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DOE OSTI · 1197507

Materials Data on Ag5(PbO3)2 by Materials Project

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Abstract

Ag5Pb2O6 crystallizes in the trigonal P-31m space group. The structure is three-dimensional. there are two inequivalent Ag+1.20+ sites. In the first Ag+1.20+ site, Ag+1.20+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.34 Å. In the second Ag+1.20+ site, Ag+1.20+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.15 Å. Pb3+ is bonded to six equivalent O2- atoms to form edge-sharing PbO6 octahedra. All Pb–O bond lengths are 2.28 Å. O2- is bonded to two Ag+1.20+ and two equivalent Pb3+ atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra.

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36 MATERIALS SCIENCEAg-O-PbAg5(PbO3)2crystal structure

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2020-07-16. Materials Data on Ag5(PbO3)2 by Materials Project. https://doi.org/10.17188/1197507

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