Multiple Knudsen Cell Configuration Improved for Alloy Activity Studies

Abstract

Knudsen effusion mass spectrometry (KEMS) allows the simultaneous determination of the identity and pressure of vapor species in equilibrium with a condensed phase as a function of temperature. This information can be used to determine the thermodynamic properties of materials. The partial pressure of species j in the cell is related to the measured intensity of the ion k formed from j, I(sup +) less than SABjk, and the absolute temperature T, where S(sub jk) is the sensitivity factor.