Equivalent absorption coefficients generated from frequency probability distributions

Abstract

A flexible and computationally accurate method of treating aerosol scattering in spectral regions in which gaseous absorption is important is described. In the method, line-by-line absorption coefficients are computed as a function of pressure, temperature, and absorber gas for the spectral region of interest. The coefficients are sorted into a probability distribution which is converted into a cumulative probability distribution, which in turn can be inverted due to its monotonic nature. The inverted distribution is a smooth curve giving the absorption coefficient as a function of an independent variable on the domain. The frequency integration of the radiative transfer equation can then be performed by a quadrature technique with values of the absorption coefficient determined from the inverted distribution curve. The method is illustrated by applying it to the 9.6 micron band of ozone.