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DOE OSTI · 1199532

Materials Data on Rb2PbCl6 by Materials Project

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Abstract

Rb2PbCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent Cl1- atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent RbCl12 cuboctahedra, faces with six equivalent RbCl12 cuboctahedra, and faces with four equivalent PbCl6 octahedra. All Rb–Cl bond lengths are 3.72 Å. Pb4+ is bonded to six equivalent Cl1- atoms to form PbCl6 octahedra that share faces with eight equivalent RbCl12 cuboctahedra. All Pb–Cl bond lengths are 2.57 Å. Cl1- is bonded to four equivalent Rb1+ and one Pb4+ atom to form a mixture of distorted corner, edge, and face-sharing ClRb4Pb square pyramids.

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36 MATERIALS SCIENCECl-Pb-Rbcrystal structureRb2PbCl6

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2017-05-10. Materials Data on Rb2PbCl6 by Materials Project. https://doi.org/10.17188/1199532

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