Search NASA⌕ Search

NASA NTRS · 20210005068

GAuche-Ethyl Alcohol: Laboratory Assignments and Interstellar Identification

Abstract

Ethyl alcohol (ethanol) is known to possess a pair of closely-spaced excited torsional substates (gauche +, gauche -) at an energy of approximately 57 K above the ground (trans) torsional substrate. We report an extended analysis of some gauch- - gauch+ Q branch (delta J=0) transitions witha three-substrate fixed frame axis method (FFAM) Hamilton.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

De Lucia, Frank C., Herbst, Eric, Sastry, K. V. L. N., Pearson, J. C.. 1996-01-01. GAuche-Ethyl Alcohol: Laboratory Assignments and Interstellar Identification. https://ntrs.nasa.gov/citations/20210005068

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related reports

The Correct Sense of Faraday Rotation

The phenomenon of Faraday rotation of linearly polarized synchrotron emission in a magneto-ionized medium has been understood and studied for decades. But since the sense of the rotation itself is irrelevant in most contexts, some uncertainty and inconsistencies have arisen in the literature about this detail. Here, we start from basic plasma theory to describe the propagation of polarized emission from a background radio source through a magnetized, ionized medium in order to rederive the correct sense of Faraday rotation. We present simple graphics to illustrate the decomposition of a linearly polarized wave into right and left circularly polarized modes, the temporal and spatial propagation of the phases of those modes, and the resulting physical rotation of the polarization orientation. We then re-examine the case of a medium that both Faraday-rotates and emits polarized radiation and show how a helical magnetic field can construct or destruct the Faraday rotation. This paper aims to resolve a source of confusion that has arisen between the plasma physics and radio astronomy communities and to help avoid common pitfalls when working with this unintuitive phenomenon.

ISM↗

The Detection of 6.9 µm Emission Features in the Infrared Spectra of IRAS 04296+3429, IRAS 05341+0852, IRAS 22272+5435: Evidence for the Presence of Hn-PAHs in Post AGB Stars

Polycyclic aromatic hydrocarbons (PAHs) are generally believed to be ubiquitous in space and responsible for numerous telltale interstellar infrared emission bands. In Sandford et al., (2013), we suggested that polycyclic aromatic hydrocarbons with excess hydrogenation at their periphery (Hn-PAHs) may be an important subclass of these molecules in some astrophysical environments. These molecules are candidates to explain objects with anomalously large 3.4 μm features, which are presumed to be associated with the aliphatic C—H stretching vibrations of the excess hydrogen. In that work, we suggest that for Hn-PAHs to be a viable candidate as the source for this 3.4 μm feature, we must also expect to observe methylene scissoring modes at 6.9 μm. In this work, we continue to develop the Hn-PAH hypothesis with a focus on the 6.9 μm feature. We also present some new observations of three post-asymptotic giant branch (post- AGB) objects with abnormally large 3.4 μm features, IRAS 04296+3429, IRAS 05341+0852, IRAS 22272+5435, in addition to one post-AGB object with normal PAH emissions, IRAS 20000+3239. These observations were made using the FORCAST instrument in grism mode on the Stratospheric Observatory for Infrared Astronomy (SOFIA) aircraft (Adams et al. 2010) and demonstrate the presence of a 6.9 μm feature for the three objects with abnormally large 3.4 μm features and no detectable 6.9 μm feature for the normal PAH emitter. These results are consistent with the hypothesis that Hn-PAHs are a possible source of these infrared emission bands.

ISM↗

Measurement of the X-Ray Proper Motion in the South-East Rim of RXJ1713.7-3946

We report on the first proper motion measurement in the supernova remnant RX J1713.73946 using the XMM-Newton X-ray telescope on a 13 yr time interval. This expansion measurement is carried out in the south-east region of the remnant, where two sharp filament structures are observed. For the outermost filament, the proper motion is 0.75(+0.05-0.06) +/- 0.069 syst arcsec/ yr which is equivalent to a shock speed of approx. 3500 km/s at a distance of 1 kpc. In contrast with the bright north-west region, where the shock is interacting with the border of the cavity, the shock in the south-east region is probably expanding in the original ambient medium carved by the progenitor and can be used to derive the current density at the shock and the age of the remnant. In the case where the shock is evolving in a wind profile (p varies as r(sup -s), s = 2) or in a uniform medium (s = 0), we estimate an age of approx. 2300 yr and approx.1800 yr respectively for an ejecta power-law index of n = 9. The specific case of an ejecta power-law index of n = 7, and s = 0, yields an age of approx. 1500 yr, which would reconcile RX J1713.73946 with the historical records of SN 393. In all scenarios, we derive similar upstream densities of the order of 0.01/cu cm, compatible with the lack of thermal X-rays from the shocked ambient medium.

ISM↗