NASA NTRS · 20210023701
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Elaine Stewart. Study of Fallout Metrics for Contamination Analysis. https://ntrs.nasa.gov/citations/20210023701
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Phthalate molecular contamination, identified in the Laser Mégajoule target chamber, can severely alter porous coatings' performance, such as glancing angle deposited quarter-wave plates (QWP). QWPs could potentially be used inside this chamber to smooth the intensity of the focal spots on the target. In this study, all-silica QWP coatings were contaminated with dimethyl phthalate. Transmission was lowered due to the absorption of phthalates, and a non-uniform retardance was induced, even after a two-month storage period in air following contamination. Infrared measurements confirmed the presence of bonds associated with phthalates within the coatings due to their sorption and only partial desorption.
As we search for life on Mars, we will be simultaneously contaminating Mars with life from Earth. The contamination from Earth could be mistaken for Martian life. How can this paradox be avoided? With the results of our research, the scientific community will be able to determine locations of future habitats that minimize the aerial extent subject to bio-contaminants, protect sites of astrobiological interest, and constrain landing site selection of life detection missions to reduce risk of false positives. We consider a putative human habitat on Mars. Biological contaminants will flow out of the habitat into the Martian atmosphere, and the atmosphere will move these contaminants around. How many biological particles per year will be released from the habitat into the Martian ambient environment? How far will the contamination travel? In what directions will it travel? How long will the contamination be in the atmosphere? We study these questions quantitatively by simulating the Martian atmosphere using the NASA Ames Mars Global Climate Model. Various combinations of human habitat locations and contaminant sizes are considered. The results from these simulations enable the creation of novel contamination heat maps showing the aerial distribution of contaminants from putative human habitats on Mars.
A challenge present in assessing contamination accumulation on many missions is predicting fallout during ground processing given the multiple and various orientations possible for surfaces such as optics and instruments. The best practice assumption has been to quantify particle build up on vertical surfaces as approximately 1/10 that of horizontal surfaces. This fractional relation is important when considering contamination allocations necessary to meet cleanliness requirements since spacecraft can be in many orientations during integration and testing. There is insufficient data to provide confidence in the 1/10 approximation, yet its use can have a significant effect on mission end of life contamination level predictions, leading to expenditures of precious resources to meet mission requirements. A study was conducted to compare and analyze the fallout in horizontal and vertical orientations. Silicon wafers were deployed in four different facilities. Data sets from a long term deployment of wafers were analyzed from a cleanroom facility housing integration of the James Webb Space Telescope (JWST) as well as from a shorter term deployment of wafers in three cleanroom facilities at Goddard Space Flight Center with lower activity. There are many variables influencing the relationship between fallout on vertical and horizontal wafers, including wafer position with respect to air flow, air changes in the facility, duration of exposure, and activity workload. The goal of this continuing study is to develop a tool to inform particulate accumulation predictions for future projects.