Formation of metallic LiH

Abstract

It is shown that a metallic form of LiH may be produced at the relatively low transition pressure of 1.1 mbar. LiH may thus be applied to studies of insulator-metal transition at high pressure. Experimental data is used to calculate LiH transition parameters: first, Herzfeld's criterion (1927) is used to determine the volume at which metallic behavior begins, and second, pressure-volume measurements for estimating the pressure at which this volume is achieved are extrapolated. For comparison, the same volume-pressure calculation is performed for H2, and it is found that the metallization of LiH should occur more easily than that of H2.