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DOE OSTI · 1192099

Materials Data on Ti5Sb2Rh by Materials Project

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Abstract

Ti5RhSb2 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded in a 6-coordinate geometry to two equivalent Rh and four equivalent Sb atoms. Both Ti–Rh bond lengths are 2.68 Å. There are two shorter (2.81 Å) and two longer (3.08 Å) Ti–Sb bond lengths. In the second Ti site, Ti is bonded in a 6-coordinate geometry to two equivalent Ti and four equivalent Sb atoms. Both Ti–Ti bond lengths are 2.62 Å. All Ti–Sb bond lengths are 2.76 Å. Rh is bonded in a 10-coordinate geometry to eight equivalent Ti atoms. Sb is bonded in a 10-coordinate geometry to ten Ti atoms.

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36 MATERIALS SCIENCEcrystal structureRh-Sb-TiTi5Sb2Rh

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2020-07-14. Materials Data on Ti5Sb2Rh by Materials Project. https://doi.org/10.17188/1192099

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