Electron-CF4 elastic scattering in the static-exchange approximation

Abstract

Differential, integral, and momentum-transfer cross sections for the elastic scattering of electrons by CF4 from 5 to 35 eV are reported. The calculations were carried out at the fixed-nuclei, static-exchange level usign the Schwinger variational principle. Analyses of the partial channel amplitudes show four broad shape resonances; two in T2, one in A1, and one in E symmetries. The positions of these resonances agree with experimental data from total-cross-section measurements, dissociative attachment studies, and low-energy electron excitation spectra, the only exception being the 8.9-eV structure in the total-cross-section data. No experimental measurements on differential cross sections are available, but comparing with the corresponding static-exchange calculations for the e-CH4 system, the e-CF4 cross sections generally are less backward peaked.