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DOE OSTI · 1199597

Materials Data on XeN2(OF4)2 by Materials Project

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Abstract

XeF8(NO)2 is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight nitroxyl molecules and four XeF8 clusters. In each XeF8 cluster, Xe is bonded in a 8-coordinate geometry to eight F atoms. There are a spread of Xe–F bond distances ranging from 2.05–2.31 Å. There are five inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one Xe atom. In the second F site, F is bonded in a single-bond geometry to one Xe atom. In the third F site, F is bonded in a single-bond geometry to one Xe atom. In the fourth F site, F is bonded in a single-bond geometry to one Xe atom. In the fifth F site, F is bonded in a single-bond geometry to one Xe atom.

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36 MATERIALS SCIENCEcrystal structureF-N-O-XeXeN2(OF4)2

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2020-05-02. Materials Data on XeN2(OF4)2 by Materials Project. https://doi.org/10.17188/1199597

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