Diffusing Wave Spectroscopy Used to Study Foams

Abstract

The white appearance of familiar objects such as clouds, snow, milk, or foam is due to the random scattering of light by the sample. As we all know, pure water is clear and easily passes a beam of light. However, tiny water droplets, such as those in a cloud, scatter light because the air and water droplet have different indexes of refraction. When many droplets, or scattering sites, are present, the incident light is scattered in random directions and the sample takes on a milky white appearance. In a glass of milk, the scattering is due to small colloidal particles. The white appearance of shaving cream, or foam, is due to the scattering of light at the water-bubble interface. Diffusing wave spectroscopy (DWS) is a laser light-scattering technique used to noninvasively probe the particle dynamics in systems that strongly scatter light. The technique takes advantage of the diffuse nature of light, which is reflected or transmitted from samples such as foams, dense colloidal suspensions (such as paint and milk), emulsions, liquid crystals, sandpiles, and even biological tissues.