Synthesis of polyformals

Abstract

Formals of CH2OH(CHOH) sub n CH2OH polyols (n = 2 to 4) are prepared in less than 15 minutes by heating to about 125 C, a mixture of e.g. sorbitol and paraformaldehyde in slight excess (5 to 10%), in the presence of e.g. sulfuric acid in catalytic quantities. Elution with methanol and filtration yield the pure solid cyclic triformal. The process can be carried in stages, using almost stoichiometric quantities of paraformaldehyde, but without any change in overall heating time.