Zero-derivative boundary condition for pulsed distributed systems

Abstract

To permit use of experimentally determined Peclet numbers in numerical simulations of pulsed distributed flow systems such as chromatograph columns, substitution of the zero-derivative boundary condition for the infinite boundary condition used in treating data is examined. Moment analysis shows that application of the zero-derivative condition external to the column will yield equivalent numerical results for the two boundary conditions. Criteria for locating this position are provided as a function of the Peclet number.