Are Einstein's transition probabilities for spontaneous emission constant in plasmas?

Abstract

An investigation is conducted with a ruby laser to experimentally confirm the quenching of spontaneous emission coefficients and propose a mechanism for the phenomenon. Results of previous experiments are examined to determine the consistency and validity of interpretations of the spontaneous emissions. For the C IV 3s-3p and 2s-3p transitions, the line-intensity ratios are found to be dependent on the separation of the laser from the target. Density gradients and Stark broadening are proposed to interpret the results in a way that does not invalidate the Einstein A values. The interpretation is extended to C III and N V, both of which demonstrate similar changes in A values in previous experiments. The apparent quenching of Ar II by photon collisions is explained by Rabi oscillations and power broadening in the argon-ion laser cavity. It is concluded that the changes in A values cannot result from dense plasma effects.