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At least 1,207 records · Page 67
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Impact toughness of commercial and model FeCrAl alloys

FeCrAl alloys are under development as possible candidate materials of accident-tolerant fuel cladding in light water reactors. In this paper, the cracking resistance of FeCrAl alloys was evaluated using half-size Charpy impact tests at temperatures ranging from room temperature to 600 °C. Ingot-metallurgy wrought FeCrAl alloys with base alloy compositions of Fe-(10–13)Cr-6Al-2Mo, in weight percent, and commercial powder-metallurgy FeCrAl alloys (Kanthal APMT) were investigated. All studied alloys showed almost zero absorbed impact energy at room temperature with brittle fracture behavior. The as-received APMT alloys exhibited poor impact toughness even at 600 °C. The ductile-brittle transition temperatures of the wrought FeCrAl alloys varied from 119 to 318 °C. Finally, the possible effects of microstructures, residual strain, materials preparation methods, process conditions, and chemical composition on the impact toughness of FeCrAl alloys were investigated by examining the Charpy impact data in combination with microstructural details of the alloys.

36 MATERIALS SCIENCE↗
NASA NTRS1974

High-temperature, low-cycle fatigue of advanced copper-base alloys for rocket nozzles. Part 2: NASA 1.1, Glidcop, and sputtered copper alloys

Short-term tensile and low-cycle fatigue data are reported for five advance copper-base alloys: Sputtered Zr-Cu as received, sputtered Zr-Cu heat-treated, Glidcop AL-10, and NASA alloys 1-1A and 1-1B. Tensile tests were performed in argon at 538 C using an axial strain rate of 0.002/sec. Yield strength and ultimate tensile strength data are reported along with reduction in area values. Axial strain controlled low-cycle fatigue tests were performed in argon at 538C using an axial strain rate of 0.002/sec to define the fatigue life over the range from 100 to 3000 cycles for the five materials studied. It was found that the fatigue characteristics of the NASA 1-1A and NASA 1-1B compositions are identical and represent fatique life values which are much greater than those for the other materials tested. The effect of temperature on NASA 1-1B alloy at a strain rate of 0.002/sec was evaluated along with the effect of strain rates of 0.0004 and 0.01/sec at 538 C. Hold-time data are reported for the NASA 1-1B alloy at 538 C using 5 minute hold periods in tension only and compression only at two different strain range values. Hold periods in tension were much more detrimental than hold periods in compression.

Conway, J. B.↗
DOE OSTI2023

Preliminary Report on Compositional Specification for Printed 316SS

The Advanced Materials and Manufacturing Technologies Program is focused on accelerating the development and deployment of advanced materials and components fabricated via additive manufacturing (AM). A key challenge for the widespread adoption of AM is the variability in material properties, which can originate from powder feedstock, process parameters, geometry, and the machine. AM powder feedstock compositions are based on those developed for conventional manufacturing. However, the smaller melt pools combined with multiple melt cycles over the course of a build can have substantial effects on the local phase selection resulting from minor batch-to-batch feedstock variability. Therefore, this report focuses on coupling CALPHAD calculations with data mining and visualization to aid the development of compositional specifications for stainless steel 316, an important alloy for nuclear applications and suitable for AM. This work reports that δ-ferrite formation has a stronger dependence on the amount of nickel in the alloy despite nickel being an austenite stabilizer. These findings show the need for exercising a tighter control on the amount of nickel in the alloy compared with the amount of chromium, which is a ferrite stabilizer.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Integrative Materials Design of Three-Phase Mo-Si-B Alloys

Mo-Si-B alloys can offer higher temperature capability than Ni-base superalloys with proper balancing of the creep, ductility, and oxidation resistance through microstructure optimization. Mo-Si-B alloys are heterogeneous, containing both brittle and ductile phases and interfaces. Therefore, the phase fractions, their distributions, and their constitutive properties over the range of room temperature to maximum use temperature must be considered. This work addresses here the optimization of mechanical properties for three-phase Mo-Si-B alloys. Three modeling tools are employed: microstructure generators to re-create statistically realistic microstructures, crystal viscoplasticity constitutive equations implemented for use with finite element solvers to capture microplasticity, and reduced-order models for evaluating important mechanical properties. In particular, the effects of microstructure on elastic modulus, yield strength, fatigue resistance, and susceptibility to brittle microcracking are considered. A novel reduced-order model is introduced for the evaluation of susceptibility to microcracking at phase interfaces. It is found that the Si content of the α-Mo phase is much more significant to the alloy’s balance of mechanical properties than the α-Mo volume fraction.

36 MATERIALS SCIENCE↗
DOE OSTI2024

In Situ Alloying Enabled by Active Liquid Metal Filler for Self‐Healing Composite Polymer Electrolytes

Abstract Solid inorganics, known for kinetically inhibiting polymer crystallization and enhancing ionic conductivity, have attracted significant attention in solid polymer electrolytes. However, current composite polymer electrolytes (CPEs) are still facing challenges in Li metal batteries, falling short of inhibiting severe dendritic growth and resulting in very limited cycling life. This study introduces Ga 62.5 In 21.5 Sn 16 (Galinstan) liquid metal (LM) as an active liquid alternative to conventional passive solid fillers, aiming at realizing self‐healing protection against dendrite problems. Compared to solid inorganics, for example silica, LM droplets could more significantly reduce polymer crystallinity and enhance Li‐ion conductivity due to their liquid nature, especially at temperatures below the polymer melting point. More importantly, LMs are unraveled as dynamic chemical traps, which are capable of blocking and consuming lithium dendrites upon contact via in situ alloying during battery operation and further inhibiting dendritic growth due to the lower deposition energy barrier of the formed Li‐LM alloy. As a proof of concept, by strategically designing an asymmetric CPE with the active LM filling, a solid‐state Li/LiFePO 4 battery achieves promising full‐cell functionality with notable rate performance and stable cycle life. This active filler‐mediated self‐healing approach could bring new insights into the battery design in versatile solid‐state systems.

Wu, Kai↗
DOE OSTI2020

Probabilistic learning and updating of a digital twin for composite material systems

This paper presents an approach for characterizing and estimating statistical dependence between a large number of observables in a composite material system. Conditional regression is carried out using the estimated joint density function, permitting a systematic exploration of interdependence between fine scale and coarse observables that can be used for both prognosis and design of complex material systems. An example demonstrates the integration of experimental data with a computational database. The statistical approach is based on the probabilistic learning on manifolds recently developed by the authors. This approach leverages intrinsic structure detected through diffusion on graphs with projected stochastic differential equations to generate samples constrained to that structure.

42 ENGINEERING↗
DOE OSTI2018

Synthesis of CS/PVA Biodegradable Composite Nanofibers as a Microporous Material with Well Controllable Procedure Through Electrospinning

In this study, we have showed a facile route for fabrication of a novel microporous material based on chitosan (CS) and poly(vinyl alcohol) (PVA) biodegradable nanofibers that have high specific surface area, considerable porosity, and small diameter. Scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, fourier transform infrared spectroscopy, Brunauer–Emmett–Teller surface area analysis, and CHNS/O elemental analyser were applied to characterize the fabricated CS/PVA composite nanofibers. Moreover, the influences of spinning conditions including concentration, voltage, electrospinning distance, and flow rate, on size distribution and pore diameter of the final product were systematically studied using 2{sup k−1} factorial design experiments, and the response surface optimization was used for determining the best synthesis parameter. The results obtained from 2{sup K−1} factorial design experiments showed that electrospinning parameters influenced the size distribution and pore diameter of the CS/PVA microporous material. Based on the response surface methodology, the CS/PVA product could be obtained with a high microporous diameter of 1.8 nm and a small diameter distribution of 15.0 nm under optimized conditions. The obtained results showed that the fabricated samples could be utilized in different applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

Comparison of experimental and simulated critical heat flux tests with various cladding alloys: Sensitivity of iron-chromium-aluminum (FeCrAl) to heat transfer coefficients and material properties

In this paper we analyze the differences between previous transient critical heat flux (CHF) experiments using iron-chromium-aluminum (FeCrAl), Inconel 600, and stainless steel 316 (SS316) alloy test sections and best-estimate modeling results from widely-used nuclear engineering systems and subchannel analysis tools. FeCrAl is an Accident Tolerant Fuel (ATF) candidate cladding material. The thermal hydraulic performance and safety characteristics of FeCrAl are being evaluated to determine viability as a cladding material in Light Water Reactors (LWRs). In this study, the results of the CHF experiments conducted at atmospheric pressure and fixed inlet coolant temperature and mass flux are compared to models built in the fifth version of the Reactor Excursion and Leak Analysis Program (RELAP5-3D) and CTF, the modernized version of COBRA-TF developed by the Consortium for Advanced Simulation of LWRs (CASL). Results from RELAP5-3D and CTF showed differences from the experiments and from each other in predicting CHF. In the Inconel 600 case, both computational tools overpredicted CHF, which led to an underprediction in the tube outer surface temperature. In the SS316 and FeCrAl cases, CHF was underpredicted by the codes, leading to an overprediction of the tube outer surface temperature. To understand the discrepancies in CHF and post-CHF predictions, studies were performed using RELAP5-3D and RAVEN to determine the sensitivity of CHF and peak test section temperature, an analog to peak cladding temperature (PCT), to heat transfer coefficients, a CHF multiplier, and uncertainties in the thermal conductivity and volumetric heat capacity. We found that CHF depends most strongly on the CHF multiplier and thermophysical properties. A combination of these factors that produced the best match to the experiment based on CHF, PCT, and the total energy deposited into the tube was determined. The best match parameters were able to provide best-estimate predictions of the CHF and integral heat flux, but were still conservative when predicting the PCT. The best match set of parameters developed in this paper are intended only as a demonstration of an approach that could be applied in the future with a larger set of experiments to produce more accurate models of CHF and post-CHF behavior.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Large Scale Synthesis of Manganese Oxide/Reduced Graphene Oxide Composites as Anode Materials for Long Cycle Lithium Ion Batteries

Manganese oxides have been frequently used as cathodes in primary batteries. Applications of manganese oxides in secondary batteries are limited by low electrical conductivity and rapid capacity fading because of electrode pulverization and aggregation. In this study, a solid-state synthetic strategy is presented that successfully combines nanosize (~ 50 nm) nickel doped α-MnO 2 with reduced graphene oxides as highly stable composite anodes in lithium ion batteries. The synthesis approach is easy to scale up and suitable for industrial applications. Here, the rationally designed Ni-α-MnO 2 /RGO was tested in galvanostatic half coin cells for Li + charge-discharge studies. The results show that this composite maintains a high capacity of 615 mAh g -1 even after 200 cycles at a high current rate of 1 C (830 mA g -1 ), and with a high Coulombic efficiency near 99%. The anodes exhibit excellent rate capability in a wide range of rate testing from 0.2 to 10 C, without showing capacity decay. This superior anode performance is ascribed to the reduced size of α-MnO 2 domains that are well dispersed in an RGO matrix, which affords good ionic/elec. cond., low charge transfer resistance and mitigates issues of vol. expansion of the anodic active materials. This study opens up an avenue for developing the manufacturing of high-performance electrodes for real applications, such as batteries in electrical vehicles.

25 ENERGY STORAGE↗
DOE OSTI2022

Translating Material-Level Characterization of Carbon-Nanotube-Reinforced Composite Gridlines to Module-Level Degradation

Cell cracks in PV modules caused by poor handling during shipping and installation as well as from extreme weather events can lead to gradual or immediate power degradation. To directly address cell-crack-induced degradation, we have formulated a carbon nanotube additive for commercial screen printed silver pastes. We have shown in previous work that these metal matrix composites have little to no effect on the cell's efficiency while enhancing the metallization's fracture toughness and electrical gap-bridging capability. In this work, we focus on translating materials level characterization techniques to module level degradation. We found that we get conflicting results from two different methods of measuring the metallization's ability to electrically bridge gaps in cracked solar cells. Mini-module stress testing is currently underway to determine which materials characterization correlates well with the min-module degradation characteristics.

carbon nanotubes↗
DOE OSTI2018

Effect of the Plasma Functionalization of Carbon Nanotubes on the Formation of a Carbon Nanotube–Nickel Oxide Composite Electrode Material

The unique properties of carbon nanotubes (CNTs) make these systems promising for the production of composite electrode materials based on a combination of CNTs and transition metal oxides. The effect the parameters of the functionalization of vertically aligned CNT arrays in mixed argon–oxygen high-frequency plasma have on the structural characteristics of CNTs is studied by Raman spectroscopy. The effect the duration of treatment at higher partial argon consumption and low total gas consumption of the working mixture has on the distribution of nickel oxide over a CNT array deposited via SILAR is determined. Results from scanning electron microscopy show that lengthening the duration of functionalization from 30 to 1200 s allows the depth of coating a CNT surface with a nickel oxide layer to be increased from 300 nm to 2.5 μm. Composite structures produced in this work can be used as electrodes of supercapacitors.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Electrodynamic Characteristics of Horn Microwave Antennas Made of Graphene-Containing Carbon-Composite Materials

Electrodynamic characteristics of the L-and C-range horn antennas made of carbon-composite materials with graphene-containing binding substance are studied. The main attention is paid to the polarization characteristics of the L-range antennas with a polarization unit based on a circular waveguide that generates elliptically polarized radiation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Variation of lead isotopic composition and atomic weight in terrestrial materials (IUPAC Technical Report)

The isotopic composition and atomic weight of lead are variable in terrestrial materials because its three heaviest stable isotopes are stable end-products of the radioactive decay of uranium ( 238 U to 206 Pb; 235 U to 207 Pb) and thorium ( 232 Th to 208 Pb). The lightest stable isotope, 204 Pb, is primordial. These variations in isotope ratios and atomic weights provide useful information in many areas of science, including geochronology, archaeology, environmental studies, and forensic science. While elemental lead can serve as an abundant and homogeneous isotopic reference, deviations from the isotope ratios in other lead occurrences limit the accuracy with which a standard atomic weight can be given for lead. In a comprehensive review of several hundred publications and analyses of more than 8000 samples, published isotope data indicate that the lowest reported lead atomic weight of a normal terrestrial materials is 206.1462 ± 0.0028 (k = 2), determined for a growth of the phosphate mineral monazite around a garnet relic from an Archean high-grade metamorphic terrain in north-western Scotland, which contains mostly 206 Pb and almost no 204 Pb. The highest published lead atomic weight is 207.9351 ± 0.0005 (k = 2) for monazite from a micro-inclusion in a garnet relic, also from a high-grade metamorphic terrain in north-western Scotland, which contains almost pure radiogenic 208 Pb. When expressed as an interval, the lead atomic weight is [206.14, 207.94]. It is proposed that a value of 207.2 be adopted for the single lead atomic-weight value for education, commerce, and industry, corresponding to previously published conventional atomic-weight values.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

(U) Calculating First-Order Sensitivities to Material Density and Composition in Fixed-Source Problems Using the MCNP6 Perturbation Capability

The Taylor series (differential operator) perturbation method, as implemented in the PERT capability in MCNP6 (Ref. 1), can be used for first-order sensitivity analyses in fixed-source problems.2 Sensitivities of a response with respect to material and nuclide densities can be used for efficient first-order uncertainty quantification. This report discusses how to compute sensitivities of material densities and compositions in order to propagate uncertainties using the standard uncertainty propagation formula.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Analyze the Composition of Materials Through the Use of Characterization Instruments - CRADA 621 (Abstract)

The purpose of this project is to conduct collaborative research involving the analysis of the composition of materials using characterization instruments. The materials will be synthesized in the Nuclear Chemistry Facility in Fulmer Hall and analyzed using instruments both at WSU and PNNL. This research requires the use of several characterization instruments, namely a Biotage SEL-2SW Flash Chromatograph, a Jasco UV-Visible Near-IR V-770 spectrometer, and a Jasco FT/IT-6700 Research Spectrometer, in the Nuclear Chemistry Facility of the WSU-PNNL Nuclear Science and Technology Institute (NSTI) in Fulmer Hall on the WSU Pullman campus.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗