Materials Data on TiRh3 by Materials Project

Abstract

Rh3Ti is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ti is bonded to twelve equivalent Rh atoms to form TiRh12 cuboctahedra that share corners with twelve equivalent TiRh12 cuboctahedra, edges with twenty-four equivalent RhTi4Rh8 cuboctahedra, faces with six equivalent TiRh12 cuboctahedra, and faces with twelve equivalent RhTi4Rh8 cuboctahedra. All Ti–Rh bond lengths are 2.73 Å. Rh is bonded to four equivalent Ti and eight equivalent Rh atoms to form distorted RhTi4Rh8 cuboctahedra that share corners with twelve equivalent RhTi4Rh8 cuboctahedra, edges with eight equivalent TiRh12 cuboctahedra, edges with sixteen equivalent RhTi4Rh8 cuboctahedra, faces with four equivalent TiRh12 cuboctahedra, and faces with fourteen equivalent RhTi4Rh8 cuboctahedra. All Rh–Rh bond lengths are 2.73 Å.