and load conditions. A simulation of the power system, including the battery current control, is developed and evaluated. The evaulation demonstrate the visbility of the battery control concept of switch the battery from a charge to discharge mode and back as required by load and environmental conditions. An acceptable system operation is demonstrated over the entire insolation range. Additionally, system sensitivity, bandwidth, and damping characteristics of the battery control are shown to be acceptable for a projected hardware implementation.

Merrill, W. C.↗

NASA NTRS1984

Results of electric-vehicle propulsion system performance on three lead-acid battery systems

Three types of state of the art 6 V lead acid batteries were tested. The cycle life of lead acid batteries as a function of the electric vehicle propulsion system design was determined. Cycle life, degradation rate and failure modes with different battery types (baseline versus state of the art tubular and thin plate batteries were compared. The effects of testing strings of three versus six series connected batteries on overall performance were investigated. All three types do not seem to have an economically feasible battery system for the propulsion systems. The tubular plate batteries on the load leveled profile attained 235 cycles with no signs of degradation and minimal capacity loss.

Ewashinka, J. G.↗

NASA NTRS1984

Laboratory discharge studies of a 6 V alkaline lantern-type battery Eveready Energizer no. 528, under various ambient temperatures (-15 deg C and + 22 deg C) and loads (30 omega and 60 omega)

The voltages of two Eveready No. 528 batteries, one the test battery, the other the control battery, were simultaneously recorded as they were discharged across 30 omega loads using a dual chart recorder. The test battery was initially put in a freezer at -15 + or - 3 C. After its voltage had fallen to .6 V, it was brought back out into the room at 22 + or - 3 C. A second run was made with 60 omega loads. Assuming a 3.0 V cut-off, the total energy output of the test battery at -15 C was 26 WHr 30 omega and 35 WHr 60 omega, and the corresponding numbers for the control battery at 22 C were 91 WHr and 100 WHr. When the test battery was subsequently allowed to warm up, the voltage rose above 4 V and the total energy output rose to 80 WHr 30 omega and 82 WHR 60 omega.

Ahrens, S. T.↗

NASA NTRS1984

Special Test Methods for Batteries

Various methods are described for measuring heat generation in primary and secondary batteries as well as the specific heat of batteries and cell thermal conductance. Problems associated with determining heat generation in large batteries are examined. Special attention is given to monitoring temperature gradients in nickel cadmium cells, the use of auxiliary electrodes for conducting tests on battery charge control, evaluating the linear sweep of current from charge to discharge, and determining zero current voltage. The fast transient behavior of batteries in the microsecond range, and the electrical conductance of nickel sinters in the thickness direction are also considered. Mechanical problems experienced in the vibration of Ni-Cd batteries and tests to simulate cyclic fatigue of the steel table connecting the plates to the comb are considered. Methods of defining the distribution of forces when cells are compressed during battery packaging are also explored.

Gross, S.↗

NASA NTRS1984

Results of electric-vehicle propulsion system performance on three lead-acid battery systems

Three types of state of the art 6 V lead acid batteries were tested. The cycle life of lead acid batteries as a function of the electric vehicle propulsion system design was determined. Cycle life, degradation rate and failure modes with different battery types (baseline versus state of the art tubular and thin plate batteries) were compared. The effects of testing strings of three versus six series connected batteries on overall performance were investigated. All three types do not seem to have an economically feasible battery system for the propulsion systems. The tubular plate batteries on the load leveled profile attained 235 cycles with no signs of degradation and minimal capacity loss.

Ewashinka, J. G.↗

NASA NTRS1991

Nickel hydrogen battery expert system

The Hubble Telescope Battery Testbed at MSFC uses the Nickel Cadmium (NiCd) Battery Expert System (NICBES-2) which supports the evaluation of performance of Hubble Telescope spacecraft batteries and provides alarm diagnosis and action advice. NICBES-2 provides a reasoning system along with a battery domain knowledge base to achieve this battery health management function. An effort is summarized which was used to modify NICBES-2 to accommodate Nickel Hydrogen (NiH2) battery environment now in MSFC testbed. The NICBES-2 is implemented on a Sun Microsystem and is written in SunOS C and Quintus Prolog. The system now operates in a multitasking environment. NICBES-2 spawns three processes: serial port process (SPP); data handler process (DHP); and the expert system process (ESP) in order to process the telemetry data and provide the status and action advice. NICBES-2 performs orbit data gathering, data evaluation, alarm diagnosis and action advice and status and history display functions. The adaptation of NICBES-2 to work with NiH2 battery environment required modification to all of the three component processes.

Shiva, Sajjan G.↗

NASA NTRS2005

Silicon Carbide Radioisotope Batteries

The substantial radiation resistance and large bandgap of SiC semiconductor materials makes them an attractive candidate for application in a high efficiency, long life radioisotope battery. To evaluate their potential in this application, simulated batteries were constructed using SiC diodes and the alpha particle emitter Americium Am-241 or the beta particle emitter Promethium Pm-147. The Am-241 based battery showed high initial power output and an initial conversion efficiency of approximately 16%, but the power output decayed 52% in 500 hours due to radiation damage. In contrast the Pm-147 based battery showed a similar power output level and an initial conversion efficiency of approximately 0.6%, but no degradation was observed in 500 hours. However, the Pm-147 battery required approximately 1000 times the particle fluence as the Am-242 battery to achieve a similar power output. The advantages and disadvantages of each type of battery and suggestions for future improvements will be discussed.

Rybicki, George C.↗

NASA NTRS1983

Full-charge indicator for battery chargers

A full-charge indicator for battery chargers, includes a transistor which is in a conductive state as long as charging current to the battery is not less than a level which indicates that the battery did not reach full charge. When the battery reaches full charge, a voltage drop in a resistor in the charging current path is not sufficient to maintain the transistor in a conducting state, and therefore it is switched off. When this occurs an LED is turned on, to indicate a full charge state of the battery. A photocoupler together with a photocoupler transistor are included. When the transistor is off, the photocoupler activates the photocoupler transistor to shunt out a resistor, thereby reducing the charging current to the battery to a float charging current and prevent the battery from being overcharged and damaged.

Cole, Steven W.↗

NASA NTRS2003

A Comparison of Two Panasonic Lithium-Ion Batteries and Cells for the IBM Thinkpad

The IBM Thinkpad 760XD has been used in the Orbiter and International Space Station since 2000. The Thinkpad is powered by a Panasonic Li-ion battery that has a voltage of 10.8 V and 3.0 Ah capacity. This Thinkpad is now being replaced by the IBM Thinkpad A31P which has a Panasonic Li-ion battery that has a voltage of 10.8 V and 4.0 Ah capacity. Both batteries have protective circuit boards. The Panasonic battery for the Thinkpad 760XD had 12 Panasonic 17500 cells of 0.75 Ah capacity in a 4P3S cOnfiguration. The new Panasonic battery has 6 Panasonic 18650 cells of 2.0 Ah capacity in a 2P3S configuration. The batteries and cells for both models have been evaluated for performance and safety. A comparison of the cells under similar test conditions will be presented. The performance of the cells has been evaluated under different rates of charge and discharge and different temperatures. The cells have been tested under abuse conditions and the safety features in the cells evaluated. The protective circuit board in the battery was also tested under conditions of overcharge, overdischarge, short circuit and unbalanced cell configurations. The results of the studies will be presented in this paper.

Jeevarajan, Judith A.↗