NASA NTRS · 19720023083
Study of sulfospinels
Abstract
Several new compounds with the formula AB2S4 were synthesized. Pressure-induced polymorphism of the sulfospinels was investigated. Sulfospinels which produced new high-pressure phases were NiRh2S4, FeYb2S4, In2S3, CrIn2S4, NiIn2S4, CoIn2S4 and MnIn2S4. The only sulfospinels which transformed to the NiAs derivatives were those in which A and B atoms had unfilled d-orbitals. P-T phase relations were investigated for a series of sulfochromites. Thin films of several ACr2S4 sulfospinels were prepared by a flash evaporization technique on the (111) and (100) planes of NaCl and on the (100) plane of Mgo.
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Tressler, R. E., Stubican, V. S.. 1972-07-01. Study of sulfospinels. https://ntrs.nasa.gov/citations/19720023083
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