Hyperfine interactions of Fe/2+/ in ilmenite.

Abstract

Hyperfine interactions at the Fe(2+) sites in ilmenite have been determined by Mossbauer spectroscopy. At 5 K, the internal magnetic field is -43 (plus or minus 3) kOe, and the quadrupole coupling constant is +1.44 (plus or minus 0.01) mm/sec. Theoretical interpretation of the internal magnetic field in terms of dipolar-, orbital-, and core-polarization contributions is shown to depend critically upon the still unknown lattice contribution to the quadrupole coupling constant.