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DOE OSTI · 1191690

Materials Data on Li2AgSb by Materials Project

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Abstract

Li2AgSb is alpha bismuth trifluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to four equivalent Sb3- atoms to form corner-sharing LiSb4 tetrahedra. All Li–Sb bond lengths are 2.88 Å. In the second Li1+ site, Li1+ is bonded to four equivalent Ag1+ atoms to form distorted corner-sharing LiAg4 tetrahedra. All Li–Ag bond lengths are 2.88 Å. Ag1+ is bonded in a body-centered cubic geometry to four equivalent Li1+ and four equivalent Sb3- atoms. All Ag–Sb bond lengths are 2.88 Å. Sb3- is bonded in a 8-coordinate geometry to four equivalent Li1+ and four equivalent Ag1+ atoms.

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36 MATERIALS SCIENCEAg-Li-Sbcrystal structureLi2AgSb

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2020-07-15. Materials Data on Li2AgSb by Materials Project. https://doi.org/10.17188/1191690

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36 MATERIALS SCIENCE↗